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Citation: LI Guang-jun, XI Hong-juan, ZHANG Su-hong, GU Chuan-tao, QIN Shao-jun, HOU Xiao-ning, GAO Zhi-xian. Catalytic characteristics of spinel CuM2O4 (M=Al, Fe, Cr) for the steam reforming of methanol[J]. Journal of Fuel Chemistry and Technology, ;2012, 40(12): 1466-1471. shu

Catalytic characteristics of spinel CuM2O4 (M=Al, Fe, Cr) for the steam reforming of methanol

  • 1.

    1. Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

  • Corresponding author: GAO Zhi-xian, 
  • Received Date: 25 April 2012
    Available Online: 29 June 2012

  • Spinel oxides of CuAl2O4, CuFe2O4 and CuCr2O4 were prepared by citrate process at 900 ℃, and their catalytic properties for methanol steam reforming was evaluated. In combination with the XRD, H2-TPR, SEM and BET data, the catalytic characteristics of spinel oxides were also discussed. The results showed that the morphology and size of the three spinel oxides were quite different and catalytic properties varied among the three spinel oxide catalysts. CuAl2O spinel showed the highest stability and lowest CO selectivity while CuFe2O4 indicated the highest CO selectivity and poor stability and CuCr2O4 encountered serious coke deposition. It has been shown, according to the long test data and results, that active Cu species were released from copper based spinel during methanol steam reforming, and their catalytic performances were influenced by both Cu sintering and coke deposition.
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