Citation: WANG Xu-hong, YUAN Shan-mei, ZHU Yu, NI Hong-jun. Preparation and performance research of PtSn catalyst supported on carbon fiber for direct ethanol fuel cells[J]. Journal of Fuel Chemistry and Technology, ;2012, 40(12): 1454-1458. shu

Preparation and performance research of PtSn catalyst supported on carbon fiber for direct ethanol fuel cells

WANG Xu-hong ^1,2 ,
YUAN Shan-mei ¹ ,
ZHU Yu ¹ ,
NI Hong-jun ^1,,

1.
1. School of Mechanical Engineering, Nantong University, Nantong 226009, China;

Corresponding author: NI Hong-jun,
Received Date: 7 June 2012
Available Online: 31 August 2012
Fund Project: 国家科技支撑计划(2011BAG02B10) (2011BAG02B10) 江苏高校自然科学重大基础研究项(08KJA480001) (08KJA480001) 南通市应用研究计划项目(BK2011029) (BK2011029) 南通大学自然科学研究专项(09ZJ002, 11ZY007)。 (09ZJ002, 11ZY007)

PtSn anode catalyst supported on carbon fiber was taken as the anode catalyst of the MEA. Commercial Pt/C catalyst was used in MEA as the cathode catalyst. The Nafion 115 membrane was the proton exchange membrane of the MEA. MEA was fabricated by hot-pressing. The sing flat cell was assembled with the prepared MEA. The influences of temperature, ethanol concentration, rates of liquor and O₂ were studied. The results showed that the performance of the fuel was better when the concentration of ethanol was 1.0 mol/L, the rate of liquor was 1.0 mL/min, the temperature was 80 ℃, and the rate of O₂ was 100 mL/min, the maximum power density of the fuel reached about 18.2 mW/cm².
- direct ethanol fuel cell (DEFC),
- carbon fiber,
- PtSn catalyst,
- membrane electrode assemble
1. [1]
  [1] 朱昱, 汪兴兴, 倪红军, 黄明宇. 成型工艺条件对MCMB/石墨复合材料性能的影响[J]. 南通大学学报(自然科学版), 2009, 8(1): 5-8. (ZHU Yu, WANG Xing-xing, NI Hong-jun, HUANG Ming-yu. Effect of molding process conditions upon performance of MCMB/graphite composite[J]. Journal of Nantong University(Natural Science Edition), 2009, 8(1): 5-8.)
2. [2]
  [2] 袁善美, 朱昱, 倪红军, 黄明宇. 直接乙醇燃料电池研究进展[J]. 化工新型材料, 2011, 39(1): 15-18. (YUAN Shan-mei, ZHU Yu, NI Hong-jun, HUANG Ming-yu. Research progress on direct ethanol fuel cell[J]. New Chemical Materials,2011, 39(1): 15-18.)
3. [3]
  [3] 陈胜洲, 林维明, 董新法. 直接甲醇燃料电池性能研究[J]. 电源技术, 2006, 30(1): 44-47. (CHEN Sheng-zhou, LIN Wei-ming, DONG Xin-fa. Study on the performance of direct methanol fuel cell[J]. Chinese Journal of Power Sources, 2006, 30(1): 44-47.)
4. [4]
  [4] 倪红军, 汪兴兴, 汤东, 李飞, CHRISTENSEN P A. 异型Ti电极直接乙醇燃料电池的制备与性能[J]. 江苏大学学报(自然科学版), 2010, 31(5): 558-563. (NI Hong-jun, WANG Xing-xing, TANG Dong, LI Fei, CHRISTENSEN P A. Preparation and cellperformance of special-shaped Ti electrode for direct ethanol fuel cell[J]. Journal of Jiangsu University(Natural Science Edition), 2010, 31(5): 558-563.)
5. [5]
  [5] JARUUK T, SUPAORN T, APICHAI T. Effect of pre-treatment approach of a carbon support on activity of PtSn/C electrocatalyts for direct ethanol fuel cells[J]. J Appl Electrochem, 2011, 41(4): 435-444.
6. [6]
  [6] DEIVARAJ T C, LEE J Y. Preparation of carbon-supported PtRu nanoparticles for direct methanol fuel cell applications-a comparative study[J]. J Power Sources, 2005, 142(1/2): 43-49.
7. [7]
  [7] LAMY C, BELGSIR E M, LEGER J M. Electro-catalytic oxidation of aliphatic alcohols: Application to the direct alcohol fuel cell (DAFC)[J]. J Appl Electrochem, 2001, 31(7): 799-809.
8. [8]
  [8] ZHOU W J, LI W Z, SONG S Q, ZHOU Z H,JIANG L H,SUN G Q, XIN Q, POULIANITIS K, KONTOU S, TSIAKARAS P. Bi- and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells[J]. J Power Sources, 2004, 131(1/2): 217-223.
9. [9]
  [9] 宋树芹. 直接乙醇燃料电池: 乙醇渗透和MEA制备及其对DEFC单池性能的影响.大连:中国科学院大连化学物理研究所, 2004. (SONG Shu-qin. Direct ethanol fuel cells: Studies on ethanol crossover & MEA preparation and their influence on single DEFC’s performance. Dalian: Institute of Chemical Physics Chinese Academy of Sciences, 2004.)
10. [10]
  [10] GHUMMAN A, LI G , BENNETT D V, PICKUP P G. Online analysis of carbon dioxide from a direct ethanol fuel cell [J]. J. Power Sources, 2009, 194(1): 286-290.
11. [11]
  [11] CASTROLUNA A M, BONESI A, TRIACA W E. Investigation of a Pt-Fe/C catalyst for oxygen reduction reaction in direct ethanol fuel cells[J]. J Nanopart Res, 2010, 12(1): 357-365.
12. [12]
  [12] ZHOU W J, ZHOU B, LI W Z, ZHOU Z H, SONG S Q, XIN Q, DOUVARTZIDES S, GOULA M, TSIAKARAS P. Performance comparison of low-temperature direct alcohol fuel cells with different anode catalysts[J]. J Power Sources, 2004, 126(1/2): 16-22.
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