Citation:
ZHU Miao, WANG Xiao-hong, HU Zhi-yu. Preparation of Pt/Al2O3 catalyst and its performance on methanol catalytic combustion at low temperature[J]. Journal of Fuel Chemistry and Technology,
;2012, 40(11): 1403-1408.
-
Pt/Al2O3 catalysts were prepared by a one step method and the catalytic activity of these catalysts was evaluated by methanol combustion at low temperature. The effects of preparation conditions including the reductant concentration, the surfactant dosage, the surfactant concentration and the calcination temperature were investigated in detail. The results indicated that the catalytic activity was the highest under the conditions of 0.1 mol/L of reductant concentration, 8.53 g/gcat. of surfactant dosage and 600℃ of calcination temperature. The methanol conversion on this kind of catalyst could reach to 52% at 25℃. The modified one step method can improve the catalytic activity further, which could reach up to 84% at 25℃.
-
Keywords:
- one step method,
- methanol,
- low temperature,
- catalytic combustion
-
-
-
[1]
[1] OKAL J, ZAWADZKI M, TYLUS W. Microstructure characterization and propane oxidation over supported Ru nanoparticles synthesized by the microwave-polyol method[J]. Appl Catal B, 2011, 101(3): 548-559.
-
[2]
[2] AVGOUROPOULOS G, OIKONOMOPOULOS E, KANISTRAS D, IOANNIDES D. Complete oxidation of ethanol over alkali-promoted Pt/Al2O3 catalysts[J]. Appl Catal B, 2006, 65(1/2): 62-69.
-
[3]
[3] LI D, ZHENG Y, WANG X. Effect of phosphoric acid on catalytic combustion of trichloroethylene over Pt/P-MCM-41[J]. Appl Catal A, 2008, 340(1): 33-41.
-
[4]
[4] SU X-W, JIN L-Y, LU J-Q, LUO M-F. Pd/Ce0.9Cu0.1O1.9-Y2O3 catalysts for catalytic combustion of toluene and ethyl acetate[J]. J Ind Eng Chem, 2009, 15(5): 683-686.
-
[5]
[5] AOUAD S, ABI-AAD E, ABOUKAIS A. Simultaneous oxidation of carbon black and volatile organic compounds over Ru/CeO2 catalysts[J]. Appl Catal B, 2009, 88(3/4): 249-256.
-
[6]
[6] PARUS W J, PATERKOWSKI W. Catalytic oxidation of organic pollutants[J]. Pol J Chem Technol, 2009, 11(4): 30-37.
-
[7]
[7] DAS D P, PARIDA K M. Mn(III) oxide pillared titanium phosphate (TiP) for catalytic deep oxidation of VOCs[J]. Appl Catal A, 2007, 324: 1-8.
-
[8]
[8] TAHIR S F, KOH C A. Catalytic destruction of volatile organic compound emissions by platinum based catalyst[J]. Chemosphere, 1999, 38(9): 2109-2116.
-
[9]
[9] WU J C S, FAN Y-C, LIN C-A. Deep oxidation of methanol using a novel Pt/boron nitride catalyst[J]. Ind Eng Chem Res, 2003, 42(14): 3225-3229.
-
[10]
[10] 潘相敏, 余瀛, 严菁, 宋小瑜, 马建新. 甲醇制氢系统中燃烧催化剂的研究[J]. 太阳能学报, 2006, 27(8): 841-845. (PAN Xiang-min, YU Ying, YAN Qian, SONG Xiao-yu, MA Jian-xin. Combustion catalyst for methanol fuel processor[J]. Acta Energiae Solaris Sinica, 2006, 27(8): 841-845.)
-
[11]
[11] HU Z, BOIADJIEV V, THUNDAT T. Nanocatalytic spontaneous ignition and self-supporting room-temperature combustion[J]. Energy Fuels, 2005, 19(3): 855-858.
-
[12]
[12] YANG P, LEE H, HABAS S E, KWESKIN S, BUTCHER D, SOMORJAI G A. Morphological control of catalytically active platinum nanocrystals[J]. Angew Chem Int Ed, 2006, 45(46): 7824-7828.
-
[13]
[13] YANG W, WANG X, YANG F,YANG C, YANG X. Carbon nanotubes decorated with Pt nanocubes by a noncovalent functionalization method and their role in oxygen reduction[J]. Adv Mater, 2008, 20(13): 2579-2587.
-
[14]
[14] HU X, WANG T, DONG S. Rapid synthesis of cubic Pt nanoparticles and their use for the preparation of Pt nanoagglomerates[J]. J Nanosci Nanotechnol, 2006, 6(7): 2056-2061.
-
[15]
[15] LIN C-S, KHAN M R, LIN S D. The preparation of Pt nanoparticles by methanol and citrate[J]. J Colloid Interface Sci, 2006, 299(2): 678-685.
-
[16]
[16] LI X, YOU X, YING P, XIAO J, LI C. Some insights into the preparation of Pt/γ-Al2O3 catalysts for the enantioselective hydrogenation of α-ketoesters[J]. Top Catal, 2003, 25(1/4): 63-70.
-
[1]
-
-
-
[1]
Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO3 for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
-
[2]
Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO2 Hydrogenation by Decoration of K on MoS2 Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
-
[3]
Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, 2024, 39(6): 342-349. doi: 10.3866/PKU.DXHX202311070
-
[4]
Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
-
[5]
Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
-
[6]
Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
-
[7]
Wanmin Cheng , Juan Du , Peiwen Liu , Yiyun Jiang , Hong Jiang . Photoinitiated Grignard Reagent Synthesis and Experimental Improvement in Triphenylmethanol Preparation. University Chemistry, 2024, 39(5): 238-242. doi: 10.3866/PKU.DXHX202311066
-
[8]
Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
-
[9]
Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
-
[10]
Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
-
[11]
Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Research on Cu-Based and Pt-Based Catalysts for Hydrogen Production through Methanol Steam Reforming. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-0. doi: 10.1016/j.actphy.2025.100049
-
[12]
Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
-
[13]
Feng Han , Fuxian Wan , Ying Li , Congcong Zhang , Yuanhong Zhang , Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181
-
[14]
Jian Jin , Jing Cheng , Xueping Yang . Integration Practice of Organic Chemistry Experiment and Safety Education: Taking the Synthesis of Triphenylmethanol as an Example. University Chemistry, 2024, 39(3): 345-350. doi: 10.3866/PKU.DXHX202309010
-
[15]
Jiageng Li , Putrama . 数值积分耦合非线性最小二乘法一步确定反应动力学参数. University Chemistry, 2025, 40(6): 364-370. doi: 10.12461/PKU.DXHX202407098
-
[16]
Yuping Wei , Yiting Wang , Jialiang Jiang , Jinxuan Deng , Hong Zhang , Xiaofei Ma , Junjie Li . Interdisciplinary Teaching Practice——Flexible Wearable Electronic Skin for Low-Temperature Environments. University Chemistry, 2024, 39(10): 261-270. doi: 10.12461/PKU.DXHX202404007
-
[17]
Xiaojun Wu , Kai Hu , Faqiong Zhao . Laying the Groundwork for General Chemistry Experiment Teaching: Exploration and Summary of Assisting Experiment Preparatory Work through Online and Offline Integration. University Chemistry, 2024, 39(8): 23-27. doi: 10.3866/PKU.DXHX202312052
-
[18]
Houzhen Xiao , Mingyu Wang , Yong Liu , Bangsheng Lao , Lingbin Lu , Minghuai Yu . Course Ideological and Political Design of Combustion Heat Measurement Experiment. University Chemistry, 2024, 39(2): 7-13. doi: 10.3866/PKU.DXHX202310011
-
[19]
Ye Wang , Ruixiang Ge , Xiang Liu , Jing Li , Haohong Duan . An Anion Leaching Strategy towards Metal Oxyhydroxides Synthesis for Electrocatalytic Oxidation of Glycerol. Acta Physico-Chimica Sinica, 2024, 40(7): 2307019-0. doi: 10.3866/PKU.WHXB202307019
-
[20]
Shi-Yu Lu , Wenzhao Dou , Jun Zhang , Ling Wang , Chunjie Wu , Huan Yi , Rong Wang , Meng Jin . Amorphous-Crystalline Interfaces Coupling of CrS/CoS2 Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(8): 2308024-0. doi: 10.3866/PKU.WHXB202308024
-
[1]
Metrics
- PDF Downloads(0)
- Abstract views(1192)
- HTML views(256)