Citation: WANG Bao-wei, SHANG Yu-guang, DING Guo-zhong, WANG Hai-yang, WANG Er-dong, LI Zhen-hua, MA Xin-bing, QIN Shao-dong, SUN Qi. Ceria-alumina composite support on the sulfur-resistant methanation activity of Mo-based catalyst[J]. Journal of Fuel Chemistry and Technology, ;2012, 40(11): 1390-1396. shu

Ceria-alumina composite support on the sulfur-resistant methanation activity of Mo-based catalyst

1.
1. Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;

Corresponding author: MA Xin-bing,
Received Date: 6 March 2012
Available Online: 25 June 2012

Ceria-alumina composite supports were prepared by co-precipitation, impregnation and deposition-precipitation method, respectively. Co-Mo catalysts supported on the composite supports were evaluated for sulfur-resistant methanation and the appropriate content of CeO₂ in the composite support was further studied. All the samples were characterized by nitrogen adsorption, X-ray diffraction (XRD) and hydrogen temperature-programmed reduction (H₂-TPR). It was found that addition of CeO₂ to Al₂O₃ significantly increased the activity of methanation and 25% CeO₂-Al₂O₃ prepared by deposition-precipitation method had the best sulfur-resistant methanation activity.
- ceria,
- alumina,
- composite support,
- Co-Mo catalyst,
- sulfur-resistant methanation
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