Citation: SONG Hua, SONG Hua-lin, CUI Xue-han, ZHANG Xu. Effect of Pd content on the catalytic performance of SO₄^2-/ZrO₂-WO₃ solid superacid in pentane isomerization[J]. Journal of Fuel Chemistry and Technology, ;2012, 40(11): 1346-1352. shu

Effect of Pd content on the catalytic performance of SO₄^2-/ZrO₂-WO₃ solid superacid in pentane isomerization

SONG Hua ^1,2,, ,
SONG Hua-lin ^3,, ,
CUI Xue-han ¹ ,
ZHANG Xu ¹

1.
1. College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China;

Corresponding author: SONG Hua, SONG Hua-lin,
Received Date: 20 April 2012
Available Online: 5 July 2012
Fund Project: 中国石油天然气股份有限公司科技风险创新基金(07-06D-01-04-03-02)。 (07-06D-01-04-03-02)

Pd-SO₄^2-/ZrO₂-WO₃ solid superacid catalysts were prepared and characterized by XRD, FT-IR, TPR, XPS, BET and TG-DTA; the effect of Pd content on its catalytic performance in n-pentane isomerization was investigated. The results showed that Pd can reduce the reduction temperature, increase the decomposition temperature of SO₄^2- and therefore improve the thermostability of the Pd-SO₄^2-/ZrO₂-WO₃ catalysts. Pd-SO₄^2-/ZrO₂-WO₃ with a Pd mass fraction of 0.05% exhibits the highest catalytic activity for isomerization; over it under 260℃, 2.0 MPa, mass hourly space velocity of 1.0 h^-1, and H₂/n-pentane molar ration of 4.0, the conversion of n-pentane and the yield of liquid products are 40.1% and 93.9%, respectively.
- solid superacid,
- catalyst,
- ZrO₂-WO₃,
- palladium,
- pentane,
- isomerization
1. [1]
  [1] TIAN G, XU Y, XU Z, TIAN Z, LIN L. Effect of aluminum on the mechanical stress stability of WOx/ZrO₂ superacid[J]. Chinese Journal of Catalysis, 2008, 29(5): 415-417.
2. [2]
  [2] LAOSIRIPOJANA N, KIATKITTIPONG W, SUTTHISRIPOK W, ASSABUMRUNGRAT S. Synthesis of methyl esters from relevant palm products in near-critical methanol with modified-zirconia catalysts[J]. Bioresour Technol, 2010, 101(21): 8416-8423.
3. [3]
  [3] SHU Q, ZHANG Q, XU G, NAWAZ Z, WANG D, WANG J. Synthesis of biodiesel from cottonseed oil and methanol using a carbonbased solid acid catalyst[J]. Fuel Process Technol, 2009, 90(7/8): 1002-1008.
4. [4]
  [4] 吴燕妮, 郭海福, 崔秀兰, 舒华. Sm₂O₃改性对S₂O₈^2-/ZrO₂-SiO₂固体超强酸催化剂性能的影响[J]. 化学研究与应用, 2005, 17(3): 400-402. (WU Yan-ni, GUO Hai-fu, CUI Xiu-lan, SHU Hua. Effect of the Sm₂O₃ on the performance of solid superacid S₂O₈^2-/ZrO₂-SiO₂[J]. Chemical Research and Application, 2005, 17(3): 400-402.)
5. [5]
  [5] 宋华, 董鹏飞, 张旭. Al含量对Pt-SO₄^2-/ZrO₂-Al₂O₃固体超强酸催化正戊烷异构化性能的影响[J]. 物理化学学报, 2010, 26(8): 2229-2234. (SONG Hua, DONG Peng-fei, ZHANG Xu. Effect of Al content on the n-pentane isomerization of the solid superacid Pt-SO₄^2-/ZrO₂-Al₂O₃[J]. Acta Physico-Chimica Sinica, 2010, 26(8): 2229-2234.)
6. [6]
  [6] 宋华, 董鹏飞, 张旭. Al含量对Pt-S₂O₈^2-/ZrO₂-Al₂O₃固体超强酸催化剂异构化性能的影响[J]. 高等学校化学学报, 2010, 31(7): 1426-1430. (SONG Hua, DONG Peng-fei, ZHANG Xu. Effect of Al contents on the isomerization performance of solid superacid Pt-S₂O₈^2-/ZrO₂-Al₂O₃[J]. Chemical Research in Chinese Universities, 2010, 31(7): 1426-1430.)
7. [7]
  [7] 宋华, 董鹏飞, 石洋. Pt含量及活化温度对固体超强酸催化剂异构化性能的影响[J]. 高等学校化学学报, 2011, 32(2): 355-360. (SONG Hua, DONG Peng-fei, SHI Yang. Effects of Pt contents and activation temperature on the isomerization performance over solid superacid Pt-S₂O₈^2-/ZrO₂-Al₂O₃[J]. Chemical Research in Chinese Universities, 2011, 32(2): 355-360.)
8. [8]
  [8] 宋华, 张旭, 梁宝兴. W含量对固体超强酸催化剂Pd-SO₄^2-/ZrO₂-WO₃异构化性能的影响[J]. 燃料化学学报, 2012, 40(4):487-493 (SONG Hua, ZHANG Xu, LIANG Bao-xing. Effect of W contents on the isomerization performance of solid superacid Pd-SO₄^2-/ZrO₂-WO₃ [J]. Journal of Fuel Chemistry and Technology, 2012, 40(4): 487-493.)
9. [9]
  [9] KLOSE B S, JENTOFT R E., HAHN A, RESSLER T, KRÖHNERTJ, WRABETZ S, YANG X, JENTOFT F C. Mechanical stress induced activity and phase composition changes in sulfated zirconia catalysts[J]. J Catal, 2003, 217(2): 487-490.
10. [10]
  [10] 井立强, 蔡伟民, 孙晓君, 侯海鸽, 徐自力, 杜尧国. Pd/ZnO和Ag/ZnO复合纳米粒子的制备、表征及光催化活性[J]. 催化学报, 2002, 23(4): 336-340. (JING Li-qiang, CAI Wei-min, SUN Xiao-jun, HOU Hai-ge, XU Zi-li, DU Yao-guo. Preparatian and characterization of Pd/ZnO and Ag/ZnO composite nanoparticles and their photocatalytic activity[J]. Chinese Journal of Catalysis, 2002, 23(4): 336-340.)
11. [11]
  [11] GUO H-F, YAN P, HAO X-Y, WANG Z-Z. Influences of introducing Al on the solid super acid SO₄^2-/SnO₂[J]. Mater Chem Phys, 2008, 112(3): 1065-1068.
12. [12]
  [12] VIJAY S, WOLF E E, MILLER J T, KROPF A J. A highly active and stable platinum-modified sulfated zirconia catalyst: Part 2. EXAFS studies of the effect of pretreatment on the state of platinum[J]. Appl Catal A, 2004, 264(1): 125-130.
13. [13]
  [13] PORTER J, DEERE D, PICKUP R. Fluorescent probes and flow cytometry: New insights into environmental bacteriology[J]. Cytometry, 1996, 23(2): 91-96.
14. [14]
  [14] FERRER V, MORONTA A, SÁNCHEZ J, SOLANO R, BERNAL S, FINOLA D. Effect of the reduction temperature on the catalytic activity of Pd-supported catalysts[J]. Catal Today, 2005, 107~108(1): 487-492.
15. [15]
  [15] 俞铁铭, 周仁贤, 唐中民, 郑小明. 微量铂、钯对Cr/ZrO₂催化剂结构与性能的影响[J]. 石油化工, 1999, 28(7): 449-451. (YU Tie-ming, ZHOU Ren-xian, TANG Zhong-min, ZHENG Xiao-ming. Effects of platinum or palladium on structure and properties of Cr/ZrO₂ catalyst[J]. Petrochemical Technology, 1999, 28(7): 449-451.)
16. [16]
  [16] 郑小明, 吕伯升, 洪情美, 金唯军. Pt/HM, Pd/HM催化剂上CO氧化反应活性和动力学研究[J]. 高等学校化学学报,1991, 12(3): 381-385. (ZHENG Xiao-ming, LV Sheng-bo, HONG Qing-mei, JIN Wei-jun. Activity and kinctics study on Pt/HM, Pd/HM catalysts for oxidation of CO[J]. Chemical Reaserch in Chinese Universities, 1991, 12(3): 381-385.)
17. [17]
  [17] 郑小明, 顾越鹏, 金松寿. Pt/HM和Pd/HM催化剂表面氧的恢复与供出活化能测定[J]. 物理化学学报, 1991, 7(1): 125-128 (ZHENG Xiao-ming, GU Yue-peng, JIN Song-shou. Measurement of the activation energy of oxygen offering and reproducing on Pt/HM, Pd/HM Catalysts[J]. Acta Physico-Chimica Sinica, 1991, 7(1): 125-128.)
18. [18]
  [18] 周仁贤, 周烈华, 朱波, 郑小明. 掺杂对Pd/Al₂O₃催化剂物相结构及表面氧性质的影响[J]. 物理化学学报, 1995, 11(1): 20-25. (ZHOU Ren-xian, ZHOU Lie-hua, ZHU Bo, ZHENG Xiao-ming. Effect of ZrO₂on support structure and surface oxygen property of Pd/Al₂O₃[J]. Acta Physico-Chimica Sinica, 1995, 11(1): 20-25.)
19. [19]
  [19] 丁春黎, 朱永娟, 顾薇. 对浸渍法制备Pd/C催化剂表面积影响因素的讨论[J]. 吉林工学院学报, 2001, 22(1): 4-6. (DING Chun-li, ZHU Yong-juan, GU Wei. A discussion on the influence of surface area of the Pd/C catalyst prepared by soaking method[J]. Journal of Jilin Institute of Technology, 2001, 22(1): 4-6.)
20. [20]
  [20] 祁伟. Pd/Al₂O₃催化剂的合成和表征[J]. 德州学院学报, 2007, 23(6): 49-51. (QI Wei. The synthesis and characterization of catalysts Pd/Al₂O₃[J]. Journal of Dezhou University, 2007, 23(6): 49-51.)
21. [21]
  [21] 黄宁康. 离子束轰击的ZrO₂-8wt%Y₂O₃薄膜的XPS分析[J]. 功能材料, 1992, 23(2): 121-128. (HUANG Ning-kang. XPS investigation of ZrO₂-8wt%Y₂O₃ film bombard with ion beam[J]. Journal of Functional Materials, 1992, 23(2): 121-128.)
22. [22]
  [22] 熊玉华, 顾为, 尉秀英, 苑鹏, 秦光荣. ZrVFe吸气剂激活过程及其机理[J]. 中国有色金属学报, 2008, 18(7): 1358-1363. (XIONG Yu-hua, GU Wei, WEI Xiu-ying, YUAN Peng, QIN Guang-rong. Activation process and mechanism of ZrVFe getter[J]. The Chinese Journal of Nonferrous Metals, 2008, 18(7): 1358-1363.)
23. [23]
  [23] CHEN X-R, DU Y-Q, CHEN C-L, XU N-P, MOU C-Y. Highly active and stable n-pentane isomerization catalystswithout noble metal containing:Al-or Ga-Promoted tungstated zirconia[J]. Catal Lett,2006,111(3): 187-193.
24. [24]
  [24] 战瑞瑞, 张荣昌. 稀土改性纳米固体超强酸SO₄^2-/ Fe₂O₃-CeO₂-SiO₂催化剂的研究[J]. 东北师大学报(自然科学版), 2008, 40(3): 80-83. (ZHAN Rui-rui, ZHANG Rong-chang. Research of nanosolid superacid catalyst of rare earth modified SO₄^2-/Fe₂O₃-CeO₂-SiO₂[J]. Journal of Northeast Normal University Natural Sciencr Edition, 2008, 40(3): 80-83.)
25. [25]
  [25] BELANDRIA L, MARIN-ASTORGAL N, GARCIA E, SOSA E, AGUIRRE F, VILLARROELl M, UZCATEGUI A, IMBERT F. Catalytic activity of Pt and Pd catalysts supported on HWP/HMS in the selective[J]. Catal Today, 2011, 172(1): 2-7.
26. [26]
  [26] 王刚, 刘全杰, 贾立明, 徐会青, 韩崇仁, 李灿. 负载Pd的分子筛催化剂上烷烃的异构化反应[J]. 石油化工, 2006, 35(5): 420-424. (WANG Gang, LIU Quan-jie, JIA Li-ming, XU Hui-qing, HAN Chong-ren, LI Can. Isomerization of alkane on molecular sieves catalyst loaded with palladium[J]. Petrochemical Technology, 2006, 35(5): 420-424.)
1. [1]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
2. [2]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
3. [3]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
4. [4]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
5. [5]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
6. [6]
  Yongwei ZHANG , Chuang ZHU , Wenbin WU , Yongyong MA , Heng YANG . Efficient hydrogen evolution reaction activity induced by ZnSe@nitrogen doped porous carbon heterojunction. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 650-660. doi: 10.11862/CJIC.20240386
7. [7]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
8. [8]
  Haoyu Sun , Dun Li , Yuanyuan Min , Yingying Wang , Yanyun Ma , Yiqun Zheng , Hongwen Huang . Hierarchical Palladium-Copper-Silver Porous Nanoflowers as Efficient Electrocatalysts for CO₂ Reduction to C₂₊ Products. Acta Physico-Chimica Sinica, 2024, 40(6): 2307007-0. doi: 10.3866/PKU.WHXB202307007
9. [9]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
10. [10]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
11. [11]
  Dong Xiang , Kunzhen Li , Kanghua Miao , Ran Long , Yujie Xiong , Xiongwu Kang . Amine-Functionalized Copper Catalysts: Hydrogen Bonding Mediated Electrochemical CO₂ Reduction to C₂ Products and Superior Rechargeable Zn-CO₂ Battery Performance. Acta Physico-Chimica Sinica, 2024, 40(8): 2308027-0. doi: 10.3866/PKU.WHXB202308027
12. [12]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
13. [13]
  Xueting Feng , Ziang Shang , Rong Qin , Yunhu Han . Advances in Single-Atom Catalysts for Electrocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2305005-0. doi: 10.3866/PKU.WHXB202305005
14. [14]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
15. [15]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
16. [16]
  Jun LI , Huipeng LI , Hua ZHAO , Qinlong LIU . Preparation and photocatalytic performance of AgNi bimetallic modified polyhedral bismuth vanadate. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 601-612. doi: 10.11862/CJIC.20230401
17. [17]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
18. [18]
  Wen YANG , Didi WANG , Ziyi HUANG , Yaping ZHOU , Yanyan FENG . La promoted hydrotalcite derived Ni-based catalysts: In situ preparation and CO₂ methanation performance. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 561-570. doi: 10.11862/CJIC.20230276
19. [19]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
20. [20]
  Qing Li , Guangxun Zhang , Yuxia Xu , Yangyang Sun , Huan Pang . P-Regulated Hierarchical Structure Ni₂P Assemblies toward Efficient Electrochemical Urea Oxidation. Acta Physico-Chimica Sinica, 2024, 40(9): 2308045-0. doi: 10.3866/PKU.WHXB202308045

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(615)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Pd content on the catalytic performance of SO42-/ZrO2-WO3 solid superacid in pentane isomerization

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Pd content on the catalytic performance of SO₄^2-/ZrO₂-WO₃ solid superacid in pentane isomerization