Citation: ZHOU Jie, ZHAO Ning, XIAO Fu-kui, WEI Wei, SUN Yu-han. Selective oxidation of glycerol over Bi-Pt catalyst on H-mordenite[J]. Journal of Fuel Chemistry and Technology, ;2012, 40(11): 1323-1327. shu

Selective oxidation of glycerol over Bi-Pt catalyst on H-mordenite

ZHOU Jie ^1,2 ,
ZHAO Ning ¹ ,
XIAO Fu-kui ¹ ,
WEI Wei ^1,, ,
SUN Yu-han ^1,3

1.
1. Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;

Corresponding author: WEI Wei,
Received Date: 31 March 2012
Available Online: 1 June 2012

Selective oxidation of glycerol (GLY) to dihydroxyacetone (DHA) was studied over Bi-Pt/H-mordenite catalyst. The results indicated that the surface area has little effect on the performance of the supported catalysts. H-mordenite as support inhibits the cracking of GLY and thus promotes the selectivity to DHA. Protic solvents such as ethanol and water favor the formation of DNA from GLY. Over the Bi-Pt/H-mordenite catalyst of optimum composition (1% Bi and 5% Pt by weight) and under the optimum reaction conditions (353 K, reaction time of 2~4 h, air flow rate of 20 mL/min, and GLY concentration of 10%), the conversion of GLY and selectivity to DHA reach 70.6% and 61.0%, respectively.
- glycerol,
- selective oxidation,
- Bi-Pt/H-mordenite,
- dihydroxyacetone
1. [1]
  [1] 闵恩泽. 绿色化学技术[M]. 南昌: 江西科学技术出版社, 2001:1-28. (MIN En-ze. Green chemistry technology[M]. Nanchang: Jiangxi Science ＆ Technology Press, 2001: 1-28.)
2. [2]
  [2] 闵恩泽. 利用可再生油料资源发展生物炼油化工厂[J]. 化工学报, 2006, 57(8):1739-1745. (MIN En-ze. Developing bio-refinary by utilizing renewable vegetable oils[J]. Journal of Chemical Industry and Engneering(China), 2006, 57(8): 1739-1745.)
3. [3]
  [3] 王庆昭, 郑宗宝, 刘子鹤, 赵学明. 生物炼制工业过程及产品[J]. 化学进展, 2007, 19(7/8):1198-1205. (WANG Qing-zhao, ZHENG Zong-bao, LIU Zi-he, ZHAO Xue-ming. The industrial processes and products of biorefineries[J]. Progress in Chemistry, 2007, 19(7/8): 1198-1205.)
4. [4]
  [4] 伍丹, 施永聪, 龙正松, 陈智慧, 龚文智, 李兵, 张俊, 陈锐, 施丽华. 可再生的绿色能源—生物柴油[J]. 贵州化工, 2007, 32(2):16-19. (WU Dan, SHI Yong-cong, LONG Zheng-song, CHEN Zhi-hui, GONG Wen-zhi, LI Bing, ZHANG Jun, CHEN Rui, SHI Li-hua. Renewable green chemistry-biodesiesel[J]. Guizhou Chemical Industry, 2007, 32(2):16-19.)
5. [5]
  [5] 何延青, 吴永强, 闻建平. 生物柴油生产及其副产物甘油的有效利用[J]. 中国油脂, 2007, 32(5): 47-51. (HE Yan-qing, WU Yong-qiang, WEN Jian-ping. Production of biodesiesel and effective utilization of the by-product glycerol[J]. China Oils and Fats, 2007, 32(5): 47-51.)
6. [6]
  [6] SUPPES G J, DASARI M A, DOSKOCIL E J, MANKIDY P J, GOFF M J. Transesterification of soybean oil with zeolite and metal catalysts[J]. Appl Catal A, 2004, 257(2): 213-223.
7. [7]
  [7] YAZDANI S S, CONZALEZS R. Anaerobic fermentation of glycerol: A path to economic viability for the biofuels industry[J]. Curr Opin Biotech, 2007, 18(3): 213-219.
8. [8]
  [8] MANUEL S. 1,3-Dihydroxyacetone as an oxygen scavenger for water: US, 4363734. 1982-12-14.
9. [9]
  [9] WITTGENSTEIN E, BERRY H K. Staining of skin with dihydroxyacetone[J]. Science, 1960, 132(3431): 894–895.
10. [10]
  [10] CORMA A, IBORRA S, VELTY A. Chemical routes for the transformation of biomass into chemicals[J]. Chem Rev, 2007, 107(6): 2411-2502.
11. [11]
  [11] KATRYNIOK B, KIMURA H, SKRZYSKA E, GIRARDON J S, FONGARLAND P, CAPRON M, DUCOULOMBIER R, MIMURA N, PAUL S, DUMEIGNIL F. Selective catalytic oxidation[J]. Green Chem, 2011, 13(8): 1960-1979.
12. [12]
  [12] NAMIKI M. Chemistry of Maillard reactions. Adv Food Res, 1988, 32: 115-184.
13. [13]
  [13] KIMURA H, TSUTO K. Selective oxidation of glycerol on a platinum-bismuth catalyst[J]. Appl Cata A, 1993, 96(2): 217-228.
14. [14]
  [14] KIMURA H. Selective oxidation of glycerol on a platinum-bismuth catalyst by using a fixed bed reactor[J]. Appl Catal A, 1993, 105(2): 147-158.
15. [15]
  [15] CLAUS P, DEMIREL-GVLEN S, LUCAS M, LEHNERT K. Verfahren zur selektiven herstellung von dihydroxyaceton aus glycerin sowie ein verfahren zur herstellung eines metallkatalysators zur selektiven oxidation von glycerin: DE, 102005044913. 2007-03-22.
16. [16]
  [16] DIMITRATOS N, LEHNERT K, LUCAS M, CLAUS P. Use of renewables for the production of chemicals: Glycerol oxidation over carbon supported gold catalysts[J]. Appl Catal B, 2007, 70(1/4): 637-643.
17. [17]
  [17] KIMURA H, TSUTO K. Process for producing compound having carbonyl and/or carboxyl group: US, 5274187 (A). 1993-12-28.
18. [18]
  [18] KIMURA H. Oxidation assisted new reaction of glycerol[J]. Poly Adv Tech, 2001, 12(11/12): 697-710.
19. [19]
  [19] GARCIA R, BESSON M, GALLEZOT P. Chemoselective catalytic oxidation of glycerol with air on platinum metals[J]. Appl Catal A,1995, 127(1/2): 165-176.
20. [20]
  [20] HU W, KNIGHT D, LOWRY B, VARMA A. Selective oxidation of glycerol to dihydroxyacetone over Pt-Bi/C catalyst: Optimization of catalyst and reaction conditions[J]. Ind Eng Chem Res, 2010, 49(21): 10876-10882.
21. [21]
  [21] BRANDNER A, LEHNERT K, BIENHOLZ A, LUCAS M, CLAUS P. Production of biomass-derived chemicals and energy: Chemocatalytic conversions of glycerol[J]. Top Catal, 2009, 52(3): 278-287.
22. [22]
  [22] CIRIMINNA R, PALMISANO G, PINAC D. One-pot electroactalytic oxidation of glycerol to DHA[J]. Tetrahedron Lett, 2006, 47(39): 6993-6995.
23. [23]
  [23] LIANG D, GAO J, WANG J, CHEN P, WEI Y, HOU Z. Bimetallic Pt-Cu catalysts for glycerol oxidation with oxygen in a base-free aqueous solution[J]. Catal Commun, 2011, 12(12): 1059-1062.
24. [24]
  [24] 梁丹, 崔世玉, 高静, 王军华, 陈平, 侯昭胤. 常压下 Pt-Bi 双金属催化剂上甘油选择性氧化[J]. 催化学报, 2011, 32(12):1831-1837. (LIANG Dan, CUI Shi-yu, GAO Jing, WANG Jun-hua, CHEN Ping, HOU Zhao-yin. Glycerol oxidation with oxygen over bimetallic Pt-Bi catalysts under atmospheric pressure[J]. Chinese Journal of Catalysis, 2011, 32(12): 1831-1837.)
25. [25]
  [25] ABBADI A, BEKKUM H. Selective chemo-catalytic routes for the preparation of β-hydroxypyruvic acid[J]. Appl Catal A, 1996, 148(2): 113-122.
26. [26]
  [26] 谢艳丽, 赵振东, 白洋, 刘艳凤. 含铂多金属催化剂的合成及其对甘油选择性催化氧化作用的研究[J]. 海南师范大学学报(自然科学版), 2007,20(3): 251-255, 288. (XIE Yan-li, ZHAO Zhen-dong, LIU Yan-feng. Sdudies on the synthesis of PtM/C muti-metallic bimetallic catalysts and their catalytic properties on the selective oxidation of glycerol[J]. Journal of Hainan Normal University (Natural Science), 2007, 20(3): 251-255, 288.)
27. [27]
  [27] MALLAT T, BODNAR Z, HUG P, BAIKER A. Selective oxidation of cinnamyl alcohol to cinnamaldehyde with air over Bi-Pt/alumina catalysts[J]. J Catal, 1995, 153(1): 131-143.
28. [28]
  [28] FORDHAM P, BESSON M, GALLEZOT P. Catalytic oxidation with air of tartronic acid to mesoxalic acid on bismuth-promoted platinum[J]. Catal Lett, 1997, 46(3/4): 195-199.
29. [29]
  [29] VILLA A, BEITH G M, PRATI L. Selective oxidation of glycerol under acidic conditions using gold catalysts[J]. Angew Chem Int Edit, 2010, 49(26): 4499-4502.
30. [30]
  [30] NIMLOS M R, BLANKBY S J, QIAN X H, HIMMEL M E, JOHNSON D K. Mechanisms of glycerol dehydration[J]. J Phys Chem A, 2006, 110(18): 6145-6156.
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