Citation: ZHANG Yi, CHEN Deng-yu, ZHANG Dong, ZHU Xi-feng. TG-FTIR analysis of bio-oil and its pyrolysis/gasification property[J]. Journal of Fuel Chemistry and Technology, ;2012, 40(10): 1194-1199. shu

TG-FTIR analysis of bio-oil and its pyrolysis/gasification property

1.
Anhui Province Key Laboratory of Biomass Clean Energy,University of Science and Technology of China, Hefei 230026, China

Corresponding author: ZHU Xi-feng,
Received Date: 17 March 2012
Available Online: 4 June 2012
Fund Project: 国家高技术研究发展计划(863计划, 2012AA051803) (863计划, 2012AA051803) 国家自然科学基金(50930006) (50930006) 国家科技支撑计划(2011BAD22B07)。 (2011BAD22B07)

The process of bio-oil pyrolysis/gasification and gas evolution characteristic was studied using a thermogravimetric analyzer coupled with Fourier transform infrared spectroscopy (TG-FTIR). Pyrolysis/gasification of bio-oil and its fractions were also performed in a fixed bed. As a result, the process of bio-oil pyrolysis/gasification can be divided into two stages. The first is volatilization and pyrolysis of the light compounds at low temperature and the second is cracking and polymerization of the heavy compounds at high temperature. The values of activation energy are 35~38 kJ/mol in the first stage and 15~22 kJ/mol in the second stage, respectively. With temperature increasing, the conversation of pyrolysis/gasification grows higher and the yield of synthesis gas (syngas) increases. However, the calorific value of the gas has an inverse correlation with the temperature. In comparison, the light fraction (LF) makes more contribution to the overall H₂ release; while CO and CH₄ are mainly generated from the heavy fraction (HF).
- bio-oil,
- pyrolysis/gasification,
- light fraction,
- heavy fraction
1. [1]
  [1] JONATHAN R M, JOELLE D B, SHANNON M K, ROBERT J E. Non-catalytic partial oxidation of bio-oil to synthesis gas for distributed hydrogen production[J]. Int J Hydrogen Energy, 2009, 34(20): 8519-8534.
2. [2]
  [2] PANIGRAHI S, CHAUDHAIR S T, BAKHSHI N N, DALAI A K. Production of synthesis gas/high-Btu gaseous fuel from pyrolysis of biomass-derived oil[J]. Energy Fuels, 2002, 16(6): 1392-1397.
3. [3]
  [3] 朱锡锋, VENDERBOSCH R H. 生物质热解油气化试验研究[J]. 燃料化学学报, 2004, 32(4): 510-512. (ZHU Xi-feng, VENDERBOSCH R H. Experimental research on gasification of bio-oil derived from biomass pyrolysis[J]. Journal of Fuel Chemistry and Technology, 2004, 32(4): 510-512.)
4. [4]
  [4] 刘承运, 陆强, 孙书生, 张栋, 朱锡锋. 稻壳生物油的燃烧及污染物排放特性研究[J]. 燃料化学学报, 2008, 36(5): 577-582. (LIU Chen-yun, LU Qiang, SUN Shu-sheng, ZHANG Dong, ZHU Xi-feng. Research on rice husk bio-oil combustion and pollutant emissions[J]. Journal of Fuel Chemistry and Technology, 2008, 36(5): 577-582.)
5. [5]
  [5] 陈登宇, 朱锡锋. 生物质热反应机理与活化能确定方法: Ⅰ干燥段研究[J]. 燃料化学学报, 2011, 39(8): 580-584. (CHEN Deng-yu, ZHU Xi-feng. Thermal reaction mechanism of biomass and determination of activation energy: I Drying section[J]. Journal of Fuel Chemistry and Technology, 2011, 39(8): 580-584.)
6. [6]
  [6] 胡荣祖. 热分析动力学[M]. 2版. 北京: 科学出版社, 2007. (HU Rong-zu. Thermal kinetics analysis [M]. 2nd ed. Beijing: Science Press, 2007.)
7. [7]
  [7] 汪从伟, 阴秀丽, 吴创之, 马隆龙. 生物油及其重质组分的热解动力学研究[J]. 工程热物理学报, 2009, 30(10): 1783-1786. ( WANG Cong-wei, YIN Xiu-li, WU Chuang-zhi, MA Lu-long. Kinetics of pyrolysis of bio-oil and its heavy fractions [J]. Journal of Engineering Thermophysics, 2009, 30(10): 1783-1786.)
8. [8]
  [8] FU P, HU S, XIANG J, SUN L S, YANG T, ZHANG A C, ZHANG J Y. Mechanism study of rice straw pyrolysis by Fourier Transform Infrared Technique[J]. Chin J Chem Eng, 2009, 17(3): 522-529.
9. [9]
  [9] GUO X J, WANG S R, WANG Q, GUO Z G, LUO Z Y. Properties of bio-oil from fast pyrolysis of rice husk[J]. Chin J Chem Eng, 2010, 19(1): 116-121.
10. [10]
  [10] 付鹏, 胡松, 孙路石, 向军, 陈巧巧, 杨涛, 张军营. 稻草和玉米秆热解气体产物的释放特性及形成机理[J]. 中国电机工程学报, 2009, 29(2): 113-118. (FU Peng, HU Song, SUN Lu-shi, XIANG Jun, CHEN Qiao-qiao, YANG Tao, ZHANG Jun-ying. Release characteristics and formation mechanism of gas products during rice straw and maize stalk pyrolysis[J]. Proceedings of the CSEE, 2009, 29(2): 113-118.)
11. [11]
  [11] 王贤华, 贺瑞雪, 杨海平, 张世红, 陈汉平. 生物油热解气化的TG-FTIR分析[J]. 太阳能学报, 2010, 34(5): 545-549. (WANG Xian-hua, HE Rui-xue, YANG Hai-ping, ZHANG Shi-hong, CHEN Han-ping. TG-FTIR analysis of bio-oil pyrolysis/gasification[J]. Acta Energiae Solaris Sinica, 2010, 34(5): 545-549.)
12. [12]
  [12] BIMBELA F, OLIVA M, RUIZ J, GARCIA L, ARAUZO J. Steam reforming of bio-oil aqueous fractions for syngas production and energy[J]. Environ Eng Sci, 2011, 28(11): 757-763.
13. [13]
  [13] GUO X J, WANG S R, GUO Z G, LIU Q, LUO Z Y, CEN K F. Pyrolysis characteristics of bio-oil fractions separated by molecular distillation[J]. Appl Energy, 2010, 87(9): 2892-2898.
14. [14]
  [14] YANG H P, YAN R, CHEN H P, LEE D H, ZHENG C G. Characteristics of hemicellulose, cellulose and lignin pyrolysis[J]. Fuel, 2007, 86(12/13): 1781-1788.
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