Citation: Yi-Lin Wu, Yong-Sheng Yan, Jian-Ming Pan, Xiao-Hui Dai, Wei-Dong Shi, Min-Jia Meng. Fabrication and evaluation of molecularly imprinted regenerated cellulose composite membranes via atom transfer radical polymerization[J]. Chinese Chemical Letters, ;2014, 25(2): 273-278. shu

Fabrication and evaluation of molecularly imprinted regenerated cellulose composite membranes via atom transfer radical polymerization

1.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China

Corresponding author: Yong-Sheng Yan,
Received Date: 11 October 2013
Available Online: 1 November 2013
Fund Project: This work was financially supported by the National Natural Science Foundation of China (Nos. 21077046, 21107037, 21176107, 21174057, 2100403, 21207051) (Nos. 21077046, 21107037, 21176107, 21174057, 2100403, 21207051) National key basic research development program (973 Program, No. 2012CBB21500) (973 Program, No. 2012CBB21500) Ph.D. Programs Foundation of Ministry of Education of China (No. 20123227120015) (No. 20123227120015)Natural Science Foundation of Jiangsu Province (Nos. BK2011461, SBK2011459, BK2011514). China Postdoctoral Science Foundation funded project (Nos. 2012M511220, 2013M530240). (Nos. BK2011461, SBK2011459, BK2011514)

A simple and effective method for surface molecularly imprinted composite membranes (MICMs) for artemisinin (Ars) based on regenerated cellulose membranes was first prepared through surfaceinitiated atom transfer radical polymerization (ATRP), and the as-prepared MICMs were then evaluated as adsorbents for selective recognition and separation of Ars molecules. Batch rebinding studies were conducted to determine the specific adsorption equilibrium, kinetics and selective permeation performance. The adsorption capacity of MICMs toward Ars by the Langmuir isotherm model was 2.008 mg g^-1, which was nearly 5.0 times higher than non-molecularly imprinted composite membranes (NICMs). The kinetic property of MICMs was well-fitted by the pseudo-second-order rate equation. The selective permeation experiments were successfully investigated to prove the excellent selective permeation performance for Ars than the competitive analog (artemether).
- Molecularly imprinted composite,
- membranes,
- Atom transfer radical polymerization,
- Selective recognition,
- Artemisinin
1. [1]
  [1] A.L. Schilmiller, R.L. Last, E. Pichersky, Harnessing plant trichome biochemistry for the production of useful compounds, Plant J. 54 (2008) 702-711.
2. [2]
  [2] A. Gautam, T. Ahmed, J. Paliwal, V. Batra, Pharmacokinetics and pharmacodynamics of endoperoxide antimalarials, Curr. Drug. Metab. 10 (2009) 289-306.
3. [3]
  [3] J.B. Jiang, G.Q. Li, X.B. Guo, Y.C. Kong, K. Arnold, Antimalarial activity of mefloquine and qinghaosu, Lancet 2 (1982) 285-288.
4. [4]
  [4] E.V. Piletska, K. Karim, M. Cutler, A.P. Sergey, Development of the protocol for purification of artemisinin based on combination of commercial and computationally designed adsorbents, J. Sep. Sci. 36 (2013) 400-406.
5. [5]
  [5] M.N. Maier, W. Lindner, Chiral recognition applications of molecularly imprinted polymers: a critical review, Anal. Bioanal. Chem. 389 (2007) 377-397.
6. [6]
  [6] G. Wulff, Molecular imprinting in cross-linked materials with the aid of molecular templates-a way towards artificial antibodies, Angew. Chem. Int. Ed. 34 (1995) 1812-1832.
7. [7]
  [7] P. Wang, X.F. Fu, J. Li, et al., Preparation of hydrophilic molecularly imprinted polymers for tetracycline antibiotics recognition, Chin. Chem. Lett. 22 (2011) 611-614.
8. [8]
  [8] Y. Wang, T.X. Wei, Surface plasmon resonance sensor chips for the recognition of bovine serum albumin via electropolymerized molecularly imprinted polymers, Chin. Chem. Lett. 24 (2013) 813-816.
9. [9]
  [9] S.A. Piletsky, T.L. Pansyuk, E.V. Piletskaya, I.A. Nichools, M. Ulbricht, Receptor and transport properties of imprinted polymer membranes - a review, J. Membr. Sci. 157 (1999) 263-278.
10. [10]
  [10] M. Ypsjolawa, K. Murakoshi, T. Kogita, et al., Chiral separation membranes from modified polysulfone having myrtenal-derived terpenoid side groups, Eur. Polym. J. 42 (2006) 2532-2539.
11. [11]
  [11] M. Ulbricht, Membrane separations using molecularly imprinted polymers, J. Chromatogr. B 804 (2004) 113-125.
12. [12]
  [12] R. Kiełczyński, M. Bryjak, Molecularly imprinted membranes for cinchona alkaloids separation, Sep. Purif. Technol. 41 (2005) 231-235.
13. [13]
  [13] I. Koyuncu, O.A. Arikan, M.R. Wiesner, C. Rice, Removal of hormones and antibiotics by nanofiltration membranes, J. Membr. Sci. 309 (2008) 94-101.
14. [14]
  [14] C.L. Winson, Y.L. Lay, A.G. Fane, Impacts of salinity on the performance of high retention membrane bioreactors for water reclamation: a review, Water Res. 44 (2010) 21-40.
15. [15]
  [15] M.E. Avramescu, W.F.C. Sager, M.H.V. Mulder, M. Wessling, Preparation of ethylene vinylalcohol copolymer membranes suitable for ligand coupling in affinity separation, J. Membr. Sci. 210 (2002) 155-173.
16. [16]
  [16] W. Albrecht, F. Santoso, K. Lutzow, et al., Preparation of aminated microfiltration membranes by degradable functionalization using plain PEI membranes with various morphologies, J. Membr. Sci. 292 (2007) 145-157.
17. [17]
  [17] S.A. Saufi, C.J. Fee, Fractionation of beta-lactoglobulin from whey by mixed matrix membrane ion exchange chromatography, Biotechnol. Bioeng. 103 (2009) 138- 147.
18. [18]
  [18] G. Yang, L. Zhang, Regenerated cellulose microporous membranes by mixing cellulose cuoxam with a water soluble polymer, J. Membr. Sci. 114 (1996) 149- 155.
19. [19]
  [19] K. Matyjaszewski, J. Xia, Atom transfer radical polymerization, Chem. Rev. 101 (2001) 2921-2990.
20. [20]
  [20] I. Langmuir, The adsorption of gases on plane surfaces of glass, mica and platinum, J. Am. Chem. Soc. 40 (1918) 1361-1403.
21. [21]
  [21] Y.S. Ho, G. McKay, The sorption of lead (Ⅱ) ions on peat, Water Res. 33 (1999) 578- 584.
22. [22]
  [22] Y.S. Ho, G. McKay, Pseudo-second order model for sorption processes, Process Biochem. 34 (1999) 451-465.
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沈阳化工大学材料科学与工程学院沈阳 110142