Citation: Jin-An Zhao, Shu-Fang Chen, Dan-Dan Zhao, Yan Guo, Kun Peng, Ji-Yong Hu. The structure and luminescence properties of three complexes based on bifunctional imidazole-dicarboxylate connector[J]. Chinese Chemical Letters, ;2013, 24(6): 483-486. shu

The structure and luminescence properties of three complexes based on bifunctional imidazole-dicarboxylate connector

1.
a Department of Chemistry and Chemical Engineering, Henan University of Urban Construction, Pingdingshan 467036, China;
2.
b College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052, China

Corresponding author: Jin-An Zhao,
Received Date: 26 January 2013
Available Online: 19 March 2013

To study the diverse coordination modes of the H₂btib, three new coordination architectures, namely, [Ag(Hbtib)CH₃CN]_n (1), [Ag(Hbtib)]_n (2) and [Pb(btib)(CH₃OH)₂]_n (3) (where H₂btib = 4-((2-butyl-5-(2-carboxy-3-(thiophen-2-yl)prop-1-enyl)-1H-imidazol-1-yl)methyl)benzoic acid) have been synthesized and characterized by elemental analysis, IR spectrum and single-crystal X-ray diffraction. Complex 1 exhibits 1D single chain structure, while 2 shows 1D double metal chainmotif, and 3 features a 2D layer topology. Also, 1, 2 and 3 display strong emission band in the solid state at room temperature.
- Imidazole-dicarboxylate connector,
- Crystal structure,
- Photoluminescence property
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沈阳化工大学材料科学与工程学院沈阳 110142