Citation: Liang-Liang Liu, Qin Wang, Dan Xia, Ting-Ting Shen, Ming-Hui Yu, Wei-Sheng Liu, Yu Tang. Intercalation assembly of optical hybrid materials based on layered terbium hydroxide hosts and organic sensitizer anions guests[J]. Chinese Chemical Letters, ;2013, 24(2): 93-95. shu

Intercalation assembly of optical hybrid materials based on layered terbium hydroxide hosts and organic sensitizer anions guests

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Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

Corresponding author: Yu Tang,
Received Date: 23 November 2012
Available Online: 18 December 2012
Fund Project:

Optical hybrid materials based on inorganic hosts and organic sensitizer guests hold promise for a virtually unlimited number of applications. In particular, the interaction and the combination of the properties of a defined inorganic matrix and a specific sensitizer could lead to synergistic effects in luminescence enhancing and tuning. The current article focuses on the intercalation assembly of optical hybrid materials based on the layered terbium hydroxide (LTbH) hosts and organic divalent carboxylic sensitizer anion guests by a hydrothermal process. The studies on the interactions between hosts and guests indicate that the type and arrangement of organic guests in the layer spacing of the LTbH hosts can make a difference in the luminescence of the hybrid inorganic-organic materials.
- Optical hybrid materials,
- Layered terbium hydroxide,
- Organic sensitizer,
- Interaction between host and guest
1. [1]
  [1] D.L. Bish, Anion-exchange in takovite: applications to other hydroxide minerals, Bull. Mineral 103 (1980) 170-175.
2. [2]
  [2] F. Li, Q. Tan, D.G. Evans, X. Duan, Synthesis of carbon nanotubes using a novel catalyst derived from hydrotalcite-like Co-Al layered double hydroxide precursor, Catal. Lett. 99 (2005) 151-156.
3. [3]
  [3] P.C. Pavan, G.D. Gomes, J.B. Valim, Adsorption of sodium dodecyl sulfate on layered double hydroxides, Microporous Mesoporous Mater. 21 (1998) 659-665.
4. [4]
  [4] M. Wei, M. Pu, J. Guo, et al., Intercalation of L-dopa into layered double hydroxides: enhancement of both chemical and stereochemical stabilities of a drug through host-guest interactions, Chem. Mater. 20 (2008) 5169-5180.
5. [5]
  [5] L.J. McIntyre, L.K. Jackson, A.M. Fogg, Ln₂(OH)₅NO₃·xH₂O(Ln = Y, Gd-Lu): a novel family of anion exchange intercalation hosts, Chem. Mater. 20 (2008) 335-340.
6. [6]
  [6] K.H. Lee, S.H. Byeon, Extended members of the layered rare-earth hydroxide family, RE₂(OH)₅NO₃ nH₂O (RE = Sm, Eu, and Gd): synthesis and anion-exchange behavior, Eur. J. Inorg. Chem. 2009 (2009) 929-936.
7. [7]
  [7] K.H. Lee, S.H. Byeon, Synthesis and aqueous colloidal solutions of RE₂(OH)₅-NO₃·nH₂O (RE = Nd and La), Eur. J. Inorg. Chem. 2009 (2009) 4727-4732.
8. [8]
  [8] C. Feldmann, T. Justel, C.R. Ronda, P.J. Schmidt, Inorganic luminescent materials: 100 years of research and application, Adv. Funct. Mater. 13 (2003) 511-516.
9. [9]
  [9] K. Binnemans, Lanthanide-based luminescent hybrid materials, Chem. Rev. 109 (2009) 4283-4374.
10. [10]
  [10] L.D. Carlos, R.A.S. Ferreira, V. de Zea Bermudez, S.J.L. Ribeiro, Lanthanide-containing light-emitting organic-inorganic hybrids: a bet on the future, Adv. Mater. 21 (2009) 509-534.
11. [11]
  [11] F. Geng, R. Ma, T. Sasaki, Anion-exchangeable layered materials based on rareearth phosphors: unique combination of rare-earth host and exchangeable anions, Acc. Chem. Res. 43 (2010) 1177-1185.
12. [12]
  [12] P. Gunawan, R. Xu, Lanthanide-doped layered double hydroxides intercalated with sensitizing anions: efficient energy transfer between host and guest layers, J. Phys. Chem. C 113 (2009) 17206-17214.
13. [13]
  [13] X. Gao, M. Hu, L. Lei, et al., Enhanced luminescence of europium-doped layered double hydroxides intercalated by sensitiser anions, Chem. Commun. 47 (2011) 2104-2106.
14. [14]
  [14] N.K. Chu, Y.H. Sun, Y.S. Zhao, et al., Intercalation of organic sensitisers into layered europium hydroxide and enhanced luminescence property, Dalton Trans. 41 (2012) 7409-7414.
15. [15]
  [15] T.J. Anastasiou, K.E. Uhrich, Novel polyanhydrides with enhanced thermal and solubility properties, Macromolecules 33 (2000) 6217-6221.
16. [16]
  [16] X.G. Huang, Q. Wang, X.H. Yan, et al., Encapsulating a ternary europium complex in a silica/polymer hybrid matrix for high performance luminescence application, J. Phys. Chem. C 115 (2011) 2332-2340.
17. [17]
  [17] E.D. Dimotakis, T.J. Pinnavaia, New route to layered double hydroxides intercalated by organic anions: precursors to polyoxometalate-pillared derivatives, Inorg. Chem. 29 (1990) 2393-2394.
18. [18]
  [18] W. Lu, N.Y. Zhu, C.M. Che, Tethered trinuclear cyclometalated platinum(Ⅱ) complexes: from crystal engineering to tunable emission energy, Chem. Commun. 38 (2002) 900-901.
19. [19]
  [19] G.R. Williams, T.G. Dunbar, A.J. Beer, A.M. Fogg, D. O'Hare, Intercalation chemistry of the novel layered double hydroxides [MAl₄(OH)₁₂](NO₃)₂·yH₂O (M = Zn, Cu Ni and Co). 1 new organic intercalates and reaction mechanisms, J. Mater. Chem. 16 (2006) 1222-1230.
20. [20]
  [20] Z.L. Wang, Z.H. Kang, E.B. Wang, Z.M. Su, L. Xu, Intercalation and photophysical properties of the tetra-(8-hydroxyquinolinato) boron complex and 3,3',4,4'-benzophenone tetracarboxylic anion into Mg-Al layered double hydroxides, Inorg. Chem. 45 (2006) 4364-4371.
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