Ligand-controlled gold catalyzed highly site-selective carbene transfer in C-H bond formation

[1] M.P. Doyle, R. Duffy, M. Ratnikov, L. Zhou, Catalytic carbene insertion into C-H bonds, Chem. Rev. 110 (2010) 704-724.

[2] Y.M. Xi, Y.J. Su, Z.Y. Yu, et al., Chemoselective carbophilic addition of a-diazoesters through ligand-controlled gold catalysis, Angew. Chem. Int. Ed. 53 (2014) 9817-9821.

[3] Z.Z. Yu, B. Ma, J.M. Chen, et al., Highly site-selective direct C-H bond functionalization of phenols with a-aryl-a-diazoacetates and diazooxindoles via gold catalysis, J. Am. Chem. Soc. 136 (2014) 6904-6907.

[4] X.L. Xie, S.F. Zhu, J.X. Guo, Y. Cai, Q.L. Zhou, Enantioselective palladium-catalyzed insertion a-aryl-adiazoacetates into the O-H bonds of phenols, Angew. Chem. Int. Ed. 53 (2014) 2978.

[5] H.M.L. Davies, Q. Jin, Intermolecular C-H activation at benzylic positions: synthesis of (+)-imperanene and (-)-a-conidendrin, Tetrahedron: Asymmetry 14 (2003) 941-949.

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