Citation: ZHAI Xue-jiao, LI Chuang, DI Xin, YIN Dong-dong, LIANG Chang-hai. Preparation of Cu/MgO catalysts for γ-valerolactone hydrogenation to 1, 4-pentanediol by MOCVD[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(5): 537-546. shu

Preparation of Cu/MgO catalysts for γ-valerolactone hydrogenation to 1, 4-pentanediol by MOCVD

Laboratory of Advanced Materials and Catalytic Engineering, School of Petroleum and Chemical Engineering, Dalian University of Technology, Panjin 124221, China

Corresponding author: LIANG Chang-hai, changhai@dlut.edu.cn
Received Date: 15 February 2017
Revised Date: 6 April 2017

Fund Project: the Fundamental Research Funds for the Central Universities DUT15ZD106the National Natural Science Foundation of China 21428301the National Natural Science Foundation of China 21573031Program for Excellent Talents in Dalian City 2016RD09

Figures(10)

The laminar MgO with high specific area and the organometallic precursor Cu (acac)₂ were used for the successful synthesis of Cu/MgO catalysts by metal-organic chemical vapor deposition (MOCVD) method. The copper supported on MgO catalysts were characterized by means of X-ray diffraction, Fourier-transform infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and N₂-physisorption. Characterization results indicated that the organic precursor was successfully deposited onto MgO and the crystal structure of MgO remained intact after deposition. The hydrogenation of γ-valerolactone (γ-GVL) was employed to evaluate the catalytic performance of the Cu/MgO catalysts. It was found that the 18% Cu/MgO catalyst exhibited excellent catalytic activity (90.5%) and selectivity (94.4%) for 1, 4-PDO at 473 K and 10 MPa, and the catalytic activity of Cu/MgO did not diminish significantly after cycling for three times.
- Cu/MgO,
- MOCVD,
- γ-valerolactone,
- hydrogenation,
- 1, 4-PDO
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