Citation: ZHOU Zhi-hui, JIN Can, ZHANG Hao-yi, LIANG Xiao-lei, ZHANG Fu-min, XIAO Qiang. CO₂ adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(2): 242-248. shu

CO₂ adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers

Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, China

Corresponding author: XIAO Qiang, xiaoq@zjnu.cn
Received Date: 18 September 2018
Revised Date: 28 November 2018

Fund Project: The project was supported by the National Natural Science Foundation of China (21471131) and College Students Technology Innovation Plan of Zhejiang Province(XinMiao Talent Plan)(2017R404017)College Students Technology Innovation Plan of Zhejiang Province(XinMiao Talent Plan) 2017R404017the National Natural Science Foundation of China 21471131

Figures(9)

Phloroglucinol-melamine-formaldehyde polymeric nanofibers (PMF) were hydrothermally synthesized by a polycondensation method using melamine, phloroglucinol and formaldehyde as starting materials. The effect of temperature on the PMF synthesis was investigated. The morphology and structure of the as-synthesized PMF were characterized by the scanning electron microscope (SEM), transmission electron microscope (TEM), N₂ adsorption-desorption and Fourier-transform infrared spectrometer (FT-IR) etc. Pure gas adsorption equilibrium isotherms of CO₂ and N₂ were determined by the volumetric method. The PMF sample synthesized at 393 K presented a higher specific surface area (64 m²/g) and a higher adsorption capacity of CO₂ (1.83 mmol/g@118 kPa, 298 K). Breakthrough column experiments indicated that efficient separation of CO₂-N₂ mixtures could be achieved on the PMF at 298 K and various pressures ranging from 200 to 600 kPa. After the PMF was thermally treated at 873 K in various atmospheres such as N₂, H₂, water vapor, etc., it was found that the specific surface area and micropore volume were greatly increased. Among the posttreated PMF samples, the one treated in 15% H₂O stream showed an improved CO₂ adsorption amount up to 2.83 mmol/g at 298 K and 118 kPa.
- melamine,
- nanofiber,
- CO₂ adsorption,
- breakthrough column,
- nitrogen-rich carbon nanofiber
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CO2 adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers

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CO₂ adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers