Citation: ZHOU Zhi-hui, JIN Can, ZHANG Hao-yi, LIANG Xiao-lei, ZHANG Fu-min, XIAO Qiang. CO₂ adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(2): 242-248. shu

CO₂ adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers

Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, China

Corresponding author: XIAO Qiang, xiaoq@zjnu.cn
Received Date: 18 September 2018
Revised Date: 28 November 2018

Fund Project: The project was supported by the National Natural Science Foundation of China (21471131) and College Students Technology Innovation Plan of Zhejiang Province(XinMiao Talent Plan)(2017R404017)College Students Technology Innovation Plan of Zhejiang Province(XinMiao Talent Plan) 2017R404017the National Natural Science Foundation of China 21471131

Figures(9)

Phloroglucinol-melamine-formaldehyde polymeric nanofibers (PMF) were hydrothermally synthesized by a polycondensation method using melamine, phloroglucinol and formaldehyde as starting materials. The effect of temperature on the PMF synthesis was investigated. The morphology and structure of the as-synthesized PMF were characterized by the scanning electron microscope (SEM), transmission electron microscope (TEM), N₂ adsorption-desorption and Fourier-transform infrared spectrometer (FT-IR) etc. Pure gas adsorption equilibrium isotherms of CO₂ and N₂ were determined by the volumetric method. The PMF sample synthesized at 393 K presented a higher specific surface area (64 m²/g) and a higher adsorption capacity of CO₂ (1.83 mmol/g@118 kPa, 298 K). Breakthrough column experiments indicated that efficient separation of CO₂-N₂ mixtures could be achieved on the PMF at 298 K and various pressures ranging from 200 to 600 kPa. After the PMF was thermally treated at 873 K in various atmospheres such as N₂, H₂, water vapor, etc., it was found that the specific surface area and micropore volume were greatly increased. Among the posttreated PMF samples, the one treated in 15% H₂O stream showed an improved CO₂ adsorption amount up to 2.83 mmol/g at 298 K and 118 kPa.
- melamine,
- nanofiber,
- CO₂ adsorption,
- breakthrough column,
- nitrogen-rich carbon nanofiber
1. [1]
  SONG C S. Global challenges and strategies for control, conversion and utilization of CO₂ for sustainable development involving energy, catalysis, adsorption and chemical processing[J]. Catal Today, 2006,115(1):2-32.
2. [2]
  HUANG Xue-qin, XIAO Qiang, ZHONG Yi-jun, ZHU Wei-dong. A wet ball-milling method to nanocrystalline Li₄SiO₄ materials for CO₂ capture at high temperatures[J]. J Fuel Chem Technol, 2016,44(9):1119-1124. doi: 10.3969/j.issn.0253-2409.2016.09.013
3. [3]
  GAO Feng, LI Cun-mei, WANG Yuan, SUN Guo-hua, LI Kai-xi. Preparation of resin-base spherical activated carbon and study on adsorption properties towards CO₂[J]. J Fuel Chem Technol, 2014,42(1):116-120.
4. [4]
  MA T Y, LIU L, YUAN Z Y. Direct synthesis of ordered mesoporous carbons[J]. Chem Soc Rev, 2013,42(9):3977-4003. doi: 10.1039/C2CS35301F
5. [5]
  BAE Y S, SNURR R Q. Development and evaluation of porous materials for carbon dioxide separation and capture[J]. Angew Chem Int Ed, 2011,50(49):11586-11596. doi: 10.1002/anie.201101891
6. [6]
  HARLICK P J E, TEZEL F H. An experimental adsorbent screening study for CO₂ removal from N₂[J]. Microporous Mesoporous Mater, 2004,76(1/3):71-79.
7. [7]
  HE Y F, SEATON N A. Heats of adsorption and adsorption heterogeneity for methane, ethane, and carbon dioxide in MCM-41[J]. Langmuir, 2006,22(3):1150-1155. doi: 10.1021/la052237k
8. [8]
  CHEN Lin-lin, WANG Xia, GUO Qing-jie. Study on CO₂ adsorption properties of tetraethylenepentamine modified mesoporous silica gel[J]. J Fuel Chem Technol, 2015,43(1):108-115. doi: 10.3969/j.issn.0253-2409.2015.01.017
9. [9]
  WANG D, MA X, SENTORUNSHALABY C, SONG C S. Development of carbon-based "molecular basket" sorbent for CO₂ capture[J]. Ind Eng Chem Res, 2012,51(7):3048-3057. doi: 10.1021/ie2022543
10. [10]
  ZHAO Hui-ling, HU Jun, WANG Jian-jun, ZHOU Li-hui, LIU Hong-lai. CO₂ capture by the amine-modified mesoporous materials[J]. Acta Phys-Chim Sin, 2007,23(6):801-806.
11. [11]
  HAO Shi-you, XIAO Qiang, ZHONG Yi-jun, ZHU Wei-dong, YANG Hui. One-pot synthesis of amino-functionalized SBA-15 and their CO₂ adsorption properties[J]. Chin J Inorg Chem, 2010,26(6):982-988.
12. [12]
  HERM Z R, SWISHER J A, SMIT B, KRISHNA R, LONG J R. Metal-organic frameworks as adsorbents for hydrogen purification and precombustion carbon dioxide capture[J]. J Am Chem Soc, 2011,133(15):5664-5667. doi: 10.1021/ja111411q
13. [13]
  LI J R, KUPPLER R J, ZHOU H C. Selective gas adsorption and separation in metal-organic frameworks[J]. Chem Soc Rev, 2009,38(5):1477-1504. doi: 10.1039/b802426j
14. [14]
  MILLWARD A R, YAGHI O M. Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature[J]. J Am Chem Soc, 2005,127(51):17998-17999. doi: 10.1021/ja0570032
15. [15]
  DING S Y, WANG W. Covalent organic frameworks (COFs):from design to applications[J]. Chem Soc Rev, 2013,42(2):548-568. doi: 10.1039/C2CS35072F
16. [16]
  XIANG Z H, CAO D P. Porous covalent-organic materials:Synthesis, clean energy application and design[J]. J Mater Chem A, 2013,1(8):2691-2718. doi: 10.1039/C2TA00063F
17. [17]
  BEN T, PEI C Y, ZHANG D L, XU J, DENG F, JING X F, QIU S L. Gas storage in porous aromatic frameworks(PAFs)[J]. Energy Environ Sci, 2011,4(10):3991-3999. doi: 10.1039/c1ee01222c
18. [18]
  PEI C Y, BEN T, GUO H, XU J, DENG F, XIANG Z H, CAO D P, QIU S L. Targeted synthesis of electroactive porous organic frameworks containing triphenyl phosphine moieties[J]. Phil Trans R Soc A, 2013,371(2000):1-15.
19. [19]
  LIU L, LI P Z, ZHU L L, ZOU R Q, ZHAO Y L. Microporous polymelamine network for highly selective CO₂ adsorption[J]. Polymer, 2013,54(2):596-600. doi: 10.1016/j.polymer.2012.12.015
20. [20]
  XU C, HEDIN N. Synthesis of microporous organic polymers with high CO₂-over-N₂ selectivity and CO₂ adsorption[J]. J Mater Chem A, 2013,1(10):3406-3414. doi: 10.1039/c3ta01160g
21. [21]
  SCHWAB M G, FASSBENDER B, SPIESS H W, THOMAS A, FENG X, MULLEN K. Catalyst-free preparation of melamine-based microporous polymer networks through schiff base chemistry[J]. J Am Chem Soc, 2009,131(21):7216-7217. doi: 10.1021/ja902116f
22. [22]
  HU J X, SHANG H, WANG J G, LUO L, XIAO Q, ZHONG Y J, ZHU W D. Highly enhanced selectivity and easy regeneration for the separation of CO₂ over N₂ on melamine-based microporous organic polymers[J]. Ind Eng Chem Res, 2014,53(29):11828-11837. doi: 10.1021/ie501736t
23. [23]
  HU Jing-xiu, ZHANG Jing, ZOU Jian-feng, XIAO Qiang, ZHONG Yi-jun, ZHU Wei-dong. Nitrogen-rich microporous carbon derived from melamine-based porous polymer for selective CO₂ adsorption[J]. Acta Phys-Chim Sin, 2014,30(6):1169-1174.
24. [24]
  ZHOU H H, XU S, SU H P, WANG M, QIAO W M, LING L C, LONG D H. Facile preparation and ultra-microporous structure of melamine-resorcinol-formaldehyde polymeric microspheres[J]. Chem Commun, 2013,49(36):3763-3765. doi: 10.1039/c3cc41109e
25. [25]
  WANG M, WANG J, QIAO W M, LING L C, LONG D H. Scalable preparation of nitrogen-enriched carbon microspheres for efficient CO₂ capture[J]. RSC Adv, 2014,4(106):61456-61464. doi: 10.1039/C4RA11647J
26. [26]
  XIAO Q, WEN J J, GUO Y N, HU J X, WANG J G, ZHANG F M, TU G M, ZHONG Y J, ZHU W D. Synthesis, carbonization, and CO₂ adsorption properties of phloroglucinol-melamine-formaldehyde polymeric nanofibers[J]. Ind Eng Chem Res, 2016,55(49):12667-12674. doi: 10.1021/acs.iecr.6b03494
27. [27]
  PERALTA D, CHAPLAIS G, SIMON-MASSERON A, BARTHELET K, CHIZALLET C, QUOINEAUD A A, PIRNGRUBER G D. Comparison of the behavior of metal-organic frameworks and zeolites for hydrocarbon separations[J]. J Am Chem Soc, 2012,134(19):8115-8126. doi: 10.1021/ja211864w
28. [28]
  STRELKO V V, KUTS V S, THROWER P A. On the mechanism of possible influence of heteroatoms of nitrogen, boron and phosphorus in a carbon matrix on the catalytic activity of carbons in electron transfer reactions[J]. Carbon, 2000,38(10):1499-1503. doi: 10.1016/S0008-6223(00)00121-4
29. [29]
  LIU L, DENG Q F, HOU X X, YUAN Z Y. User-friendly synthesis of nitrogen-containing polymer and microporous carbon spheres for efficient CO₂ capture[J]. J Mater Chem, 2012,22(31):15540-15548. doi: 10.1039/c2jm31441j
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CO2 adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers

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CO₂ adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers