Citation: YANG Wen-shen, LIN Jun-heng, YIN Xiu-li, WU Chuang-zhi. Release of HCl and H₂S during gasification of refuse derived-fuel chars[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(1): 121-128. shu

Release of HCl and H₂S during gasification of refuse derived-fuel chars

1.
Key Laboratory of Renewable Energy, CAS, Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: YIN Xiu-li, xlyin@ms.giec.ac.cn
Received Date: 7 September 2018
Revised Date: 23 November 2018

Fund Project: Science and Technology Program of Guangzhou 201707010242the Guangdong Natural Science Foundation 2017B030308002The project was supported by the National Key R&D Program of China (2016YFE0203300), the Guangdong Natural Science Foundation (2017B030308002) and Science and Technology Program of Guangzhou (201707010242)the National Key R&D Program of China 2016YFE0203300

Figures(10)

Using a horizontal tubular reactor together with chemical adsorption, release characteristics of corrosive gases, viz., HCl and H₂S, during steam and CO₂ gasification process of aged and normal refuse derived-fuels char (ARC and NRC) were investigated. Effects of gasification temperature, type and flow rate of gasification medium on their release behaviors were examined. In H₂O gasification at 950℃ the carbon gasification rates, HCl and H₂S yields of ARC are 66.1%, 100% and 74.9%, respectively, and those are 77.8%, 100% and 2.9% in CO₂ gasification, respectively. The carbon gasification rates, HCl and H₂S yields of NRC in H₂O gasification are 98.8%, 100% and 53.7%, and those are 100%, 96.2% and 10.3% in CO₂ gasification, respectively. The release characteristics of HCl and H₂S are investigated with different flow rates of H₂O and CO₂ in the NRC gasification. HCl and H₂S yields of NRC increase with increasing flow rate of H₂O, but the promoting effect can be ignored when H₂O/C is ≥ 3.3. HCl yield of NRC increases but H₂S yield decreases with increasing flow rate of CO₂.
- HCl,
- H₂S,
- aged refuse derived-fules char,
- normal refuse derived-fuels char,
- gasification
1. [1]
  "The 13^th Five-Year Plan" construction planning for harmless treatment facilities of national municipal waste[R]. Beijing: Ministry of Housing and Urban-Rural Development of the People's Republic of China, 2016.
2. [2]
  ZHAO You-cai, CHAI Xiao-li, NIU Dong-jie. Characteristics of aged refuse in closed refuse landfill in Shanghai[J]. J Tongji Univ (Nat Sci)), 2006,34(10):1360-1364. doi: 10.3321/j.issn:0253-374X.2006.10.017
3. [3]
  ROTHEUT M, QUICKER P. Energetic utilisation of refuse derived fuels from landfill mining[J]. Waste Manage, 2017,62:101-117. doi: 10.1016/j.wasman.2017.02.002
4. [4]
  LI G K, HOU F, GUO Z, YAO G, SANG N. Analyzing nutrient distribution in different particle-size municipal aged refuse[J]. Waste Manage, 2011,31(11):2203-2207. doi: 10.1016/j.wasman.2011.06.010
5. [5]
  COMMISSION E. Council Directive 99/31/EC of 26 April 1999 on the landfill of waste (Landfill Directive)[EB]. 1999.
6. [6]
  BOSMANS A, VANDERREYDT I, GEYSEN D, HELSEN L. The crucial role of Waste-to-Energy technologies in enhanced landfill mining:A technology review[J]. J Clean Prod, 2013,55(14):10-23.
7. [7]
  ROTHEUT M, QUICKER P. Energetic utilization of refuse derived fuels from landfill mining[J]. Waste Mange, 2017,62:101-117. doi: 10.1016/j.wasman.2017.02.002
8. [8]
  CHALERMCHAROENRAT S, LAOHALIDANOND K, KERDSUWAN S. Optimization of combustion behavior and producer gas quality from reclaimed landfill through highly densify RDF-gasification[J]. Energy Procedia, 2015,79:321-326. doi: 10.1016/j.egypro.2015.11.496
9. [9]
  YUAN Hao-ran, LU Tao, XIONG Zu-hong, HUANG Hong-yu, KOBAYASHI Noriyuki, CHEN Yong, LI Zhi-qiang. Advance in pyrolysis and gasification of municipal solid waste study[J]. Chem Ind Eng Prog, 2012,31(2):421-427.
10. [10]
  HJELMAR O. Disposal strategies for municipal solid waste incineration residues[J]. J Hazard Mater, 1996,47(1/3):345-368.
11. [11]
  MAKEN S, JANG S H, PARK J W, PARK J W, SONG H C, LEE S, CHANG E H. Vitrification of MSWI fly ash using Brown's gas and fate of heavy metals[J]. J Sci Ind Res, 2005,64(3):198-204.
12. [12]
  TUPPURAINEN K, HALONEN I, RUOKOJARVI P, TARHANEN J, RUUSKANEN J. Formation of PCDDs and PCDFs in municipal waste incineration and its inhibition mechanisms:A review[J]. Chemosphere, 1998,36(7):1493-1511. doi: 10.1016/S0045-6535(97)10048-0
13. [13]
  SENNECA O. Kinetics of pyrolysis, combustion and gasification of three biomass fuels[J]. Fuel Process Technol, 2007,88(1):87-97. doi: 10.1016/j.fuproc.2006.09.002
14. [14]
  SHUIT S H, TAN K T, LEE K T, KAMARUDDIN A H. Oil palm biomass as a sustainable energy source:A Malaysian case study[J]. Energy, 2009,34(9):1225-1235. doi: 10.1016/j.energy.2009.05.008
15. [15]
  PAN T J, GESMUNDO F, NIU Y. Corrosion behavior of three iron-based model alloys in reducing atmospheres containing HCl and H₂S at 600℃[J]. Corros Sci, 2007,49(3):1362-1377. doi: 10.1016/j.corsci.2006.06.014
16. [16]
  HU H, FANG Y, LIU H, YU R, LUO G, LIU W, LI A, YAO H. The fate of sulfur during rapid pyrolysis of scrap tires[J]. Chemosphere, 2014,97(1):102-107.
17. [17]
  YUAN G, CHEN D, YIN L, WANG Z, ZHAO L, WANG J Y. High efficiency chlorine removal from polyvinyl chloride (PVC) pyrolysis with a gas-liquid fluidized bed reactor[J]. Waste Manage, 2014,34(6):1045-1050. doi: 10.1016/j.wasman.2013.08.021
18. [18]
  ZHU H M, JIANG X G, YAN J H, CHI Y, CEN K F. TG-FTIR analysis of PVC thermal degradation and HCl removal[J]. J Anal Appl Pyrolysis, 2008,82(1):1-9. doi: 10.1016/j.jaap.2007.11.011
19. [19]
  LANE D J, VAN EYK P J, ASHMAN P J, KWONG C W, DE NYS R, ROBERTS D A, COLE A J, LEWIS D M. Release of Cl, S, P, K, and Na during thermal conversion of algal biomass[J]. Energy Fuels, 2015,29(4):2542-2554. doi: 10.1021/acs.energyfuels.5b00279
20. [20]
  LIN Jun-heng, YANG Wen-shen, YIN Xiu-li, WU Chuang-zhi. Release of HCl and H₂S during pyrolysis of aged refuse derived-fuels[J]. J Fuel Chem Technol, 2018,46(2):152-159. doi: 10.3969/j.issn.0253-2409.2018.02.004
21. [21]
  RUAN Song-bin. Discussion about means and process of country towns domestic waste treatment in Guangxi[J]. Environ Sanit Eng, 2008,16(1):27-30. doi: 10.3969/j.issn.1005-8206.2008.01.008
22. [22]
  HU H, FANG Y, LIU H, YU R, LUO G, LIU W, LI A, YAO H. The fate of sulfur during rapid pyrolysis of scrap tires[J]. Chemosphere, 2014,97(1):102-107.
23. [23]
  YU J, SUN L, MA C, QIAO Y, YAO H. Thermal degradation of PVC:A review[J]. Waste Manage, 2016,48:300-314. doi: 10.1016/j.wasman.2015.11.041
24. [24]
  DU Yao, FANG Yuan, SHEN Dong-sheng, LONG Yu-yang. Review on pollution control technologies of hydrogen sulfide odor in landfill[J]. Trans Chin Soc Agric Eng, 2015,31(1):269-275.
25. [25]
  RECARI J, BERRUECO C, ABELLÍ S, MONTANÉ D, FARRIOL X. Gasification of two solid recovered fuels (SRFs) in a lab-scale fluidized bed reactor:Influence of experimental conditions on process performance and release of HCl, H₂S, HCN and NH₃[J]. Fuel Process Technol, 2016,142:107-114. doi: 10.1016/j.fuproc.2015.10.006
26. [26]
  DUAN L, ZHAO C, ZHOU W, QU C, CHEN X. Investigation on coal pyrolysis in CO₂ atmosphere[J]. Energy Fuels, 2009,23(7):3826-3830. doi: 10.1021/ef9002473
27. [27]
  FRIGGE L, ELSERAFI G, STROHLE J, EPPLE B. Sulfur and chlorine gas species formation during coal pyrolysis in nitrogen and carbon dioxide atmosphere[J]. Energy Fuels, 2016,30(9):7713-7720. doi: 10.1021/acs.energyfuels.6b01080
1. [1]
  Xingyu Liao , Xiangming Yi , Kin Shing Chan . 追凶之路上的怪客——硫化氢. University Chemistry, 2025, 40(6): 172-176. doi: 10.12461/PKU.DXHX202408039
2. [2]
  Linfang ZHANG , Wenzhu YIN , Gui YIN . A 2-dicyanomethylene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran-based near-infrared fluorescence probe for the detection of hydrogen sulfide and imaging of living cells. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 540-548. doi: 10.11862/CJIC.20240405
3. [3]
  Yu Dai , Xueting Sun , Haoyu Wu , Naizhu Li , Guoe Cheng , Xiaojin Zhang , Fan Xia . Determination of the Michaelis Constant for Gold Nanozyme-Catalyzed Decomposition of Hydrogen Peroxide. University Chemistry, 2025, 40(5): 351-356. doi: 10.12461/PKU.DXHX202407052
4. [4]
  Liu Lin , Zemin Sun , Huatian Chen , Lian Zhao , Mingyue Sun , Yitao Yang , Zhensheng Liao , Xinyu Wu , Xinxin Li , Cheng Tang . Recent Advances in Electrocatalytic Two-Electron Water Oxidation for Green H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(4): 2305019-0. doi: 10.3866/PKU.WHXB202305019
5. [5]
  Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H₂O₂ by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
6. [6]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
7. [7]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
8. [8]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
9. [9]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-0. doi: 10.3866/PKU.WHXB202407005
10. [10]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
11. [11]
  Jichao XU , Ming HU , Xichang CHEN , Chunhui WANG , Leichen WANG , Lingyi ZHOU , Xing HE , Xiamin CHENG , Su JING . Construction and hydrogen peroxide-activated chemodynamic activity of ferrocene?benzoselenadiazole conjugate. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1495-1504. doi: 10.11862/CJIC.20250144
12. [12]
  Lisen Sun , Yongmei Hao , Zhen Huang , Yongmei Liu . Experimental Teaching Design for Viscosity Measurement Serves the Optimization of Operating Conditions for Kitchen Waste Treatment Equipment. University Chemistry, 2024, 39(2): 52-56. doi: 10.3866/PKU.DXHX202307063
13. [13]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
14. [14]
  Haiyu Zhu , Zhuoqun Wen , Wen Xiong , Xingzhan Wei , Zhi Wang . 二维半金属/硅异质结中肖特基势垒高度的准确高效预测. Acta Physico-Chimica Sinica, 2025, 41(7): 100078-0. doi: 10.1016/j.actphy.2025.100078
15. [15]
  Kexin Yan , Zhaoqi Ye , Lingtao Kong , He Li , Xue Yang , Yahong Zhang , Hongbin Zhang , Yi Tang . Seed-Induced Synthesis of Disc-Cluster Zeolite L Mesocrystals with Ultrashort c-Axis: Morphology Control, Decoupled Mechanism, and Enhanced Adsorption. Acta Physico-Chimica Sinica, 2024, 40(9): 2308019-0. doi: 10.3866/PKU.WHXB202308019
16. [16]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
17. [17]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
18. [18]
  Yang ZHOU , Lili YAN , Wenjuan ZHANG , Pinhua RAO . Thermal regeneration of biogas residue biochar and the ammonia nitrogen adsorption properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1574-1588. doi: 10.11862/CJIC.20250032
19. [19]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
20. [20]
  Yuting Bai , Cenqi Yan , Zhen Li , Jiaqiang Qin , Pei Cheng . Preparation of High-Strength Polyimide Porous Films with Thermally Closed Pore Property by In Situ Pore Formation Method. Acta Physico-Chimica Sinica, 2024, 40(9): 2306010-0. doi: 10.3866/PKU.WHXB202306010

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(2345)
HTML views(190)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Release of HCl and H2S during gasification of refuse derived-fuel chars

Metrics

通讯作者: 陈斌, bchen63@163.com

Release of HCl and H₂S during gasification of refuse derived-fuel chars