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Citation: LIU Shuai, LIU Jin-bo, LI Xu-he, ZHANG Jian, YAN Jing-sen, LIANG Fei-xue, WANG Yan-juan. Preparation of WO3/g-C3N4 heterojunction catalyst and its oxidative desulfurization performance[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(7): 852-862. shu

Preparation of WO3/g-C3N4 heterojunction catalyst and its oxidative desulfurization performance

  • 1.

    Liaoning Shihua University, Fushun 113001, China

  • 2.

    Liaoning Institute of Science and Technology, Benxi 117004, China

  • Corresponding author: ZHANG Jian, zhangjian_lnpu@163.com
  • Received Date: 26 March 2019
    Revised Date: 23 April 2019

    Fund Project: the Natural Science Foundation of Liaoning Province 20170540475The project was supported by the Natural Science Foundation of Liaoning Province (20170540475) and Pilot Program of University of Liao-ning Innovation and Education Reform

Figures(14)

  • Graphite phase carbon nitride (g-C3N4) and metal oxide tungsten trioxide (WO3) heterojunction nanocomposites WO3/g-C3N4 were prepared by roasting from urea and ammonium tungstate. The physical and chemical properties of the catalysts were investigated by means of XRD, UV-vis, SEM, PL and XPS. The characterization indicated that WO3 and g-C3N4 interacted well in the catalysts, and electron transfer occurred between them, which ensured high oxidative desulfurization activity of WO3/g-C3N4. Supported catalyst WO3/g-C3N4 was prepared using WO3 as the support. Isopropyl peroxide was used as the oxidant to investigate the catalyst performance in oxidative desulfurization of the simulated oil. Under the reaction conditions of 80℃ and the content ratio of O/S at 3, a 72.79% of dibenzothiophene (DBT) conversion could be achieved after 180 min. It was fund that the superoxide free radicals (·O2-), electron (e-) and hydroxyl free radicals (·OH) promoted the reaction rate through free radical capture experiment and the reaction mechanism was proposed.
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