Citation: Wen Li, Changfeng Huang, Hua Cao, Xiang Liu. Progress in the Visible-Light-Induced Radical Cascade Cyclization of 1, n-Enynes[J]. Chemistry, ;2021, 84(3): 240-245, 239. shu

Progress in the Visible-Light-Induced Radical Cascade Cyclization of 1, n-Enynes

School of Chemistry and Chemical Engineering and Guangdong Cosmetics Engineering & Technology Research Center, Guangdong Pharmaceutical University, Zhongshan, 528458

Corresponding author: Xiang Liu, liux96@gdpu.edu.cn
Received Date: 22 August 2020
Accepted Date: 17 September 2020

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Carbon and nitrogen heterocyclic compounds are widely found in natural products, bioactive molecules, drugs and many other fine chemicals. In recent years, a large number of synthetic methods have been developed to prepare these compounds. Among them, visible-light-induced radical cascade cyclization of 1, n-enynes has become a powerful tool for the preparation of these compounds because of its green and friendly conditions, simple operation, good chemical selectivity and functional group compatibility. Based on the types of free radicals, this paper summarizes the latest progress in the field of visible light induced radical cascade cyclization of 1, n-enynes since 2013.
- Photocatalysis,
- 1, n-enynes,
- Synthetic methods
1. [1]
  Xuan J, Studer A. Chem. Soc. Rev., 2017, 46: 4329~4346.
2. [2]
  Li Y, Pan G A, Luo M J, et al. Chem. Commun., 2020, 56: 6907~6924.
3. [3]
  Xuan J, Xiao W J. Angew. Chem. Int. Ed., 2012, 51: 2~13.
4. [4]
  Prier C K, Rankic D A, Macmillan D W, et al. Chem. Rev., 2013, 113: 5322~5363.
5. [5]
  Deng G B, Wang Z Q, Xia J D, et al. Angew. Chem. Int. Ed., 2013, 52: 1535~1538.
6. [6]
  Gao F, Yang C, Ma N, Gao G L, et al. Org. Lett., 2016, 18: 600~603.
7. [7]
  Li C G, Xu G Q, Xu P F. Org. Lett., 2017, 19: 512~515.
8. [8]
  Jana S, Verma A, Kadu R, et al. Chem. Sci., 2017, 8: 6633~6644.
9. [9]
  Liu Y, Song R J, Luo S L, et al. Org. Lett., 2018, 20: 212~215.
10. [10]
  Shen Z J, Shi H N, Hao W J, et al. Chem. Commun., 2018, 54: 11542~11545.
11. [11]
  Huang M H, Zhu C F, He C L, et al. Org. Chem. Front., 2018, 5: 1653~1650.
12. [12]
  Hou H, Tang D L, Li H X, et al. J. Org. Chem., 2019, 84: 7509~7517.
13. [13]
  Jiao M J, Liu D, Hu X Q, et al. Org. Chem. Front., 2019, 6: 3834~3838.
14. [14]
  Correia J T M, Silva G P D, Andre E S, et al. Adv. Synth. Catal., 2019, 361: 1~8.
15. [15]
  Wang S W, Yu J, Zhou Q Y, et al. ACS Sustain. Chem. Eng., 2019, 7, 10154~10162.
16. [16]
  Zhuang K Q, Cui Y S, Yuan X, et al. ACS Sustain. Chem. Eng., 2020, 8: 11729~11736.
17. [17]
  Qu Y, Xu W T, Zhang J J, et al. J. Org. Chem., 2020, 85: 5379~5389.
18. [18]
  Huang M H, Zhu Y L, Hao W J, et al. Adv. Synth. Catal., 2017, 13: 2229~2234.
19. [19]
  Hou H, Li H X, Xu Y, et al. Adv. Synth. Catal., 2018, 22: 4325~4329.
20. [20]
  Meng X X, Kang Q Q, Zhang J Y, et al. Green Chem., 2020, 22: 1388~1392.
21. [21]
  Mutra M R, Kudale V S, Tsai W, et al. Green Chem., 2020, 22: 2288~2300.
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沈阳化工大学材料科学与工程学院沈阳 110142