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Citation: MEI Li-bin, LIU Xin-min. Preparation, characterization and CO2 adsorption of ion exchange resin supported solid amine adsorbents[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(7): 880-888. shu

Preparation, characterization and CO2 adsorption of ion exchange resin supported solid amine adsorbents

  • Qingdao University of Science & Technology, Qingdao 266042, China

  • Corresponding author: LIU Xin-min, lxm220@qust.edu.cn
  • Received Date: 8 March 2017
    Revised Date: 6 May 2017

    Fund Project: the Shandong Province Science and Technology Development Project 2010GGX10709

Figures(10)

  • A series of solid amine adsorbents were prepared by using three different preparation methods with ion exchange resin (D001) as carrier and with tetraethylenepentamine (TEPA) as modifier. The sorbents were characterized by nitrogen adsorption/desorption, Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA) techniques. The effects of TEPA loadings, adsorption temperatures, influent gas flow rates and CO2 partial pressure on the CO2 adsorption capacity in a fixed bed reactor were investigated. The results show that the solid amine adsorbent prepared by the coordination method has a better dispersibility and stability, and the maximum CO2 adsorption capacity is 4 mmol/g when the TEPA loading is 40%, the adsorption temperature is 65 ℃ and the influent gas flow rate is 40 mL/min. The amount of CO2 adsorption only decreases by 3.98% and remains almost unchanged after 10 cycles of desorption and desorption. The study of thermodynamics and kinetics indicates that the adsorption mechanism is dominated by both chemical and physical adsorption.
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