Citation: YIN Hai-liang, LIU Xin-liang, ZHOU Tong-na, LIN Ai-guo. Effect of preparation method of nanosized zeolite HY-Al₂O₃ composite as NiMo catalyst support on diesel HDS[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(8): 950-956. shu

Effect of preparation method of nanosized zeolite HY-Al₂O₃ composite as NiMo catalyst support on diesel HDS

1.
Academy of Science & Technology, China University of Petroleum(huadong), Dongying 257061, China
2.
Environmental Protection Agency of Dongying, Dongying 257300, China

Corresponding author: YIN Hai-liang, yinhl@upc.edu.cn
Received Date: 23 March 2018
Revised Date: 25 June 2018

Fund Project: Promotive Research Fund for Excellent Young and Middle-aged Scientists of Shandong Province, China BS2013CL021The project was supported by National Natural Science Foundation of China (21206197), Shandong Provincial Natural Science Foundation, China (2016GSF117030) and Promotive Research Fund for Excellent Young and Middle-aged Scientists of Shandong Province, China (BS2013CL021)National Natural Science Foundation of China 21206197Shandong Provincial Natural Science Foundation, China 2016GSF117030

Figures(9)

Two NiMo catalysts using the nanosized zeolite HY-Al₂O₃ composite (labeled as NYA) prepared by mechanical mixing method and sol-gel method as the support were prepared and characterized by XRD, BET, TPD, H₂-TPR, HRTEM and FT-IR spectroscopy. The former catalyst possessed larger pore volume and specific surface area, more acid amount, superior reducibility of metal phase and higher dispersion of edge and corner Mo atoms, and showed higher hydrodesulfurization (HDS) performance. Compared with the former catalyst, the latter catalyst had more MoO₃ to be converted to active type-Ⅱ NiMoS phase, possessed higher stacking degree and bigger length of MoS₂ slabs, and showed lower active phase dispersion. Although the sol-gel method was beneficial to increase the precursor ratio of type-Ⅱ NiMoS phase, the poor pore structure caused by this method inhibited this advantage and reduced the catalytic activity of the catalyst.
- nanosized zeolite,
- hydrodesulfurization,
- hybrid mode
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of preparation method of nanosized zeolite HY-Al2O3 composite as NiMo catalyst support on diesel HDS

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通讯作者: 陈斌, bchen63@163.com

Effect of preparation method of nanosized zeolite HY-Al₂O₃ composite as NiMo catalyst support on diesel HDS