Citation: Feng Ming, Zhang Gaixia, Zhao Xiaoli, Fang Li. Construction and Application of Molecular Imprinted Electrochemical Sensor for Propyl Gallate Detection[J]. Chemistry, ;2019, 82(3): 243-250. shu

Construction and Application of Molecular Imprinted Electrochemical Sensor for Propyl Gallate Detection

School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006

Corresponding author: Fang Li, fangli@sxu.edu.cn
Received Date: 27 July 2018
Accepted Date: 30 October 2018

Figures(11)

Molecular imprinted polymers (MIPs) were prepared on polyethylenimine (PEI) grafted multi-wall carbon nanotube (MWCNT-PEI) by using propyl gallate (PG) as target molecule, ethylene glycol diglycidyl ether as cross-linker. The molecular imprinted electrochemical sensor (MIES) for PG detection was then constructed by dropping the obtained MIPs onto the surface of glassy carbon electrode (GCE). The obtained materials were characterized and measured by FTIR, XRD, CV, EIS and DPV. The conductivity, linear response, specificity, stability and repeatability of the sensor for PG detection were investigated in detail. The constructed MIES exhibited excellent linear responses to PG in the range of 1×10^-8 to 1×10^-5 mol·L^-1, with a detection limit of 2.5×10^-9 mol·L^-1. As a result, the recovery of PG in real samples was about 95%~98%.
- Propyl gallate,
- Molecular imprinted polymers,
- Molecular imprinted electrochemical sensor,
- Multi-walled carbon nanotubes
1. [1]
  H H Yong, H J Moon, R Y Bo et al. Toxicol In Vitro, 2010, 24(4):1183~1189.
2. [2]
  B B Sha, X B Yin, X H Zhang et al. J. Chromatogr. A, 2007, 1167(1):109~115.
3. [3]
  C André, I Castanheira, J M Cruz et al. Trends Food Sci. Tech., 2010, 21(5):229~246.
4. [4]
  C Perrin, L Meyer. Food Chem., 2002, 77(1):93~100.
5. [5]
  D M Wyatt. J. Am. Oil Chem. Soc., 1981, 58(10):917~920.
6. [6]
  Y He, S Xu, M Deng et al. Instrum. Sci. Technol., 2017, 45(4):404~411.
7. [7]
  C A I Hall, A Zhu, M G Zeece. J. Agric. Food. Chem., 1994, 42(4):919~921.
8. [8]
  Q Xiang, Y Gao, Y Xu et al. Anal. Sci., 2007, 23(6):713~717.
9. [9]
  Y Guan, Q Chu, F Liang et al. Food Chem., 2006, 94(1):157~162.
10. [10]
  G Xu, Y Chi, L Li et al. Food Chem., 2015, 177:37~42.
11. [11]
  A E Vikraman, Z Rasheed, L Rajith et al. Food Anal. Method., 2013, 6(3):775~780.
12. [12]
  M Oishi, T Matsuda, S Nojiri et al. Shokuhin Eiseigaku Zasshi (Journal of the Food Hygienic Society of Japan), 2002, 43(2):104~109.
13. [13]
  J Riber, C D L Fuente, M D Vazquez et al. Talanta, 2000, 52(2):241~252.
14. [14]
  M Luque, A RíOs, M Valcárcel. Anal. Chim. Acta, 1999, 395(1):217~223.
15. [15]
  M Škrinjar, M H Kolar, N Jelšek et al. J. Food Compos. Anal., 2007, 20:539~545.
16. [16]
  R Xing, S Wang, Z Bie et al. Nat. Protoc., 2017, 12(5):964~987.
17. [17]
  E Piletska, H Yawer, F Canfarotta et al. Sci. Rep., 2017, 7(1):11537.
18. [18]
  O Brüggemann, A Visnjevski, R Burch et al. Anal. Chim. Acta, 2004, 504(1):81~88.
19. [19]
  M Huang, W Pang, J Zhang et al. J. Pharm. Biomed. Anal., 2012, 58(1):12~18.
20. [20]
21. [21]
  M Cui, J Huang, Y Wang et al. Biosens. Bioelectron., 2015, 68:563~569.
22. [22]
  Y Dai, X Li, L Fan et al. Biosens. Bioelectron., 2016, 86:741~747.
23. [23]
  J M You, D Kim, S Jeon. Electrochim. Acta, 2012, 65:288~293.
24. [24]
  J Y Kim, Y Jo, S Lee et al. Tetrahed. Lett., 2010, 41(8):6290~6292.
25. [25]
  D Zhang, D Yu, W Zhao et al. Analyst, 2012, 137:2629~2636.
26. [26]
  A Martínez-Alonso, S Losada-Barreiro, C Bravo-Díaz. J. Mol. Liq., 2015, 210:143~150.
27. [27]
28. [28]
  H Dong, L Ding, F Yan et al. Biomaterials, 2011, 32:3875~3882.
29. [29]
  L Zhao, F Zhao, B Zeng. Biosens. Bioelectron., 2014, 60:71~76.
30. [30]
  H Moradian, H Fasehee, H Keshvari et al. Colloids Surf. B, 2014, 122:115~125.
31. [31]
  X Xina, S Suna, H Li et al. Sens. Actuat. B, 2015, 209:275~280.
32. [32]
  G Wulff. Microchim. Acta, 2013, 180(15):1359~370.
33. [33]
  M A Khasawneh, P T Vallano1, V T Remcho. J. Chromatogr. A, 2001, 922:87~97.
34. [34]
  J H Andrew, L S Francesca, M Panagiotis et al. Anal. Chim. Acta, 2005, 538:9~14.
35. [35]
  M D Morales, M C González, A J Reviejo et al. Microchem. J., 2005, 80:71~78.
36. [36]
  M P Aguilar-Caballos, A GoÂmez-Hens, D PeÂrez-Bendito. Anal. Chim. Acta, 1997, 354:173~179.
37. [37]
  X Kan, H Zhou, C Li et al. Electrochim. Acta, 2012, 63:69~75.
38. [38]
  X Xing, S Liu, J Yu et al. Biosens. Bioelectron., 2012, 31:277~283.
39. [39]
40. [40]
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