Citation: GUO Hai-jun, TANG Wei-chao, ZHANG Hai-rong, PENG Fen, WANG Can, HUANG Qian-lin, XIONG Lian, CHEN Xin-de, OUYANG Xin-ping, QIU Xue-qing. Effects of the preparation solvent on structure and catalytic properties of NiCoB amorphous alloy catalysts for hydrogenation of furfural[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(7): 817-827. shu

Effects of the preparation solvent on structure and catalytic properties of NiCoB amorphous alloy catalysts for hydrogenation of furfural

GUO Hai-jun ^1,2,3,4,5 ,
TANG Wei-chao ^1,2,3,4 ,
ZHANG Hai-rong ^1,2,3,4 ,
PENG Fen ^1,2,3,4 ,
WANG Can ^1,2,3,4 ,
HUANG Qian-lin ^1,2,3,4,6 ,
XIONG Lian ^1,2,3,4 ,
CHEN Xin-de ^1,2,3,4,*,, ,
OUYANG Xin-ping ⁵ ,
QIU Xue-qing ⁵

1.
Key Laboratory of Renewable Energy, Chinese Academy of Sciences, Guangzhou 510640, China
2.
Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
3.
Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
4.
R & D Center of Xuyi Attapulgite Applied Technology, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Xuyi 211700, China
5.
School of Chemistry & Chemical Engineering, South China University of Technology, Guangzhou 510640, China
6.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: CHEN Xin-de, cxd_cxd@hotmail.com
Received Date: 20 March 2017
Revised Date: 5 May 2017

Fund Project: the National Natural Science Foundation of China 21406229the Program of Jiangsu Province Science and Technology BE2014101Guangdong Provincial Key Laboratory Foundation of New and Renewable Energy Research and Development Y709jh1001

Figures(8)

A series of NiCoB amorphous alloy catalysts were prepared by chemical reduction method in different single and mixed solvent systems and their performance for liquid phase hydrogenation of furfural (FUR) was evaluated. The catalysts were also characterized by N₂ adsorption-desorption, ICP, FE-SEM, HRTEM, XRD and XPS. The results showed that the surface tension, viscosity, polarity and solubility parameter of preparation solvent had important effects on the composition, morphology, structure and the catalytic properties of FUR hydrogenation of the NiCoB amorphous alloy catalyst. The NiCoB-MEG catalyst prepared by the mixed solvent of methanol/ethylene glycol (MEG, volume ratio of 1:1) showed the optimum liquid phase hydrogenation performance of FUR to furfuryl alcohol (FA) with a FUR conversion of 96.4% and a FA selectivity of 83.49%. It can be due to the improvement of dispersion and reduction of metallic components by the synergistic effect between methanol and ethylene glycol.
- hydrogenation of furfural,
- preparation solvent,
- NiCoB,
- amorphous alloy catalysts,
- furfuryl alcohol
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