Citation: Agüero Fabiola Nerina, Alonso Jose Antonio, Fernández-Díaz Maria Teresa, Cadus Luis Eduardo. Ni-based catalysts obtained from perovskites oxides for ethanol steam reforming[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(11): 1332-1341. shu

Ni-based catalysts obtained from perovskites oxides for ethanol steam reforming

1.
Instituto de Investigaciones en Tecnología Química(INTEQUI), UNSL-CONICET, Almirante Brown 1455, 5700 San Luis, Argentina
2.
Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas, Cantoblanco, 28049 Madrid, Spain
3.
Institut Laue-Langevin, B. P. 156, F-38042 Grenoble Cedex 9, France

Corresponding author: Cadus Luis Eduardo, lcadus@unsl.edu.ar
Received Date: 29 June 2018
Revised Date: 19 September 2018

Figures(7)

Perovskites as host structures of cations were used in order to generate in situ active and stable catalysts for ethanol steam reforming. For this purpose, La_1-xMg_xAl_1-yNi_yO₃ (x=0.1; y=0, 0.1, 0.2, 0.3) perovskites were synthetized by the citrate method. Ni segregation is evident for a substitution level higher than 0.2. The segregation of Ni as NiO generated species interacts with different metal-support after the reduction step. The y=0.1 catalyst presents the highest H₂ yield value about 85% during reaction time, with low mean values of CH₄ and CO selectivities of 3.4% and 11%, respectively and a low carbon formation. The better performance of y=0.1 catalyst could be attributed to the minor proportion of segregated phases, thus a controlled expulsion of Ni is successfully reached.
- perovskites,
- catalyst design,
- ethanol,
- steam reforming
1. [1]
  CHORKENDORFF I, NIEMANTSVERDRIET J W. Concepts of Modern Catalysis and Kinetics[M]. Wiley Editorial. 2003.
2. [2]
  ARAMOUNI A K, TOUMA J G, TARBOUSH B A, ZEAITER J M. Catalyst design for dry reforming of methane:Analysis review[J]. Renewable Sustainable Energy Rev, 2017,82(part 3):2570-2585.
3. [3]
  CHOI S O, MOON S H. Performance of La_1-xCe_xFe_0.7Ni_0.3O₃ perovskite catalysts for methane steam reforming[J]. Catal Today, 2009,146(1):148-153.
4. [4]
  PALCHEVA R, OLSBYE U, PALCUT M, RAUWEL P, TYULIEV G, VELINOV N, FJELLVÄG H H. Rh promoted La_0.75Sr_0.25(Fe_0.8Co_0.2)_1-xGa_xO_3-δ perovskite catalysts:Characterization and catalytic performance for methane partial oxidation to synthesis gas[J]. Appl Surf Sci, 2015,357(part A):45-54.
5. [5]
  NI M, LEUNG D, LEUNG M. A review on reforming bio-ethanol for hydrogen production[J]. Int J Hydrogen Energy, 2007,32(15):3238-3247. doi: 10.1016/j.ijhydene.2007.04.038
6. [6]
  PEREIRA E B, RAMÍREZ D E L A, PISCINA P, MARTI S, HOMS N. H₂ production by oxidative steam reforming of ethanol over K promoted Co-Rh/CeO₂-ZrO₂ catalysts[J]. Energy Environ Sci, 2010,3:487-493. doi: 10.1039/b924624j
7. [7]
  HAN X, YU Y, HE H, SHAN W. Hydrogen production from oxidative steam reforming of ethanol over rhodium catalysts supported on Ce-La solid solution[J]. Int J Hydrogen Energy, 2013,38(25):10293-10304. doi: 10.1016/j.ijhydene.2013.05.137
8. [8]
  COSTA L O, VASCONCELOS S M, PINTO A L, SILVA A M, MATTOS L V, NORONHA F B. Rh/CeO₂ catalyst preparation and characterization for hydrogen production from ethanol partial oxidation[J]. J Mater Sci, 2008,43(2):440-449. doi: 10.1007/s10853-007-1982-2
9. [9]
  KRALEVA E, SOKOLOV S, NASILLO G, BENTRUP U, EHRICH H. Catalytic performance of CoAlZn and NiAlZn mixed oxides in hydrogen production by bio-ethanol partial oxidation[J]. Int J Hydrogen Energy, 2014,39(1):209-220. doi: 10.1016/j.ijhydene.2013.10.072
10. [10]
  BEYHAN S, LÉGER J M, KADIRGAN F. Understanding the influence of Ni, Co, Rh and Pd additionto PtSn/C catalyst for the oxidation of ethanol by in situ Fourier transform infrared spectroscopy[J]. Appl Catal B:Environ, 2014,144:66-74. doi: 10.1016/j.apcatb.2013.07.020
11. [11]
  CHEN H Q, YU H, YANG G X, PENG F, WANG H J, WANG J. Auto-thermal ethanol micro-reformer with a structural Ir/La₂O₃/ZrO₂ catalyst for hydrogen production[J]. Chem Eng J, 2011,167(1):322-327. doi: 10.1016/j.cej.2010.12.077
12. [12]
  SILVA A M, COSTA L O, BARANDAS A P, BORGES L E, MATTOS L V, NORONHA F B. Effect of the metal nature on the reaction mechanism of the partial oxidation of ethanol over CeO₂-supported Pt and Rh catalysts[J]. Catal Today, 2008,133-135:755-761. doi: 10.1016/j.cattod.2007.12.103
13. [13]
  FRUSTERI F, FRENI S. Bio-ethanol, a suitable fuel to produce hydrogen for a molten carbonate fuel cell[J]. J Power Sources, 2007,173(1):200-209. doi: 10.1016/j.jpowsour.2007.04.065
14. [14]
  BION N, EPRON F, DUPREZ D. Bioethanol reforming for H₂ production. A comparison with hydrocarbon reforming[J]. Catalysis, 2010,22:1-55.
15. [15]
  HARYANTO A, FERNANDO S, MURALI N, ADHIKARI S. Current status of hydrogen production techniques by steam reforming of ethanol:A Review[J]. Energy Fuels, 2005,19(5):2098-2106. doi: 10.1021/ef0500538
16. [16]
  BENGAARD H S, NORSKOV J K, SEHESTED J, CLAUSEN B S, NIELSEN L P, MOLENBROEK A M, ROSTRUP-NIELSEN J R. Steam reforming and graphite formation on Ni catalysts[J]. J Catal, 2002,209(2):365-384. doi: 10.1006/jcat.2002.3579
17. [17]
  BOROWIECKI T. Nickel catalysts for steam reforming of hydrocarbons; size of crystallites and resistance to coking[J]. Appl Catal, 1982,4:223-231. doi: 10.1016/0166-9834(82)80104-8
18. [18]
  AGÜERO F, MORALES M R, LARREGOLA S, IZURIETA E, LOPEZ E, CADUS L E. La_1-xCa_xAl_1-yNi_yO₃ perovskites used as precursors of nickel based catalysts for ethanol steam reforming[J]. Int J Hydrogen Energy, 2015,4015510. doi: 10.1016/j.ijhydene.2015.08.051
19. [19]
  COURTY P, AJOT H, MARCILLY C, DELMON B. Oxydes mixtes ou en solution solide sous forme très divisé e obtenus par décomposition thermique de précurseurs amorphes[J]. Powder Technol, 1973,7(1):21-38. doi: 10.1016/0032-5910(73)80005-1
20. [20]
  RIETVELD H M. A profile refinement method for nuclear and magnetic structures[J]. Appl Crystallogr, 1969,2:65-71. doi: 10.1107/S0021889869006558
21. [21]
  RODRIGUEZ CARVAJAL. Recent advances in magnetic-structure determination by neutron power diffraction[J]. Phys B, 1993,192(1/2):55-69.
22. [22]
  WU Y J, DÍAZ ALVARADO F, SANTOS J C, GRACIA F, CUNHA A F, RODRIGUES A E. Sorption-enhanced steam reforming of ethanol:thermodynamic comparison of CO₂ sorbents[J]. Chem Eng Technol, 2012,35(5):847-858. doi: 10.1002/ceat.v35.5
23. [23]
  CUNHA A F, WU Y J, DÍAZ ALVARADO F A, SANTOS J C, VAIDYA P D, RODRIGUES A E. CAN, Steam reforming of ethanol on a Ni/Al₂O₃ catalyst coupled with a hydrotalcite-like sorbent in a multilayer pattern for CO₂ uptake[J]. Can J Chem Eng, 2012,90(6):1514-1526. doi: 10.1002/cjce.v90.6
24. [24]
  SÁNCHEZ-SÁNCHEZ M C, NAVARRO R M, FIERRO J L G. Ethanol steam reforming over Ni/M_xO_y-Al₂O₃ (M-Ce, La, Zr and Mg) catalysts:influence of support on the Hydrogen production[J]. Int J Hydrogen Energy, 2007,321462. doi: 10.1016/j.ijhydene.2006.10.025
25. [25]
  HARDINI D, YOON C, HON J, YOON S, NAM S, LIM T. Influence of preparation methods and OSC on activity and stability[J]. Catal Lett, 2012,142(2):205-212. doi: 10.1007/s10562-011-0746-4
26. [26]
  RIBEIRO N, NETO R, MOYA S, SOUZA M, SCHMAL M. Synthesis of NiAl₂O₄ with high surface area as precursor of Ni nanoparticles for hydrogen production[J]. Int J Hydrogen Energy, 2010,35(21):11725-11732. doi: 10.1016/j.ijhydene.2010.08.024
27. [27]
  GALLEGO G S, MONDRAGÓN F, BARRAULT J, TATIBOUËT J-M, BATIOT-DUPEYRAT C. CO₂ reforming of CH₄ over La-Ni based perovskite precursors[J]. Appl Catal A:Gen, 2006,311(1):164-171.
28. [28]
  SIERRA GALLEGO G, MONDRAGON F, TATIBOUËT J-M, BARRAULT J, BATIOT-DUPEYRAT C. Carbon dioxide reforming of methane over La₂NiO₄ as catalyst precursor and characterization of carbon deposition[J]. Catal Today, 2008,133-135:200-209. doi: 10.1016/j.cattod.2007.12.075
29. [29]
  JIRATOVA K, MIKULOVA J, KLEMPA J, GRYGAR T, BASTL Z, KOVANDA F. Modification of Co-Mn-Al mixed oxide with potassium and its effect on deep oxidation of VOC[J]. Appl Catal A:Gen, 2009,361:106-116. doi: 10.1016/j.apcata.2009.04.004
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沈阳化工大学材料科学与工程学院沈阳 110142