Citation: WANG Zhuting, SUN Shumen. SYNTHESIS AND CHARACTERIZATION OF TITANOCENE POLYMER DERIVATIVES*[J]. Chinese Journal of Polymer Science, ;1988, 6(4): 359-364. shu

SYNTHESIS AND CHARACTERIZATION OF TITANOCENE POLYMER DERIVATIVES*

WANG Zhuting ,
SUN Shumen

Received Date: 14 November 1987

Titanocene polymer derivatives with potential antitumor properties were synthesized by interfacial condensation. The preformed polymers used are PAA (polyacrylic acid), CPSMA (1:1 alternating copolymer of styrene and maleic anhydride) and DVEMA (1:2 copolymer of divinyl ether and maleic anhydride). The ratio of practical and theoretical titanium content is 73.6%, 92.2% and 86.2% for PAA, CPSMA and DVEMA polymer derivatives respectively. The IR spectra of the polymer derivatives possess the characteristic absorptions of titanocene.XPS(X-ray photoelectron spectroscopy) of O1s and Ti2p3/2 supports the existence of Ti-O bonding.
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