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Citation: Wu Mingmei, Su Qiang, Hu Gang, Du Senlin, Ren Yufang. Pteparation and Properties of Telluratocuprate (Ⅱ,Ⅲ) Complexes[J]. Chinese Journal of Applied Chemistry, ;1995, 12(5): 33-36. shu

Pteparation and Properties of Telluratocuprate (Ⅱ,Ⅲ) Complexes

Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 17 November 1994
Revised Date: 6 March 1995

Detailed investigation on the preparation and properties of telluratocuprate(Ⅱ,Ⅲ) complexes has been performed. In the solution of H₆TeO₆/KOH,Cu(Ⅲ) complex was obtained by adopting ozone as oxidant and a new copper(Ⅲ) compound Ba₄K[Cu (H₂TeO₆)₂](OH)₄·6H₂O was isolated. The cyclic voltammogram of "Cu(Ⅲ)/Cu(Ⅱ)"couple in alka-line solution was described. According to the electronic spectra and Cu_2p XPS of the new Cu(Ⅲ) compound, Na₄H[Cu(H₂TeO₆)₂]·17H₂O and related Cu(Ⅱ) complexes, the ligand field parameters and the binding energies of Cu_2p3/2 for these Cu(Ⅲ) and Cu(Ⅱ) complexes were determined.
- telluratocuprate(Ⅱ,Ⅲ) complex,
- ozone oxidation,
- voltammogram,
- electronic spectrum,
- XPS
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