Citation: Ernest Koranteng, Yi-Yin Liu, Si-Yue Liu, Qiang-Xian Wu, Liang-Qiu Lu, Wen-Jing Xiao. Practical C-P bond formation via heterogeneous photoredox and nickel synergetic catalysis[J]. Chinese Journal of Catalysis, ;2019, 40(12): 1841-1846. doi: S1872-2067(19)63379-6 shu

Practical C-P bond formation via heterogeneous photoredox and nickel synergetic catalysis

a CCNU-uOttawa Joint Research Centre, Hubei International Scientific and Technological Cooperation Base of Pesticide and Green Synthesis, Key Laboratory of Pesticides & Chemical Biology Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, Hubei, China;
b State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, Gansu, China

Received Date: 19 April 2019
Revised Date: 11 May 2019

Fund Project: We are grateful to the National Science Foundation of China (21822103, 21820102003, 21772052, 21772053, 21572074, 21472057), the Program of Introducing Talents of Discipline to Universities of China (111 Program, B17019), the Natural Science Foundation of Hubei Province (2017AHB047), and the International Joint Research Center for Intelligent Biosensing Technology and Health for support of this research.

An efficient C-P bond formation reaction was developed by virtue of the synergetic catalysis strategy by merging heterogeneous photocatalysis and nickel catalysis. This platform utilizing cadmium sulfide semiconductors as heterogeneous photocatalysts and nickel complexes as transition metal catalysts provided a variety of organophosphorus compounds from readily available aryl and vinyl halides, as well as aryl triflates, with generally a good-to-excellent reaction efficiency (31 examples, 46%-98% yields). The current protocol features mild reaction conditions, a broad substrate scope, recyclability of photocatalysts, and inexpensive catalysts, thus defining the practical and economic proprieties of the present catalyst system.
- Photoredox catalysis,
- Nickel catalysis,
- Construction of carbon-phosphorus bond,
- Heterogeneous
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