Citation: Zhong-Pan Hu, Dandan Yang, Zheng Wang, Zhong-Yong Yuan. State-of-the-art catalysts for direct dehydrogenation of propane to propylene[J]. Chinese Journal of Catalysis, ;2019, 40(9): 1233-1254. doi: S1872-2067(19)63360-7 shu

State-of-the-art catalysts for direct dehydrogenation of propane to propylene

a Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Institute of New Catalytic Materials Science, School of Materials Science and Engineering, Nankai University, Tianjin 300350, China;
b State Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, Ningxia, China

Received Date: 28 January 2019

Fund Project: This work was supported by the National Natural Science Foundation of China (21421001, 21573115), the Fundamental Research Funds for the Central Universities (63185015), and the Foundation of State Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering (2017-K13).

With growing demand for propylene and increasing production of propane from shale gas, the technologies of propylene production, including direct dehydrogenation and oxidative dehydrogenation of propane, have drawn great attention in recent years. In particular, direct dehydrogenation of propane to propylene is regarded as one of the most promising methods of propylene production because it is an on-purpose technique that exclusively yields propylene instead of a mixture of products. In this critical review, we provide the current investigations on the heterogeneous catalysts (such as Pt, CrO_x, VO_x, GaO_x-based catalysts, and nanocarbons) used in the direct dehydrogenation of propane to propylene. A detailed comparison and discussion of the active sites, catalytic mechanisms, influencing factors (such as the structures, dispersions, and reducibilities of the catalysts and promoters), and supports for different types of catalysts is presented. Furthermore, rational designs and preparation of high-performance catalysts for propane dehydrogenation are proposed and discussed.
- Propane dehydrogenation,
- Propylene,
- Heterogeneous catalyst,
- Active site,
- Catalytic mechanism
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