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Citation: GUO Lei, HU Ge, LI Wenpo, ZHANG Shengtao. Underpotential Deposition of Zinc on Au Electrode[J]. Chinese Journal of Applied Chemistry, ;2013, 30(2): 214-219. doi: DOI:10.3724/SP.J.1095.2013.20090 shu

Underpotential Deposition of Zinc on Au Electrode

1.
College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China

Corresponding author: LI Wenpo,
Received Date: 12 March 2012
Available Online: 27 April 2012
Fund Project: 重庆市自然科学基金重点项目(CSTC,2008BC4020)资助 (CSTC,2008BC4020)

The underpotential deposition(UPD) of zinc from alkaline media on Au substrate has been studied by cyclic voltammetry and chronoampermetry.Experimental conditions such as the concentration of zinc precursor and scanning rate have been investigated.The analysis of the experimental data clearly showed the UPD process was initiated at-0.935 V(vs.SCE).In adaition,the concentration change of metal cation may affect the kinetics of the UPD process.The potentiostatic transients suggested an adatom-incorporation limited,two-dimensional(2D) instantaneous nucleation and growth mechanism.In addition,the adsorption of hydroxyl group could exert significant influence on the UPD of zinc on Au.
- zinc,
- Au electrode,
- underpotential deposition
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