Citation: Yao Biao, Wu Jiahao, Wang Yu, Jiang Huanfeng. Methods of Transition Metal-Catalyzed Asymmetric Oxidation[J]. Chinese Journal of Organic Chemistry, ;2020, 40(10): 3044-3064. doi: 10.6023/cjoc202005095 shu

Methods of Transition Metal-Catalyzed Asymmetric Oxidation

Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641

Corresponding author: Jiang Huanfeng, jianghf@scut.edu.cn
Received Date: 31 May 2020
Revised Date: 6 July 2020
Available Online: 11 August 2020
Fund Project: the National Key Research and Development Program of China 2016YFA06002900Project supported by the National Key Research and Development Program of China (No. 2016YFA06002900) and the Key Research and Development Program of Guangdong Province (No. 2020B010188001)the Key Research and Development Program of Guangdong Province 2020B010188001

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Transition metal-catalyzed asymmetric oxidation, as one of important research targets of chiral synthesis, provides a direct, practical route for the synthesis of various chiral bioactive products and drugs, and has received much attention. The recent progress of the methods of transition metal-catalyzed asymmetric oxidation, especially, asymmetric oxidative functionalization of olefins, C-H bond asymmetric oxidation reaction, asymmetric BV oxidation and sulfide asymmetric oxidation is elaborated. Outlook of those issuesis is also discussed.
- transition metal catalysis,
- asymmetric oxidation,
- enantioselectivity,
- olefin,
- C-H activation
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沈阳化工大学材料科学与工程学院沈阳 110142