Citation: Zhang Huifang, Qiu Zaozao, Xie Zuowei. Recent Advances in Transition Metal-Promoted Multicomponent Cascade Reactions for Controlled Synthesis of Complex Carborane Derivatives[J]. Chinese Journal of Organic Chemistry, ;2020, 40(10): 3203-3213. doi: 10.6023/cjoc202005079 shu

Recent Advances in Transition Metal-Promoted Multicomponent Cascade Reactions for Controlled Synthesis of Complex Carborane Derivatives

Zhang Huifang ^a,b ,
Qiu Zaozao ^b,c,, ,
Xie Zuowei ^b,d,,

a.
School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007
b.
Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
c.
CAS Key Laboratory of Energy Regulation Materials, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
d.
Department of Chemistry, The Chinese University of Hong Kong, Hong Kong

Corresponding author: Qiu Zaozao, qiuzz@sioc.ac.cn Xie Zuowei, zxie@cuhk.edu.hk
Received Date: 28 May 2020
Revised Date: 15 June 2020
Available Online: 19 June 2020
Fund Project: Chinese Academy of Sciences, and the Hong Kong Research Grants Council 14306519National Natural Science Foundation of China 21772223Project supported by the National Natural Science Foundation of China (No. 21772223), the Science and Technology Commission of Shanghai Municipality (No. 18590760800), the Chinese Academy of Sciences, and the Hong Kong Research Grants Council (No. 14306519)Science and Technology Commission of Shanghai Municipality 18590760800

Figures(22)

Carboranes are a class of carbon-boron molecular clusters with exceptional thermal and chemical stabilities. They are finding a variety of applications in medicine, materials, and coordination/organometallic chemistry as functional building blocks. To this end, the selective functionalization of carboranes has received growing research interests. Transition metal-promoted multicomponent cascade reactions are particularly attractive since they have the advantages of step- and atom- economy for the construction of complex products from readily available starting materials by simple operations. The recent advances in transition metal-promoted multicomponent cascade reactions for selective functionalization of carboranes are summarized in this focus review. The related reaction mechanisms and challenges in this research area are also discussed.
- borane cluster,
- carborane,
- transition metal,
- functionalization,
- cascade reaction
1. [1]
  (a) Grimes, R. N. Carboranes, 3rd ed., Academic Press, Amsterdam, 2016.
  (b) Hosmane, N. S. Boron Science: New Technologies and Application, CRC Press, Boca Raton, FL, 2012.
2. [2]
  (a) Scholz, M.; Hey-Hawkins, E. Chem. Rev. 2011, 111, 7035.
  (b) Leśnikowski, Z. J. J. Med. Chem. 2016, 59, 7738.
3. [3]
  (a) Hosmane, N. S.; Maguire, J. A. In Comprehensive Organometallic Chemistry Ⅲ, Vol. 3, Eds.: Crabtree, R. H.; Mingos, D. M. P., Elsevier, Oxford, 2007, Chapter 5.
  (b) Xie, Z. Acc. Chem. Res. 2003, 36, 1.
  (c) Yao, Z.-J.; Jin, G.-X. Coord. Chem. Rev. 2013, 257, 2522.
  (d) Qiu, Z.; Ren, S.; Xie, Z. Acc. Chem. Res. 2011, 44, 299.
  (e) Estrada, J.; Lavallo, V. Angew. Chem. Int. Ed. 2017, 56, 9906.
  (f) El-Hellani, A.; Lavallo, V. Angew. Chem. Int. Ed. 2014, 53, 4489.
  (g) Fisher, S. P.; Tomich, A. W.; Lovera, S. O.; Kleinsasser, J. F.; Guo, J.; Asay, M. J.; Nelson, H. M.; Lavallo, V. Chem. Rev. 2019, 119, 8262.
  (h) Yao, Z.-J.; Yu, W.-B.; Lin, Y.-J.; Huang, S.-L.; Li, Z.-H.; Jin, G.-X. J. Am. Chem. Soc. 2014, 136, 2825.
  (i) Gao, Y.; Guo, S.-T.; Cui, P.-F.; Aznarez, F.; Jin, G.-X. Chem. Commun. 2019, 55, 210.
  (j) Cui, P.-F.; Gao, Y.; Guo, S.-T.; Lin, Y.-J.; Li, Z.-H.; Jin, G.-X. Angew. Chem. Int. Ed. 2019, 58, 8129.
4. [4]
  (a) Jude, H.; Disteldorf, H.; Fischer, S.; Wedge, T.; Hawkridge, A. M.; Arif, A. M.; Hawthorne, M. F.; Muddiman, D. C.; Stang, P. J. J. Am. Chem. Soc. 2005, 127, 12131.
  (b) Koshino, M.; Tanaka, T.; Solin, N.; Suenaga, K.; Isobe, H.; Nakamura, E. Science 2007, 316, 853.
  (c) Dash, B. P.; Satapathy, R.; Gaillard, E. R.; Maguire, J. A.; Hosmane, N. S. J. Am. Chem. Soc. 2010, 132, 6578.
  (d) Kung, C.-W.; Otake, K.; Buru, C. T.; Goswami, S.; Cui, Y.; Hupp, J. T.; Spokoyny, A. M.; Farha, O. K. J. Am. Chem. Soc. 2018, 140, 3871.
  (e) Villagómez, C. J.; Sasaki, T.; Tour, J. M.; Grill, L. J. Am. Chem. Soc. 2010, 132, 16848.
  (f) Qian, E. Q.; Wixtrom, A. I.; Axtell, J. C.; Saebi, A.; Rehak, P.; Han, Y.; Moully, E. H.; Mosallaei, D.; Chow, S.; Messina, M.; Wang, J.-Y.; Royappa, A. T.; Rheingold, A. L.; Maynard, H. D.; Kral, P.; Spokoyny, A. M. Nat. Chem. 2017, 9, 333.
  (g) Saha, A.; Oleshkevich, E.; Viñas, C.; Teixidor, F. Adv. Mater. 2017, 29, 1704238.
  (h) Guo, J.; Liu, D.; Zhang, J.; Zhang, J.; Miao, Q.; Xie, Z. Chem. Commun. 2015, 51, 12004.
  (i) Jung, D.; Saleh, L. M. A.; Berkson, Z. J.; El-Kady, M. F.; Hwang, J. Y.; Mohamed, N.; Wixtrom, A. I.; Titarenko, E.; Shao, Y.; McCarthy, K.; Guo, J.; Martini, I. B.; Kraemer, S.; Wegener, E. C.; Saint-Cricq, P.; Ruehle, B.; Langeslay, R. R.; Delferro, M.; Brosmer, J. L.; Hendon, C. H.; Gallagher-Jones, M.; Rodriguez, J.; Chapman, K. W.; Miller, J. T.; Duan, X.; Kaner, R. B.; Zink, J. I.; Chmelka, B. F.; Spokoyny, A. M. Nat. Mater. 2018, 17, 341.
  (j) Cui, P.-F.; Lin, Y.-J.; Li, Z.-H.; Jin, G.-X. J. Am. Chem. Soc. 2020, 142, 8532.
5. [5]
  (a) Mukherjee, S.; Thilagar, P. Chem. Commun. 2016, 52, 1070.
  (b) Núñez, R.; Tarrés, M.; Ferrer-Ugalde, A.; de Biani, F. F.; Teixidor, F. Chem. Rev. 2016, 116, 14307.
  (c) Li, X.; Yan, H.; Zhao, Q. Chem. Eur. J. 2016, 22, 1888.
6. [6]
  (a) Heying, T. L.; Ager, J. W.; Clark, S. L.; Mangold, D. J.; Goldstein, H. L.; Hillman, M.; Polak, R. J.; Szymanski, J. W. Inorg. Chem. 1963, 2, 1089.
  (b) Fein, M. M.; Bobinski, J.; Mayes, N.; Schwartz, N.; Cohen, M. S. Inorg. Chem. 1963, 2, 1111.
  (c) El-Zaria, M. E., Keskar, K., Genady, A. R., Ioppolo, J. A., McNulty, J.; Valliant, J. F. Angew. Chem. Int. Ed. 2014, 53, 5156.
7. [7]
  (a) Wu, S.; Jones, M., Jr. Inorg. Chem. 1986, 25, 4802.
  (b) Bregadze, V. I. Chem. Rev. 1992, 92, 209.
  (c) Viñas, C.; Benakki, R.; Teixidor, F.; Casabó, J. Inorg. Chem. 1995, 34, 3844.
  (d) Gomez, F. A.; Johnson, S. E.; Hawthorne, M. F. J. Am. Chem. Soc. 1991, 111, 5915.
  (e) Gomez, F. A.; Hawthorne, M. F. J. Org. Chem. 1992, 57, 1384.
  (f) Anderson, K. P.; Mills, H. A.; Mao, C.; Kirlikovali, K. O.; Axtell, J. C.; Rheingold, A. L.; Spokoyny, A. M. Tetrahedron 2019, 75, 187.
8. [8]
  (a) Lu, J.-Y.; Wan, H.; Zhang, J.; Wang, Z.; Li, Y.; Du, Y.; Li, C.; Liu, Z.-T.; Liu, Z.-W.; Lu, J. Chem.-Eur. J. 2016, 22, 17542.
  (b) Tang, C.; Xie, Z. Angew. Chem. Int. Ed. 2015, 54, 7662.
  (c) Xie, Z. Sci. China Chem. 2014, 57, 1061.
  (d) Coult, R.; Fox, M. A.; Gill, W. R.; Herbertson, P. L.; MacBride, J. A. H.; Wade, K. J. Organomet. Chem. 1993, 462, 19.
9. [9]
  (a) Tang, C.; Zhang, J.; Xie, Z. Angew. Chem. Int. Ed. 2017, 56, 8642.
  (b) Tang, C.; Zhang, J.; Zhang, J.; Xie, Z. J. Am. Chem. Soc. 2018, 140, 16423.
10. [10]
  Lyu, H.; Zhang, J.; Yang, J.; Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2019, 141, 4219.
  (b) Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2015, 137, 3502.
  (c) Quan, Y.; Xie, Z. Angew. Chem. Int. Ed. 2016, 55, 1295.
  (d) Zhang, X.; Yan, H. Chem. Sci. 2018, 9, 3964.
  (e) Zhang, X.; Zheng, H.; Li, J.; Xu, F.; Zhao, J.; Yan, H. J. Am. Chem. Soc. 2017, 139, 14511.
  (f) Cao, K.; Huang, Y.; Yang, J.; Wu, J. Chem. Commun. 2015, 51, 7257.
  (g) Lin, F.; Yu, J.-L.; Shen, Y.; Zhang, S.-Q.; Spingler, B.; Liu, J.; Hong, X.; Duttwyler, S. J. Am. Chem. Soc. 2018, 140, 13798.
  (h) Xu, T. T.; Cao, K.; Zhang, C. Y.; Wu, J.; Ding, L. F.; Yang, J. Org. Lett. 2019, 21, 9276.
  (i) Xu, T. T.; Cao, K.; Zhang, C. Y.; Wu, J.; Jiang, L.; Yang, J. Chem. Commun. 2018, 54, 13603.
11. [11]
  (a) Liang, X.; Shen, Y.; Zhang, K.; Liu, J.; Duttwyler, S. Chem. Commun. 2018, 54, 12451.
  (b) Lin, F.; Shen, Y.; Zhang, Y.; Sun, Y.; Liu, J.; Duttwyler, S. Chem. Eur. J. 2018, 24, 551.
  (c) Lyu, H.; Quan, Y.; Xie, Z. Angew. Chem. Int. Ed. 2015, 54, 10623.
  (d) Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2014, 136, 15513.
  (e) Mirabelli, M. G. L.; Sneddon, L. G. J. Am. Chem. Soc. 1988, 110, 449.
  (f) Wu, J.; Cao, K.; Xu, T.-T.; Zhang, X.-J.; Jiang, L.; Yang, J.; Huang, Y., RSC Adv. 2015, 5, 91683.
  (g) Shen, Y.; Pan, Y.; Zhang, K.; Liang, X.; Liu, J.; Spingler, B.; Duttwyler, S. Dalton Trans. 2017, 46, 3135.
  (h) Shen, Y.; Zhang, K.; Liang, X.; Dontha, R.; Duttwyler, S. Chem. Sci. 2019, 10, 4177.
  (i) Cheng, R.; Qiu, Z.; Xie, Z. Chem. Eur. J. 2020, 26, 7121.
12. [12]
  (a) Chen, Y.; Au, Y. K.; Quan, Y.; Xie, Z. Sci. China Chem. 2019, 62, 74.
  (b) Quan, Y.; Tang, C.; Xie, Z. Chem. Sci. 2016, 7, 5838.
13. [13]
  Cheng, R.; Qiu, Z.; Xie, Z. Nat. Commun. 2017, 8, 14827. doi: 10.1038/ncomms14827
14. [14]
  Qiu, Z.; Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2013, 135, 12192. doi: 10.1021/ja405808t
15. [15]
  (a) Cui, C. X.; Zhang, J.; Qiu, Z.; Xie, Z. Dalton Trans. 2020, 49, 1380.
  (b) Au, Y. K.; Lyu, H.; Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2020, 142, 6940.
  (c) Lyu, H.; Quan, Y.; Xie, Z. Angew. Chem. Int. Ed. 2016, 55, 11840.
  (d) Cao, K.; Xu, T.-T.; Wu, J.; Jiang, L.; Yang, J. Chem. Commun. 2016, 52, 11446.
  (e) Li, C.-X.; Zhang, H.-Y.; Wong, T.-Y.; Cao, H.-J.; Yan, H.; Lu, C.-S. Org. Lett. 2017, 19, 5178.
16. [16]
  Lyu, H.; Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2016, 138, 12727. doi: 10.1021/jacs.6b07086
17. [17]
  Lyu, H.; Quan, Y.; Xie, Z. Chem. Eur. J. 2017, 23, 14866. doi: 10.1002/chem.201703006
18. [18]
  (a) Quan, Y.; Qiu, Z.; Xie, Z. Chem. Eur. J. 2018, 24, 2795.
  (b) Quan, Y.; Xie, Z. Chem. Soc. Rev. 2019, 48, 3660.
  (c) Yu, W.-B.; Cui, P.-F.; Gao, W.-X.; Jin, G.-X. Coord. Chem. Rev. 2017, 350, 300.
  (d) Zhang, X.; Yan, H. Coord. Chem. Rev. 2019, 378, 466.
19. [19]
  Qiu, Z.; Ren, S.; Xie, Z. Acc. Chem. Res. 2011, 44, 299. doi: 10.1021/ar100156f
20. [20]
  Qiu, Z.; Xie, Z. J. Am. Chem. Soc. 2009, 131, 2084. doi: 10.1021/ja809389k
21. [21]
  Deng, L.; Chan, H.-S.; Xie, Z. J. Am. Chem. Soc. 2006, 128, 7728. doi: 10.1021/ja061605j
22. [22]
  Ren, S.; Chan, H.-S.; Xie, Z. Organometallics 2009, 28, 4106. doi: 10.1021/om9002973
23. [23]
  Ren, S.; Qiu, Z.; Xie, Z. J. Am. Chem. Soc. 2012, 134, 3242. doi: 10.1021/ja211485t
24. [24]
  Ren, S.; Chan, H.-S.; Xie, Z. J. Am. Chem. Soc. 2009, 131, 3862. doi: 10.1021/ja900563u
25. [25]
  Ren, S.; Qiu, Z.; Xie, Z. Organometallics 2012, 31, 4435. doi: 10.1021/om300202p
26. [26]
  Ren, S.; Qiu, Z.; Xie, Z. Angew. Chem. Int. Ed. 2012, 51, 1010. doi: 10.1002/anie.201106212
27. [27]
  Quan, Y.; Zhang, J.; Xie, Z. J. Am. Chem. Soc. 2013, 135, 18742. doi: 10.1021/ja410233e
28. [28]
  Zhang, J.; Quan, Y.; Lin, Z.; Xie, Z. Organometallics 2014, 33, 3556. doi: 10.1021/om5004545
29. [29]
  Cui, C.-X.; Ren, S.; Qiu, Z.; Xie, Z. Dalton Trans. 2018, 47, 2453. doi: 10.1039/C7DT04751G
30. [30]
  Quan, Y.; Qiu, Z.; Xie, Z. J. Am. Chem. Soc. 2014, 136, 7599. doi: 10.1021/ja503489b
31. [31]
  Wang, Z.; Ye, H.; Li, Y.; Li, Y.; Yan, H. J. Am. Chem. Soc. 2013, 135, 11289. doi: 10.1021/ja4047075
32. [32]
  Zhang, R.; Zhu, L.; Liu, G.; Dai, H.; Lu, Z.; Zhao, J.; Yan, H. J. Am. Chem. Soc. 2012, 134, 10341. doi: 10.1021/ja303334t
33. [33]
  Qiu, Z.; Xie, Z. J. Am. Chem. Soc. 2010, 132, 16085. doi: 10.1021/ja1058789
34. [34]
  Lyu, H. Quan, Y.; Xie, Z. Chem. Sci. 2018, 9, 6390.
35. [35]
  Au, Y.-K.; Lyu, H.; Quan, Y.; Xie, Z. J. Am. Chem. Soc. 2019, 141, 12855. doi: 10.1021/jacs.9b06204
36. [36]
  Au, Y.-K.; Lyu, H.; Quan, Y.; Xie, Z. Chin. J. Chem. 2020, 38, 383. doi: 10.1002/cjoc.201900475
37. [37]
  (a) Li, J.; Logan, C. F.; Jones, M. Jr. Inorg. Chem. 1991, 30, 4866.
  (b) Zheng, Z.; Jiang, W.; Zinn, A. A.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1995, 34, 2095.
  (c) Harakas, G.; Vu, T.; Knobler, C. B.; Hawthorne, M. F. J. Am. Chem. Soc. 1998, 120, 6405.
  (d) Viñas, C.; Barberà, G.; Oliva, J. M.; Teixidor, F.; Welch, A. J.; Rosair, G. M. Inorg. Chem. 2001, 40, 6555.
38. [38]
  Ge, Y.; Zhang, J.; Qiu, Z.; Xie, Z. Angew. Chem. Int. Ed. 2020, 59, 4851. doi: 10.1002/anie.201914500
39. [39]
  (a) Poater, J.; Solà, M.; Viñas, C.; Teixidor, F. Chem. Eur. J. 2016, 22, 7437.
  (b) Axtell, J. C.; Saleh, L. M. A.; Qian, E. A.; Wixtrom, A. I.; Spokoyny, A. M. Inorg. Chem. 2018, 57, 2333.
  (c) Bolli, C.; Derendorf, J.; Keßler, M.; Knapp, C.; Scherer, H.; Schulz, C.; Warneke, J. Angew. Chem. Int. Ed. 2010, 49, 3536.
  (d) Kirchmann, M.; Wesemann, L. Dalton Trans. 2008, 2144.
  (e) Messina, M. S.; Axtell, J. C.; Wang, Y.; Chong, P.; Wixtrom, A. I.; Kirlikovali, K. O.; Upton, B. M.; Hunter, B. M.; Shafaat, O. S.; Khan, S. I.; Winkler, J. R.; Gray, H. B.; Alexandrova, A. N.; Maynard, H. D.; Spokoyny, A. M. J. Am. Chem. Soc. 2016, 138, 6952.
  (f) Peryshkov, D. V.; Strauss, S. H. Inorg. Chem. 2017, 56, 4072.
  (g) Wang, W.; Wang, X.; Cao, J.; Liu, J.; Qi, B.; Zhou, X.; Zhang, S.; Gabel, D.; Nau, W. M.; Assaf, K. I.; Zhang, H. Chem. Commun. 2018, 54, 2098.
  (h) Assaf, K. I.; Ural, M. S.; Pan, F.; Georgiev, T.; Simova, S.; Rissanen, K.; Gabel, D.; Nau, W. M. Angew. Chem. Int. Ed. 2015, 54, 6852.
  (i) Assaf, K. I.; Hennig, A.; Peng, S.; Guo, D.-S.; Gabel, D.; Nau, W. M. Chem. Commun. 2017, 53, 4616.
  (j) Jung, D.; Saleh, L. M. A.; Berkson, Z. J.; El-Kady, M. F.; Hwang, J. Y.; Mohamed, N.; Wixtrom, A. I.; Titarenko, E.; Shao, Y.; McCarthy, K.; Guo, J.; Martini, I. B.; Kraemer, S.; Wegener, E. C.; Saint-Cricq, P.; Ruehle, B.; Langeslay, R. R.; Delferro, M.; Brosmer, J. L.; Hendon, C. H.; Gallagher-Jones, M.; Rodriguez, J.; Chapman, K. W.; Miller, J. T.; Duan, X.; Kaner, R. B.; Zink, J. I.; Chmelka, B. F.; Spokoyny, A. M. Nat. Mater. 2018, 17, 341.
40. [40]
  Zhang, Y.; Sun, Y.; Lin, F.; Liu, J.; Duttwyler, S. Angew. Chem. Int. Ed. 2016, 55, 15609. doi: 10.1002/anie.201607867
41. [41]
  Zhang, Y.; Wang, T.; Wang, L.; Sun, Y.; Lin, F.; Liu, J.; Duttwyler, S. Chem. Eur. J. 2018, 24, 15812. doi: 10.1002/chem.201803455
42. [42]
  Cheng, R.; Li, B.; Wu, J.; Zhang, J.; Qiu, Z.; Tang, W.; You, S. L.; Tang, Y.; Xie, Z. J. Am. Chem. Soc. 2018, 140, 4508. doi: 10.1021/jacs.8b01754
1. [1]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
2. [2]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
3. [3]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
4. [4]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
5. [5]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
6. [6]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
7. [7]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
8. [8]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
9. [9]
  Xinyu Zhu , Meili Pang . Application of Functional Group Addition Strategy in Organic Synthesis. University Chemistry, 2024, 39(3): 218-230. doi: 10.3866/PKU.DXHX202308106
10. [10]
  Hongxia Yan , Rui Wu , Weixu Feng , Yan Zhao , Yi Yan . Innovation Inspired by Classical Chemistry: Luminescent Hyperbranched Polysiloxanes. University Chemistry, 2025, 40(4): 154-159. doi: 10.12461/PKU.DXHX202409010
11. [11]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
12. [12]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
13. [13]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
14. [14]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
15. [15]
  Lubing Qin , Fang Sun , Meiyin Li , Hao Fan , Likai Wang , Qing Tang , Chundong Wang , Zhenghua Tang . 原子精确的(AgPd)₂₇团簇用于硝酸盐电还原制氨：一种配体诱导策略来调控金属核. Acta Physico-Chimica Sinica, 2025, 41(1): 2403008-. doi: 10.3866/PKU.WHXB202403008
16. [16]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
17. [17]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013
18. [18]
  Hong RAO , Yang HU , Yicong MA , Chunxin LÜ , Wei ZHONG , Lihua DU . Synthesis and in vitro anticancer activity of phenanthroline-functionalized nitrogen heterocyclic carbene homo- and heterobimetallic silver/gold complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2429-2437. doi: 10.11862/CJIC.20240275
19. [19]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
20. [20]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1567)
HTML views(233)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142