Citation: Zhang Yanxia, Han Jianwei. Recent Progress of Chiral Iminophosphorane Catalysis[J]. Chinese Journal of Organic Chemistry, ;2020, 40(10): 3154-3165. doi: 10.6023/cjoc202005043 shu

Recent Progress of Chiral Iminophosphorane Catalysis

Zhang Yanxia ^a,b ,
Han Jianwei ^a,b,,

a.
Shanghai Key Laboratory of Functional Materials Chemistry, Department of Fine Chemicals, School of Chemistry & Molecular Engineering, East China University of Science and Technology, Shanghai 200237
b.
Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Corresponding author: Han Jianwei, jianweihan@ecust.edu.cn
Received Date: 18 May 2020
Revised Date: 19 June 2020
Available Online: 30 June 2020
Fund Project: National Natural Science Foundation of China 21472213National Natural Science Foundation of China 21202186Project supported by the National Natural Science Foundation of China (Nos. 21472213, 21202186) and the Croucher Foundation of Hong Kong

Figures(19)

As organocatalysts, organic base catalysts play an important role in the quest for optically pure compounds. Chiral iminophosphoranes, being organosuperbases, are very stable under air and moisture conditions, thereby providing an attractive platform for the design of various asymmetric organocatalysts. The recent achievements concerning chiral iminophosphoranes in the development of both organocatalysis and their applications in asymmetric synthesis are summarized and discussed.
- chiral iminophosphorane,
- asymmetric catalysis,
- research progress,
- organocatalysis
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