Citation: Dong Xiaojuan, Jin Weiwei, Liu Chenjiang. Recent Advances in Transition-Metal Catalyzed Defunctionalization Reaction[J]. Chinese Journal of Organic Chemistry, ;2020, 40(7): 1860-1873. doi: 10.6023/cjoc202002038 shu

Recent Advances in Transition-Metal Catalyzed Defunctionalization Reaction

School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046

Corresponding author: Jin Weiwei, wwjin0722@163.com Liu Chenjiang, pxylcj@126.com
Received Date: 26 February 2020
Revised Date: 10 April 2020
Available Online: 23 April 2020
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21702175, 21961037) and the 1000 Youth Talents PlanProject supported by the National Natural Science Foundation of China 21702175Project supported by the National Natural Science Foundation of China 21961037

Figures(33)

Functional groups are atoms or groups that determine the chemical properties of organic compounds. It often plays the role of guiding group in organic synthesis chemistry. Defunctionalization is the chemical transformation of a substrate with more functional groups into a compound with fewer functional groups, which has positive applications in solving environmental problems, resource shortage and biomass degradation. But due to the bond energy, heating, acid or base are often involved in defunctionalization. In recent years, defunctionalization has been moving toward a greener and more sustainable direction. Metal catalysis provides a new way for defunctionalization. The recent applications of different metal-mediated defunctionalization in organic synthesis and their mechanism are summarized.
- transition metal,
- defunctionalization,
- protonation,
- selectivity
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沈阳化工大学材料科学与工程学院沈阳 110142