Citation: Sun Yue, Guan Rui, Liu Zhaohong, Wang Yeming. Recent Advances in Hydroboration of Alkenes Catalyzed by Fe, Co and Ni[J]. Chinese Journal of Organic Chemistry, ;2020, 40(4): 899-912. doi: 10.6023/cjoc201909035 shu

Recent Advances in Hydroboration of Alkenes Catalyzed by Fe, Co and Ni

Sun Yue ^a ,
Guan Rui ^a ,
Liu Zhaohong ^a,, ,
Wang Yeming ^b,,

a.
Department of Chemistry, Northeast Normal University, Changchun 130024
b.
Institute of Chemical and Industrial Bioengineering, Jilin Engineering Normal University, Changchun 130052

Corresponding author: Liu Zhaohong, liuzh944@nenu.edu.cn Wang Yeming, wangyeming2011@163.com
Received Date: 26 September 2019
Revised Date: 15 November 2019
Available Online: 19 December 2019

Figures(18)

The synthesis of alkyl boronic esters has attracted much attention because of their wide applications in organic synthesis, materials and medicines. Transition-metal catalyzed hydroboration of alkenes was one of the most effective methods to construct alkyl boronic esters. Compared with rhodium, ruthenium, palladium, iridium and other precious metal catalysts, iron, cobalt and nickel catalysts were not only low cost, but also they displayed unique reactivity and selectivity. In this paper, the important advances in hydroboration of alkenes catalyzed by iron, cobalt and nickel have been summarized since 1994, including catalytic activity, selectivity and substrate scope of different catalytic systems.
- iron-catalysis,
- cobalt-catalysis,
- nickel-catalysis,
- hydroboration,
- regio-selectivity
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沈阳化工大学材料科学与工程学院沈阳 110142