Citation: Liu Quanyao, Shi Lei, Liu Ning. Pyridine Bridged Organocatalyst for the Synthesis of 3-Aryl-2-oxazolidinones from Carbon Dioxide, Terminal Epoxide, and Aryl Amine[J]. Chinese Journal of Organic Chemistry, ;2019, 39(10): 2882-2891. doi: 10.6023/cjoc201903030 shu

Pyridine Bridged Organocatalyst for the Synthesis of 3-Aryl-2-oxazolidinones from Carbon Dioxide, Terminal Epoxide, and Aryl Amine

Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003

Corresponding author: Liu Ning, ningliu@shzu.edu.cn
Received Date: 16 March 2018
Revised Date: 17 May 2019
Available Online: 3 October 2019

Figures(8)

A series of carboxyl group or hydroxyl group functionalized organocatalysts were synthesized and applied in three component reaction of carbon dioxide with epoxide, and aryl amines for the synthesis of 3-aryl-2-oxazolidinones. The method allows the reaction to proceed smoothly in the mild reaction conditions, together with excellent substrates scope of epoxides and aryl amines. The control experiments suggest that the cyclic carbonates are formed by the coupling of epoxides with carbon dioxide, which further react with the amino alcohol generated from epoxides and aryl amines, finally resulting in the desired products.
- organocatalyst,
- carbon dioxide,
- oxazolidinones,
- epoxide
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