Citation: Ma Rong, Song Gege, Xi Qiuzhen, Yang Liu, Li Er-Qing, Duan Zheng. Phosphine-Catalyzed[3+2] Annulations with γ-Methyl Allenoates[J]. Chinese Journal of Organic Chemistry, ;2019, 39(8): 2196-2202. doi: 10.6023/cjoc201901040 shu

Phosphine-Catalyzed[3+2] Annulations with γ-Methyl Allenoates

International Phosphorus Laboratory, International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001

Corresponding author: Li Er-Qing, lierqing@zzu.edu.cn Duan Zheng, duanzheng@zzu.edu.cn
Received Date: 25 January 2019
Revised Date: 22 March 2019
Available Online: 9 August 2019
Fund Project: the National Natural Science Foundation of China 21272218the National Natural Science Foundation of China 21702189the China Postdoctoral Science Foundation 2018T110737the Postdoctoral Research Grant in Henan Province 001701006Project supported by the National Natural Science Foundation of China (Nos. 21702189, 21672193, 21272218), the China Postdoctoral Science Foundation (Nos. 2017M610458, 2018T110737) and the Postdoctoral Research Grant in Henan Province (No. 001701006)the National Natural Science Foundation of China 21672193the China Postdoctoral Science Foundation 2017M610458

Figures(2)

The phosphine-catalyzed[3+2] annulation of γ-methyl allenoates with 2-arylidene-1H-indene-1, 3(2H)-diones is reported. In the reaction, a series of highly functionalized spiro[4.4]dec-6-ene skeletons were obtained in moderate to good yields and high diastereoselectivities. It should be noted that the perfect α-regioselective annulation adducts were obtained with simple PPh₃ catalyst.
- phosphine-catalyzed,
- γ-methyl allenoates,
- [3+2]annulation
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