Citation: Kong Shengnan, Qian Xuefeng, Shu Mouhai, Xiao Wende. Asymmetric Addition Reaction Catalyzed by 1- (2-Hydroxynaphtha-len-1-yl)naphthalen-2-ol Functionalized Porous Organic Polymer[J]. Chinese Journal of Organic Chemistry, ;2018, 38(10): 2754-2760. doi: 10.6023/cjoc201804011 shu

Asymmetric Addition Reaction Catalyzed by 1- (2-Hydroxynaphtha-len-1-yl)naphthalen-2-ol Functionalized Porous Organic Polymer

School of Chemistry & Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240

Corresponding author: Shu Mouhai, mhshu@sjtu.edu.cn
Received Date: 8 April 2018
Revised Date: 25 May 2018
Available Online: 7 October 2018
Fund Project: Project supported by the National Natural Science Foundation of China (No. 21271129)the National Natural Science Foundation of China 21271129

Figures(6)

A functionalized porous organic polymer POP-BINOL has been prepared and characterized by various techniques including carbon-13 cross-polarization magic-angle spinning nuclear magnetic resonance (¹³C CP/MAS NMR), fourier transform infrared spectroscopy (FT-IR), powder X-ray diffraction (pXRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption and thermogravimetric analysis (TG). After being treated with Ti (OⁱPr)₄, the composite material could be used as highly effective and reusable heterogeneous catalyst for asymmetric diethylzinc addition to aldehydes with medium and upper ee value.
- porous organic polymers,
- BINOL,
- heterogeneous catalysis,
- asymmetric addition reaction
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沈阳化工大学材料科学与工程学院沈阳 110142

Asymmetric Addition Reaction Catalyzed by 1- (2-Hydroxynaphtha-len-1-yl)naphthalen-2-ol Functionalized Porous Organic Polymer

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com