Citation: Xu Yueying, Wang Wei, Chen Jianzhuang, Lin Shaoliang. Preparation and Directional Photomanipulation of Azobenzene Containing Supramolecular Polymer Ordered Porous Film[J]. Chinese Journal of Organic Chemistry, ;2018, 38(8): 2161-2166. doi: 10.6023/cjoc201803037 shu

Preparation and Directional Photomanipulation of Azobenzene Containing Supramolecular Polymer Ordered Porous Film

Shanghai Key Laboratory of Advanced Polymeric Materials, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237

Corresponding author: Lin Shaoliang, slin@ecust.edu.cn
Received Date: 24 March 2018
Revised Date: 21 April 2018
Available Online: 3 August 2018
Fund Project: the National Natural Science Foundation of China 51573046Project supported by the National Natural Science Foundation of China (Nos. 51622301, 51573046), and the Project of Shanghai Municipality (No. 14SG29)the National Natural Science Foundation of China 51622301the Project of Shanghai Municipality 14SG29

Figures(7)

Supramolecular polymer can be formed from amphiphilic block copolymer polystyrene-b-poly(4-vinylpyridine) (PS-b-P4VP) and 4'-iodo-4-dimethylaminoazobenzene molecule through halogen bond. In this paper, honeycomb ordered porous films were prepared by static breath figure (BF) method by this supramolecular polymer. The effects of IAzo content and light illumination conditions on the morphology of supramolecular polymer porous film were studied in detail. The formation of the supramolecular polymer, the surface and the fracture morphology of the porous film were characterized by infrared spectroscopy and scanning electron microscopy. These results showed that with the increase of IAzo content, the pore size of supramolecular polymer porous film gradually increased. In addition, under the irradiation of linearly polarized light, the round hole structure of the porous film can be converted into rectangular holes or rhombic holes according to the change of polarization direction of linearly polarized light. The degree of deformation increases with the increase of azobenzene content and the extension of illumination time. The porous film prepared from this azobenzene-containing supramolecular polymer realizes the light regulation of porous structure by non-synthetic means.
- supramolecular polymer,
- ordered porous film,
- photomanipulation,
- azobenzene
1. [1]
  (a) Phillip, W. A. ; O'Neill, B. ; Rodwogin, M. ; Hillmyer, M. A. ; Cussler, E. L. ACS Appl. Mater. Interfaces 2010, 2, 847.
  (b) Wang, W. ; Yao, Y. ; Luo, T. -C. ; Chen, L. -Z. ; Lin, J. -P. ; Li, L. ; Lin, S. -L. ACS Appl. Mater. Interfaces 2017, 9, 4223.
  (c) Abidian, M. R. ; Kim, D. H. ; Martin, D. C. Adv. Mater. 2006, 18, 405.
2. [2]
  Widawski, G.; Rawiso, M.; François, B. Nature 1994, 369, 387. doi: 10.1038/369387a0
3. [3]
  Zhang, A.-J.; Bai. H.; Li, L. Chem. Rev. 2015, 115, 9801. doi: 10.1021/acs.chemrev.5b00069
4. [4]
  Wang, W.; Du, C.; Wang, X.-F.; He, X.-H.; Lin, J.-P.; Li, L.; Lin, S.-L. Angew. Chem., Int. Ed. 2014, 53, 12116. doi: 10.1002/anie.201407230
5. [5]
  De Greef, T. F. A.; Smulders, M. M. J.; Wolffs, M.; Schenning, A. P. H. J.; Sijbesma, R. P.; Meijer, E. W. Chem. Rev. 2009, 109, 5687. doi: 10.1021/cr900181u
6. [6]
  Vapaavuori, J.; Heikkinen, I. T. S.; Dichiarante, V.; Resnati, G.; Metrangolo, P.; Sabat, R. G.; Bazuin, C. G.; Priimagi, A.; Pellerin, C. Macromolecules 2015, 48, 7535. doi: 10.1021/acs.macromol.5b01813
7. [7]
  (a) Saccone, M. ; Dichiarante, V. ; Forni, A. ; Goulet-Hanssens, A. ; Cavallo, G. ; Vapaavuori, J. ; Terraneo, G. ; Barrett, C. J. ; Resnati, G. ; Metrangolo, P. ; Priimagi, A. J. Mater. Chem. C 2015, 3, 759.
  (b) Lee, Y. -J. ; Yang, S. -I. ; Kang, D. -S. ; Joo, S. -W. Chem. Phys. 2009, 361, 176.
8. [8]
  Wang, D.-R.; Wang, X.-G. Prog. Polym. Sci. 2013, 38, 271. doi: 10.1016/j.progpolymsci.2012.07.003
9. [9]
  Wang, W.; Shen, D.-F.; Li, X.; Yao, Y.; Lin, J.-P.; Wang, A.; Yu, J.; Wang, Z.-L.; Hong, S.-W.; Lin, Z.-Q.; Lin, S.-L. Angew. Chem., Int. Ed. 2018, 57, 2139. doi: 10.1002/anie.201712100
10. [10]
  Kong, X.-L.; Wang X.-F.; Luo T.-C.; Yao, Y.; Li, L.; Lin, S.-L. ACS Appl. Mater. Interfaces 2017, 9, 19345. doi: 10.1021/acsami.7b04273
11. [11]
  (a) Han, M. ; Morino, S. ; Ichimura, K. Macromolecules 2000, 33, 6360.
  (b) Karageorgiev, P. ; Neher, D. ; Schulz, B. ; Stiller, B. ; Pietsch, U. ; Giersig, M. ; Brehmer, L. Nat. Mater. 2005, 4, 699.
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Directional Photomanipulation of Azobenzene Containing Supramolecular Polymer Ordered Porous Film

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com