Citation: Chen Shuqi, Yang Wen, Yao Yongqi, Yang Xin, Deng Yingying, Yang Dingqiao. Progress in Ruthenium-Catalyzed Asymmetric Hydrogenation of β-Keto Esters[J]. Chinese Journal of Organic Chemistry, ;2018, 38(10): 2534-2552. doi: 10.6023/cjoc201802022 shu

Progress in Ruthenium-Catalyzed Asymmetric Hydrogenation of β-Keto Esters

Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry and Environment, South China Normal University, Guangzhou 510006

Corresponding author: Yang Dingqiao, yangdq@scnu.edu.cn
Received Date: 24 February 2018
Revised Date: 15 May 2018
Available Online: 7 October 2018
Fund Project: the Natural Science Foundation of Guangdong Province S2013020013091the City of Guangzhou Science and Technology Plan Projects 156300018the National Natural Science Foundation of China 21372090the National Natural Science Foundation of China 21172081Project supported by the National Natural Science Foundation of China (Nos. 21172081, 21372090), the Natural Science Foundation of Guangdong Province (No. S2013020013091) and the City of Guangzhou Science and Technology Plan Projects (No. 156300018)

Figures(17)

Ruthenium-catalyzed asymmetric hydrogenation of β-keto esters is one of the most effective methods for the synthesis of chiral β-hydroxy esters. The recent research progress in ruthenium-catalyzed asymmetric hydrogenation of β-keto esters is reviewed. Great attention was paid to the influences of chiral ligands, substrate structure, solvents and additives on the homogeneous asymmetric hydrogenation, as well as the influences of support materials and additives on the heterogeneous asymmetric hydrogenation.
- ruthenium catalyst,
- β-keto ester,
- asymmetric hydrogenation,
- research progress
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沈阳化工大学材料科学与工程学院沈阳 110142