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Citation: Tang Boxiao, Fang Xiaoniu, Kuang Renyun, Cai Jinhua, Wu Jianhong. Carrier-Free and Recyclable PdCl2-Catalyzed Suzuki-Miyaura and Mizoroki-Heck Reactions in Water/Ionic Liquid Media[J]. Chinese Journal of Organic Chemistry, ;2017, 37(11): 2956-2961. doi: 10.6023/cjoc201706016 shu

Carrier-Free and Recyclable PdCl2-Catalyzed Suzuki-Miyaura and Mizoroki-Heck Reactions in Water/Ionic Liquid Media

  • Key Laboratory of Coordination Chemistry of Jiangxi Province, Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jinggangshan University, Ji'an 343009

  • Corresponding author: Tang Boxiao, 520tangboxiao@163.com
  • Received Date: 14 June 2017
    Revised Date: 11 July 2017
    Available Online: 9 November 2017

    Fund Project: the National Natural Science Foundation of China 51363009Project supported by the National Natural Science Foundation of China (Nos. 21563015, 51363009) and the Natural Science Foundation of Jiangxi Province (No. 20151BAB203010)the Natural Science Foundation of Jiangxi Province 20151BAB203010the National Natural Science Foundation of China 21563015

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  • Efficient and unsupported protocols were developed for PdCl2-catalyzed Suzuki-Miyaura and Mizoroki-Heck reactions using water/ionic liquid systems to afford the cross-coupling products with excellent yields. It is noteworthy that the PdCl2/K2CO3/water/ionic liquid systems can be recovered and used for 3~5 cycles directly. The results suggest that the unsupported and recyclable systems can be extended to the other realm of C-C bond formation.
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