Citation: Wu Jiang, Li Jiawen, Li Hao, Zhu Chunyin. Visible Light Photoredox Catalysis Mediated Elementary Steps in Organometallic Reactions[J]. Chinese Journal of Organic Chemistry, ;2017, 37(9): 2203-2210. doi: 10.6023/cjoc201704030 shu

Visible Light Photoredox Catalysis Mediated Elementary Steps in Organometallic Reactions

Wu Jiang ^b ,
Li Jiawen ^a ,
Li Hao ^a ,
Zhu Chunyin ^a,,

a.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013
b.
State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Corresponding author: Zhu Chunyin, zhucycn@gmail.com
Received Date: 18 April 2017
Revised Date: 22 May 2017
Available Online: 7 September 2017
Fund Project: Project supported by the Qing Lan Project of Jiangsu Province

Figures(13)

Many organometallic reactions involve three elementary steps including oxidative addition, transamination, and reductive elimination. But sometimes very high barrier exists for this approach, leading to the failure of the reactions. The key development in recent reports is the implementation of visible-light photocatalysts as a means to induce the desired redox processes in a mild and selective manner. In this context, organometallic reactions mediated by photoredox catalysts could give rise to novel reactivity, thus this area has drawn much attention in organic chemistry community. In this review, prominent examples from the recent literatures are organized on the basis of the elementary transformation enabled by photoredox catalysis.
- organometallic reactions,
- elementary steps,
- visible light photoredox
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