Citation: Lin Wei, Cai Qi, Zheng Chunzhi, Zheng Yongxiang, Shi Daqing. Synthesis of Functionalized Coumarino[4, 3-d]pyrazolo[3, 4-b]pyridine Derivatives and Their Selective Recognition for Zn²⁺[J]. Chinese Journal of Organic Chemistry, ;2017, 37(9): 2392-2398. doi: 10.6023/cjoc201702032 shu

Synthesis of Functionalized Coumarino[4, 3-d]pyrazolo[3, 4-b]pyridine Derivatives and Their Selective Recognition for Zn²⁺

Lin Wei ^1,, ,
Cai Qi ¹ ,
Zheng Chunzhi ¹ ,
Zheng Yongxiang ² ,
Shi Daqing ^2,,

a.
School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001
b.
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123

Corresponding author: Lin Wei, linwei@jsut.edu.cn Shi Daqing, dqshi@suda.edu.cn
Received Date: 23 February 2017
Revised Date: 17 April 2017
Available Online: 2 September 2017
Fund Project: the National Natural Science Foundation of China 21502074Project supported by the National Natural Science Foundation of China (No. 21502074) and the Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions (No. 15KJA150006)the Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions 15KJA150006

Figures(8)

A series of functionalized coumarino[4, 3-d]pyrazolo[3, 4-b]pyridine derivatives 3a~3h were synthesized by the addition and cyclization of 3-acetoacetylcoumarin with 5-aminopyrazole catalyzed by CuSO₄. Some of the synthesized compounds had high fluorescence quantum yields. The properties of the compounds with cations such as Ag⁺, Cr³⁺, Co²⁺, Cu²⁺, Pb²⁺, Sn⁴⁺, Fe³⁺ and Zn²⁺ were examined by fluorescence spectroscopy. The results showed that compounds 3a and 3b have selective recognition for Zn²⁺.
- coumarino[4, 3-d]pyrazolo[3, 4-b]pyridine derivative,
- synthesis,
- fluorescence property,
- Zn²⁺,
- selective recognition
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Synthesis of Functionalized Coumarino[4, 3-d]pyrazolo[3, 4-b]pyridine Derivatives and Their Selective Recognition for Zn2+

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通讯作者: 陈斌, bchen63@163.com

Synthesis of Functionalized Coumarino[4, 3-d]pyrazolo[3, 4-b]pyridine Derivatives and Their Selective Recognition for Zn²⁺