Citation: Zeng Fei, Tang Linli, Chen Xiaoming, Li Zhizhang, Han Ying, Chen Chuanfeng. Complexation of Novel Water-Soluble Cylindrical Macrotricyclic Host and Paraquat[J]. Chinese Journal of Organic Chemistry, ;2016, 36(8): 1937-1941. doi: 10.6023/cjoc201603024 shu

Complexation of Novel Water-Soluble Cylindrical Macrotricyclic Host and Paraquat

Zeng Fei ^a,*,, ,
Tang Linli ^a ,
Chen Xiaoming ^a ,
Li Zhizhang ^a ,
Han Ying ^b ,
Chen Chuanfeng ^b,*,,

a.
Key Laboratory Comprehensive Utilization of Dominant Plants Resources in South Hunan, Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou 425199
b.
CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190

Corresponding author: Zeng Fei, zengfei@iccas.ac.cn Chen Chuanfeng, cchen@iccas.ac.cn
Received Date: 15 March 2016
Revised Date: 30 March 2016

Fund Project:

Figures(6)

The complexation between the novel water-soluble cylindrical macrotricyclic host and paraquat guests in both solution and solid state was investigated in detail. It was found that the host could form 1:1 complexes with paraquat salts in water solution and solid state. Interestingly, the complexation and decomplexation of the complexes between the host and the guest could be achieved by changing the pH of the solution, and the process could also be observed by naked eye.
- macrotricyclic host,
- paraquat,
- complexation,
- acid-base controlled
1. [1]
  Pedersen, C. J. J. Am. Chem. Soc. 1967, 89, 7017.
2. [2]
3. [3]
4. [4]
5. [5]
  Corbellini, F.; Knegtel, R. M.; Grootenhuis, P. D.; Crego-Cala- ma, M.; Reinhoudt, D. N. Chem. Eur. J. 2004, 11, 298. (b) Liu, Y.; Guo, D.-S.; Yang, E.-C.; Zhang, H.-Y.; Zhao, Y.-L. Eur. J. Org. Chem. 2005, 2005, 162. (c) Guo, D. S.; Wang, K.; Wang, Y. X.; Liu, Y. J. Am. Chem. Soc. 2012, 134, 10244. (d) Kulasekharan, R.; Ramamurthy, V. Org. Lett. 2011, 13, 5092. (e) Tu, C.; Zhu, L.; Li, P.; Chen, Y.; Su, Y.; Yan, D.; Zhu, X.; Zhou, G. Chem. Commun. 2011, 47, 6063. (f) Specht, A.; Bernard, P.; Goeldner, M.; Peng, L. Angew. Chem., Int. Ed. 2002, 41, 4706.
6. [6]
  Li, Z.; Yang, J.; Yu, G.; He, J.; Abliz, Z.; Huang, F. Chem. Commun. 2014, 50, 2841. (b) Si, W.; Chen, L.; Hu, X. B.; Tang, G.; Chen, Z.; Hou, J. L.; Li, Z. T. Angew. Chem., Int. Ed. 2011, 50, 12564. (c) Yu, G.; Xue, M.; Zhang, Z.; Li, J.; Han, C.; Huang, F. J. Am. Chem. Soc. 2012, 134, 13248. (d) Ma, Y.; Ji, X.; Xiang, F.; Chi, X.; Han, C.; He, J.; Abliz, Z.; Chen, W.; Huang, F. Chem. Commun. 2011, 47, 12340. (e) Chen, H.; Fan, J.; Hu, X.; Ma, J.; Wang, S.; Li, J.; Yu, Y.; Jia, X.; Li, C. Chem. Sci. 2015, 6, 197. (f) Ma, J.; Deng, H.; Ma, S.; Li, J.; Jia, X.; Li. C. Chem. Commun. 2015, 51, 6621.
7. [7]
  Cram, D. J.; Cram, J. M. Science 1974, 183, 803. (b) Wei, P.; Yan, X.; Huang, F. Chem. Soc. Rev. 2015, 44, 815. (c) Chen, C.-F. Chem. Commun. 2011, 47, 1674. (d) Jiang, Y.; Chen, C.-F. Eur. J. Org. Chem. 2011, 6377. (e) Han, Y.; Meng, Z.; Ma, Y.-X.; Chen, C.-F. Acc. Chem. Res. 2014, 47, 2026.
8. [8]
  Hoffart, D. J.; Tiburcio, J.; de la Torre, A.; Knight, L. K.; Loeb, S. J. Angew. Chem., Int. Ed. 2008, 47, 97. (b) Chen, L.; Zhang, Y. M.; Liu, Y. J. Phys. Chem. B 2012, 116, 9500. (c) Chen, L.; Zhang, H. Y.; Liu, Y. J. Org. Chem. 2012, 77, 9766. (d) Ji, X.; Zhang, M.; Yan, X.; Li, J.; Huang, F. Chem. Commun. 2013, 49, 1178.
9. [9]
  Zeng, F.; Chen, C.-F. Org. Biomol. Chem. 2015, 13, 1988.
10. [10]
  Connors, K. A. Binding Constants, John-Wiley and Sons, New York, 1987.
1. [1]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
2. [2]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
3. [3]
  Hui-Ying Chen , Hao-Lin Zhu , Pei-Qin Liao , Xiao-Ming Chen . Integration of Ru(Ⅱ)-Bipyridyl and Zinc(Ⅱ)-Porphyrin Moieties in a Metal-Organic Framework for Efficient Overall CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(4): 2306046-0. doi: 10.3866/PKU.WHXB202306046
4. [4]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057
5. [5]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
6. [6]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
7. [7]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
8. [8]
  Yuhao Chen , Zhuo Cheng , Qijun Hu , Jian Pei . 酸碱理论的发展历程. University Chemistry, 2025, 40(8): 368-375. doi: 10.12461/PKU.DXHX202412001
9. [9]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
10. [10]
  Jingping Li , Suding Yan , Jiaxi Wu , Qiang Cheng , Kai Wang . Improving hydrogen peroxide photosynthesis over inorganic/organic S-scheme photocatalyst with LiFePO₄. Acta Physico-Chimica Sinica, 2025, 41(9): 100104-0. doi: 10.1016/j.actphy.2025.100104
11. [11]
  Jingyi Xie , Qianxi Lü , Weizhen Qiao , Chenyu Bu , Yusheng Zhang , Xuejun Zhai , Renqing Lü , Yongming Chai , Bin Dong . Enhancing Cobalt―Oxygen Bond to Stabilize Defective Co₂MnO₄ in Acidic Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305021-0. doi: 10.3866/PKU.WHXB202305021
12. [12]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
13. [13]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-0. doi: 10.1016/j.actphy.2024.100039
14. [14]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
15. [15]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
16. [16]
  Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . Green H₂O₂ synthesis via melamine-foam supported S-scheme Cd_0.5Zn_0.5In₂S₄/S-doped carbon nitride heterojunction: synergistic interfacial charge transfer and local photothermal effect. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-0. doi: 10.1016/j.actphy.2025.100093
17. [17]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
18. [18]
  Tongyu Zheng , Teng Li , Xiaoyu Han , Yupei Chai , Kexin Zhao , Quan Liu , Xiaohui Ji . A DIY pH Detection Agent Using Persimmon Extract for Acid-Base Discoloration Popularization Experiment. University Chemistry, 2024, 39(5): 27-36. doi: 10.3866/PKU.DXHX202309107
19. [19]
  Wenhui Li , Changshuo Zhu , Xinyu Cui , Chenfei Zhao , Lina Qiu , Yan Li , Chuandong Wu , Min Yang , Yuan Zhuang . Visual Determination of Acid-Base Titration Endpoints Using Smartphone APP-Based Analysis. University Chemistry, 2025, 40(7): 328-335. doi: 10.12461/PKU.DXHX202409062
20. [20]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1137)
HTML views(266)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142