Citation: Li Wenfang, Zhu Junyan, Dong Zeyuan. Synthesis of Hollow Aromatic Helix and Their Selective Recognition for Alkali Metal Ions[J]. Chinese Journal of Organic Chemistry, ;2016, 36(7): 1668-1671. doi: 10.6023/cjoc201601004 shu

Synthesis of Hollow Aromatic Helix and Their Selective Recognition for Alkali Metal Ions

1.
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012

Corresponding author: Dong Zeyuan,
Received Date: 4 January 2016
Revised Date: 9 May 2016

Fund Project: the National Natural Science Foundation of China 21274051the National Natural Science Foundation of China 21574054

Figures(4)

A novel type of hollow aromatic helices was prepared according to an improved organic synthesis approach. By means of UV-Vis spectroscopy, the recognition and selectivity of aromatic helix (AH) for alkali metal ions were investigated. The results indicated that AH could specifically recognize the alkali metal ions with an order of Rb⁺ > K⁺ > Cs⁺ > Na⁺ > Li⁺. In addition, the fluorescence titration was carried out by adding Rb⁺ into the AH solution, which further underpinned the binding capacity and sensitive responsiveness of AH for the alkali metal ions.
- aromatic helix,
- hollow channel,
- alkali metal ions,
- selective recognition
1. [1]
  Hille, B. Ionic Channels of Excitable Membranes, 3rd ed., Sinauer Associates: Sunderland, MA, 2001.
2. [2]
  Tabushi, I.; Kuroda, Y.; Yokota, K. Tetrahedron Lett. 1982, 23(44), 4601.
3. [3]
  Cornell, B. A.; Braach-Maksvytis, V.; King, L.; Osman, P.; Raguse, B.; Wieczorek, L.; Pace, R. Nature 1997, 387(6633), 580.
4. [4]
  Das, G.; Talukdar, P.; Matile, S. Science 2002, 298(5598), 1600.
5. [5]
  Sakai, N.; Matile, S. Langmuir 2013, 29, 9031.
6. [6]
  Zhang, D.; Yang, Z.Y. J. Phys. Chem. B 2011, 115(49), 4333.
7. [7]
  Blake, A. J.; Cooke, P. A.; Doyle, K. J.; Gair, S.; Simpkins, N. S. Tetrahedron Lett. 1998, 39, 9093.
8. [8]
  Goto, H.; Katagiri, H.; Furusho, Y.; Yashima, E. J. Am. Chem. Soc. 2006, 128, 7176.
9. [9]
  Nakano, T.; Okamoto, Y. Chem. Rev. 2001, 101, 4013.
10. [10]
  de Witte, P. A. J.; Castriciano, M.; Cornelissen, J.J. L. M.; Scolaro, L. M.; Nolte, R. J. M.; Rowan, A. E. Chem. Eur. J. 2003, 9, 1775.
11. [11]
  Delsuc, N; Godde, F.; Kauffmann, B.; Léger, J. M.; Huc, I. J. Am. Chem. Soc. 2007, 129, 11348.
12. [12]
  Kudo, M.; Maurizot, V.; Kauffmann, B.; Tanatani, A.; Huc, I. J. Am. Chem. Soc. 2013, 135, 9628.
13. [13]
  Chandramouli, N.; Ferrand, Y.; Lautrette, G.; Kauffmann, B.; Mackereth, C. D.; Laguerre, M.; Dubreuil, D.; Huc, I. Nat. Chem. 2015, 7, 334.
14. [14]
  Zhu, J. Y.; Dong, Z. Y.; Lei, S. B.; Cao, L. L.; Yang, B.; Li, W. F.; Zhang, Y. C.; Liu, J. Q.; Shen, J. C. Angew. Chem., Int. Ed. 2015, 54, 3097.
15. [15]
  Ren, C. L.; Victor, M.; Zhao, H. Q.; Shen, J.; Zhou, F.; Ong, W. Q.; Du, Z. Y.; Zhang, K.; Su, H. B.; Zeng, H. Q. J. Am. Chem. Soc. 2011, 133, 13930.
16. [16]
17. [17]
  Berni, E.; Kauffmann, B.; Bao, C. Y.; Lefeuvre, J.; Bassani, D. M.; Huc, I. Chem. Eur. J. 2007, 13, 8463.
18. [18]
1. [1]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . 中空结构光催化剂. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-0. doi: 10.1016/j.actphy.2025.100071
2. [2]
  Renjie Xue , Chao Ma , Jing He , Xuechao Li , Yanning Tang , Lifeng Chi , Haiming Zhang . Catassembly in the Host-Guest Recognition of 2D Metastable Self-Assembled Networks. Acta Physico-Chimica Sinica, 2024, 40(9): 2309011-0. doi: 10.3866/PKU.WHXB202309011
3. [3]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
4. [4]
  Jingyi Xie , Qianxi Lü , Weizhen Qiao , Chenyu Bu , Yusheng Zhang , Xuejun Zhai , Renqing Lü , Yongming Chai , Bin Dong . Enhancing Cobalt―Oxygen Bond to Stabilize Defective Co₂MnO₄ in Acidic Oxygen Evolution. Acta Physico-Chimica Sinica, 2024, 40(3): 2305021-0. doi: 10.3866/PKU.WHXB202305021
5. [5]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
6. [6]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
7. [7]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
8. [8]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
9. [9]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
10. [10]
  Jun Huang , Pengfei Nie , Yongchao Lu , Jiayang Li , Yiwen Wang , Jianyun Liu . 丝光沸石负载自支撑氮掺杂多孔碳纳米纤维电容器及高效选择性去除硬度离子. Acta Physico-Chimica Sinica, 2025, 41(7): 100066-0. doi: 10.1016/j.actphy.2025.100066
11. [11]
  Zhi Chai , Huashan Huang , Xukai Shi , Yujing Lan , Zhentao Yuan , Hong Yan . Wittig反应的立体选择性. University Chemistry, 2025, 40(8): 192-201. doi: 10.12461/PKU.DXHX202410046
12. [12]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
13. [13]
  Yunhao Zhang , Yinuo Wang , Siran Wang , Dazhen Xu . Progress in Selective Construction of Functional Aromatics from Nitrogenous Cycloalkanes. University Chemistry, 2024, 39(11): 136-145. doi: 10.3866/PKU.DXHX202401083
14. [14]
  Xilin Zhao , Xingyu Tu , Zongxuan Li , Rui Dong , Bo Jiang , Zhiwei Miao . Research Progress in Enantioselective Synthesis of Axial Chiral Compounds. University Chemistry, 2024, 39(11): 158-173. doi: 10.12461/PKU.DXHX202403106
15. [15]
  Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002
16. [16]
  .
  CCS Chemistry | 超分子活化底物为自由基促进高效选择性光催化氧化
  . CCS Chemistry, 2025, 7(10.31635/ccschem.025.202405229): -.
17. [17]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
18. [18]
  Shuhong Xiang , Lv Yang , Yingsheng Xu , Guoxin Cao , Hongjian Zhou . Selective electrosorption of Cs(Ⅰ) from high-salinity radioactive wastewater using CNT-interspersed potassium zinc ferrocyanide electrodes. Acta Physico-Chimica Sinica, 2025, 41(9): 100097-0. doi: 10.1016/j.actphy.2025.100097
19. [19]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
20. [20]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1180)
HTML views(161)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142