Citation: Zhao Haiying, Yin Fengnan, Yu Lingyan, Li Baoguo, Bian Zhanxi. Facile Synthesis of Ferrocenylchalcone Promoted by Ionic Liquid or Phase-Transfer Catalyst[J]. Chinese Journal of Organic Chemistry, ;2016, 36(5): 1118-1121. doi: 10.6023/cjoc201511045 shu

Facile Synthesis of Ferrocenylchalcone Promoted by Ionic Liquid or Phase-Transfer Catalyst

1.
Inner Mongolia Key Laboratory of Fine Organic Synthesis, College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021

Corresponding author: Zhao Haiying, hyzhao@imu.edu.cn Bian Zhanxi, bzx1957@sina.com
Received Date: 25 November 2015
Revised Date: 14 December 2015

Fund Project: Project supported by the National Natural Science Foundation of China No. 21562032and the Natural Science Foundation of Inner Mongolia Nos. 2013MS0207, 2014JQ02the Research Program of Science and Technology at Universities of Inner Mongolia No. NJZZ001

The Claisen-Schmidt condensation of acetylferrocene with arylaldehydes in the presence of ionic liquids (ILs) or phase-transfer catalysts (PTCs) provided the corresponding ferrocenylchalcones in high yields, and PTCs can promote the condensation reaction better than those of ILs. Optimum conditions were as follows: molar ratio of acetylferrocene, arylaldehyde, n-Bu₄NPF₆ and NaOH is 1:1:2.5:0.75, and the appropriate reaction temperature is 35 ℃ in anhydrous EtOH.
- ferrocene,
- chalcone,
- ionic liquid,
- phase-transfer catalyst,
- Claisen-Schmidt condensation
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沈阳化工大学材料科学与工程学院沈阳 110142