Citation: Chen Zhonghang, Han Zongsu, Shi Wei, Cheng Peng. Design, Synthesis and Applications of Chiral Metal-Organic Frameworks[J]. Acta Chimica Sinica, ;2020, 78(12): 1336-1348. doi: 10.6023/A20090439 shu

Design, Synthesis and Applications of Chiral Metal-Organic Frameworks

College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Shi Wei, shiwei@nankai.edu.cn
Received Date: 23 September 2020
Available Online: 9 December 2020
Fund Project: the Fundamental Research Funds for the Central Universities, Nankai University 63201043the Fundamental Research Funds for the Central Universities, Nankai University 63201016the Natural Science Foundation of Tianjin 18JCJQJC47200Project supported by the National Natural Science Foundation of China (No. 21861130354), the Natural Science Foundation of Tianjin (No. 18JCJQJC47200) and the Fundamental Research Funds for the Central Universities, Nankai University (Nos. 63201016, 63201043)the National Natural Science Foundation of China 21861130354

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Chiral metal-organic frameworks have shown important applications in the identification and separation of enantiomers and asymmetric heterogeneous catalysis, owing to their structural diversities and multifunctionalities. Recently, the applications of chiral metal-organic frameworks have been expanded to other research fields, such as circularly polarized luminescence and chiral ferroelectrics. Compared with achiral metal-organic frameworks, it is highly challenging to synthesize chiral metal-organic frameworks, because the chirality introduction usually results in the difficulty of the crystallization and purification process for the design of chiral metal-organic frameworks. In this review, we discussed three main strategies that have been utilized to construct chiral metal-organic frameworks, including direct synthesis by chiral ligands, spontaneous resolution with achiral ligands or in the presence of chiral-template, and post-synthetic modification of achiral metal-organic frameworks. Moreover, the recent research progresses of chiral metal-organic frameworks in chiral molecular recognition, enantiomer separation, asymmetric catalysis, circularly polarized luminescence, and chiral ferroelectrics are discussed.
- chirality,
- metal-organic frameworks,
- design and synthesis,
- property
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