Citation: Sun Qi, Xiao Feng-Shou. Exploration of Porous Organic Polymers as a Platform for Biomimetic Catalysis[J]. Acta Chimica Sinica, ;2020, 78(9): 827-832. doi: 10.6023/A20060227 shu

Exploration of Porous Organic Polymers as a Platform for Biomimetic Catalysis

Sun Qi ^a ,
Xiao Feng-Shou ^b,,

a.
College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
b.
Key Lab of Applied Chemistry of Zhejiang Province and Department of Chemistry, Zhejiang University, Hangzhou 310028, China

Corresponding author: Xiao Feng-Shou, fsxiao@zju.edu.cn
Received Date: 12 June 2020
Available Online: 15 July 2020
Fund Project: the Fundamental Research Funds for the Central Universities 17221012001Project supported by the Fundamental Research Funds for the Central Universities (No. 17221012001) and the National Natural Science Foundation of China (No. 21720102001)the National Natural Science Foundation of China 21720102001

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Nature has served as a dominant source of inspiration in the area of chemistry, serving as prototypes for the design of materials with proficient performance. In this account, we present our effort to explore porous organic polymers (POPs) as a platform for the construction of biomimetic catalysts to enable new technologies to achieve efficient conversions. For each aspect, we firstly describe the chemical basis of nature, followed by presenting the principles and design strategies involved for functionalizing POPs along with a summary of critical requirements for materials, culminating in a demonstration of unique features of POPs. Our endeavors of using POPs to address the fundamental scientific problems related to biomimetic catalysis are then presented to show their enormous potential and capabilities for a wide range of catalytic transformations. To conclude, a personal perspective on the challenges and opportunities in this emerging field are presented.
- porous organic polymers,
- biomimetic design,
- secondary interaction,
- flexible framework,
- wettability control
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