Citation: Zhao Yajing, Xie Liang, Ma Lanchao, He Junhui. Preparation and Application of Polydimethylsiloxane Encapsulated Graphene-based Flexible Infrared Detector[J]. Acta Chimica Sinica, ;2020, 78(2): 161-169. doi: 10.6023/A19100378 shu

Preparation and Application of Polydimethylsiloxane Encapsulated Graphene-based Flexible Infrared Detector

Zhao Yajing ^a,c,† ,
Xie Liang ^a,b,† ,
Ma Lanchao ^b ,
He Junhui ^a,,

a.
Functional Nanomaterials Laboratory, Center for Micro/nanomaterials and Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b.
College of Materials Science&Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, China
c.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: He Junhui, jhhe@mail.ipc.ac.cn

^†

Received Date: 22 October 2019
Available Online: 10 February 2020
Fund Project: the Science and Technology Commission of Beijing Municipality Z151100003315018the National Natural Science Foundation of China 21571182the National Key Research and Development Program of China 2017YFA0207102Project supported by the National Natural Science Foundation of China (No. 21571182), the National Key Research and Development Program of China (No. 2017YFA0207102), the Science and Technology Commission of Beijing Municipality (No. Z151100003315018) and the Beijing "Practical Training Program"

Figures(14)

In this paper, we prepared reduced graphene oxide (rGO) films by first drop-casting graphene oxide (GO)/ethanol dispersion on top of silicon nanowires array, followed by thermal reduction in 95% Ar-5% H₂ (volume ratio) atmosphere. A series of rGO thin films were prepared by thermal reduction at different annealing temperatures ranging from 100℃ to 1200℃, and characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, four-probe square resistance tester and scanning electron microscopy (SEM). The experimental results indicate that reduction of oxygen-containing groups, dehydrogenation of C-H groups and reconstruction of C=C skeleton occurred significantly on the GO plane. Compared with the insulating GO film, the resistance of rGO thin films decreases greatly, and the sheet resistance of rGO films shows a decreasing trend with increase of reduction temperature. Then, flexible polydimethylsiloxane (PDMS) encapsulated graphene-based devices (P-rGO-P) were fabricated by spin-coating PDMS on the surface of obtained rGO films with evaporated Au interdigital electrodes. The flexible devices maintained the integrity of the rGO films while providing self-supporting characteristics. The rGO film in the device had a clear layered structure, and a certain movable space between the upper and lower PDMS layers. This sandwich structure ensures that when the P-rGO-P flexible detector is bent and squeezed, the rGO film has sufficient buffer space, and would not be subjected to excessive stress arising from adhesion to PDMS. In short, the sandwich structure endows the originally fragile device with excellent flexibility. The P-rGO-P detector was successfully applied to detecting infrared laser irradiation, human body infrared radiation, bending motions and pressure changes. The experimental results showed that the flexible encapsulated P-rGO-P infrared detectors derived from the rGO thin films reduced at varied temperatures all had response to near-infrared (1064 nm) laser irradiation, and the maximum response reached up to 2.78 mA/W. In addition, the P-rGO-P flexible detector also demonstrated fast and sensitive response to human body infrared radiation and bending changes, and could maintain its integrity and responsiveness after repeated bending.
- reduced graphene oxide,
- flexibility,
- photoelectric conversion,
- infrared detector,
- strain detector
1. [1]
  Hong, G.; Diao, S.; Antaris, A. L.; Dai, H. Chem. Rev. 2015, 115, 10816.
2. [2]
  Ko, H. C.; Stoykovich, M. P.; Song, J.; Malyarchuk, V.; Choi, W. M.; Yu, C.-J.; Geddes Ⅲ, J. B.; Xiao, J.; Wang, S.; Huang, Y.; Rogers, J. A. Nature 2008, 454, 748.
3. [3]
  Martyniuk, P.; Rogalski, A. Prog. Quantum Electron. 2008, 32, 89.
4. [4]
  Rauch, T.; Böberl, M.; Tedde, S. F.; Fürst, J.; Kovalenko, M. V.; Hesser, G.; Lemmer, U.; Heiss, W.; Hayden, O. Nat. Photonics 2009, 3, 332.
5. [5]
  Rogalski, A.; Chrzanowski, K. Metrol. Meas. Syst. 2014, 21, 565.
6. [6]
  Lv, J. T.; Yang, L. J.; Li, Z. G.; Wei, Y. T.; Zhang, B. J.; Liang, L. Q.; Wang, F. W.; Si, G. Y. Acta Chim. Sinica 2013, 71, 1275.
7. [7]
  Zhou, J. P.; Wu, B. G.; Zhou, Z. K.; Tian, J. W.; Yuan, A. H. Chin. J. Org. Chem. 2019, 39, 406.
8. [8]
  Juang, F.-S.; Su, Y.-K.; Yu, H. H.; Liu, K.-J. Mater. Chem. Phys. 2003, 78, 620.
9. [9]
  Xie, C.; Yan, F. Small 2017, 13, UNSP 1701822.
10. [10]
  Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183.
11. [11]
  Wu, H.-Q.; Linghu, C.-Y.; Lu, H.-M.; Qian, H. Chin. Phys. B 2013, 22, 098106.
12. [12]
  Zhu, J.; Yang, X.; Fu, Z.; He, J.; Wang, C.; Wu, W.; Zhang, L. Chemistry 2016, 22, 2515.
13. [13]
  Gong, M.; Liu, Q.; Cook, B.; Kattel, B.; Wang, T.; Chan, W. L.; Ewing, D.; Casper, M.; Stramel, A.; Wu, J. Z. ACS Nano 2017, 11, 4114.
14. [14]
  Haider, G.; Roy, P.; Chiang, C.-W.; Tan, W.-C.; Liou, Y.-R.; Chang, H.-T.; Liang, C.-T.; Shih, W.-H.; Chen, Y.-F. Adv. Funct. Mater. 2016, 26, 620.
15. [15]
  Manga, K. K.; Wang, J.; Lin, M.; Zhang, J.; Nesladek, M.; Nalla, V.; Ji, W.; Loh, K. P. Adv. Mater. 2012, 24, 1697.
16. [16]
  Dang, V. Q.; Han, G.-S.; Trung, T. Q.; Duy, L. T.; Jin, Y.-U.; Hwang, B.-U.; Jung, H.-S.; Lee, N.-E. Carbon 2016, 105, 353.
17. [17]
  De Fazio, D.; Goykhman, I.; Yoon, D.; Bruna, M.; Eiden, A.; Milana, S.; Sassi, U.; Barbone, M.; Dumcenco, D.; Marinov, K.; Kis, A.; Ferrari, A. C. ACS Nano 2016, 10, 8252.
18. [18]
  Xu, H.; Wu, J.; Feng, Q.; Mao, N.; Wang, C.; Zhang, J. Small 2014, 10, 2300.
19. [19]
  Cai, J.; Ruffieux, P.; Jaafar, R.; Bieri, M.; Braun, T.; Blankenburg, S.; Muoth, M.; Seitsonen, A. P.; Saleh, M.; Feng, X.; Müllen, K.; Fasel, R. Nature 2010, 466, 470.
20. [20]
  Eda, G.; Mattevi, C.; Yamaguchi, H.; Kim, H.; Chhowalla, M. J. Phys. Chem. C 2009, 113, 15768.
21. [21]
  Cao, Y.; Yang, H.; Zhao, Y.; Zhang, Y.; Ren, T.; Jin, B.; He, J.; Sun, J.-L. ACS Photonics 2017, 4, 2797.
22. [22]
  Cao, Y.; Zhu, J.; Xu, J.; He, J.; Sun, J. L.; Wang, Y.; Zhao, Z. Small 2014, 10, 2345.
23. [23]
  Yang, H.; Cao, Y.; He, J.; Zhang, Y.; Jin, B.; Sun, J.-L.; Wang, Y.; Zhao, Z. Carbon 2017, 115, 561.
24. [24]
  Huang, W.; Dong, X.; Cai, Y. Chin. Sci. Bull. 2016, 62, 635.
25. [25]
  Yan, S.; Zhang, G.; Jiang, H.; Li, F.; Zhang, L.; Xia, Y.; Wang, Z.; Wu, Y.; Li, H. ACS Appl. Mater. Interfaces 2019, 11, 10736.
26. [26]
  Sun, J.-L.; Zhang, W.; Zhu, J.-L.; Bao, Y. Opt. Express 2010, 18, 4066.
27. [27]
  Zheng, J.-G.; Sun, J.-L.; Xue, P. Chin. Phys. Lett. 2011, 28, 127302.
28. [28]
  Koppens, F. H.; Mueller, T.; Avouris, P.; Ferrari, A. C.; Vitiello, M. S.; Polini, M. Nat. Nanotech. 2014, 9, 780.
29. [29]
  Ito, Y.; Zhang, W.; Li, J.; Chang, H.; Liu, P.; Fujita, T.; Tan, Y.; Yan, F.; Chen, M. Adv. Funct. Mater. 2016, 26, 1271.
30. [30]
  Bae, J. J.; Yoon, J. H.; Jeong, S.; Moon, B. H.; Han, J. T.; Jeong, H. J.; Lee, G. W.; Hwang, H. R.; Lee, Y. H.; Jeong, S. Y.; Lim, S. C. Nanoscale 2015, 7, 15695.
31. [31]
  Jiang, F.; Zheng, X. L.; Chen, L.; Hu, N.; Yang, J.; Liao, Y. J. New Chem. Mater. 2016, 44, 7.
32. [32]
  Cao, Y.; Zhao, Y.; Wang, Y.; Zhang, Y.; Wen, J.; Zhao, Z.; Zhu, L. Carbon 2019, 144, 193.
33. [33]
  Hummers, W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339.
1. [1]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
2. [2]
  Yuhang Zhang , Weiwei Zhao , Hongwei Liu , Junpeng Lü . Progress on Self-Powered Photodetectors Based on Low-Dimensional Materials. Acta Physico-Chimica Sinica, 2025, 41(3): 2310004-0. doi: 10.3866/PKU.WHXB202310004
3. [3]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 2309045-0. doi: 10.3866/PKU.WHXB202309045
4. [4]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . Photomultiplication-Type All-Polymer Photodetectors and Their Applications in Photoplethysmography Sensor. Acta Physico-Chimica Sinica, 2025, 41(1): 100007-0. doi: 10.3866/PKU.WHXB202311021
5. [5]
  Qiaoqiao BAI , Anqi ZHOU , Xiaowei LI , Tang LIU , Song LIU . Construction of pressure-temperature dual-functional flexible sensors and applications in biomedicine. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2259-2274. doi: 10.11862/CJIC.20240128
6. [6]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
7. [7]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
8. [8]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
9. [9]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
10. [10]
  Yang Meiqing , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 2310046-0. doi: 10.3866/PKU.WHXB202310046
11. [11]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
12. [12]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
13. [13]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
14. [14]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
15. [15]
  Huasen Lu , Shixu Song , Qisen Jia , Guangbo Liu , Luhua Jiang . Advances in Cu₂O-based Photocathodes for Photoelectrochemical Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(2): 2304035-0. doi: 10.3866/PKU.WHXB202304035
16. [16]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
17. [17]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
18. [18]
  Anbang Du , Yuanfan Wang , Zhihong Wei , Dongxu Zhang , Li Li , Weiqing Yang , Qianlu Sun , Lili Zhao , Weigao Xu , Yuxi Tian . Photothermal Microscopy of Graphene Flakes with Different Thicknesses. Acta Physico-Chimica Sinica, 2024, 40(5): 2304027-0. doi: 10.3866/PKU.WHXB202304027
19. [19]
  Ke Zhao , Zhen Liu , Luyao Liu , Changyuan Yu , Jingshun Pan , Xuguang Huang . Functionalized Reflective Structure Fiber-Optic Interferometric Sensor for Trace Detection of Lead Ions. Acta Physico-Chimica Sinica, 2024, 40(4): 2304029-0. doi: 10.3866/PKU.WHXB202304029
20. [20]
  Yingtong FAN , Yujin YAO , Shouhao WAN , Yihang SHEN , Xiang GAO , Cuie ZHAO . Construction of copper tetrakis(4-carboxyphenyl)porphyrin/silver nanowire composite electrode for flexible and transparent supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1309-1317. doi: 10.11862/CJIC.20250043

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(1689)
HTML views(348)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142