Citation: Song Bo, Qin Anjun, Tang Ben Zhong. New Polymerizations Based on Green Monomer of Carbon Dioxide[J]. Acta Chimica Sinica, ;2020, 78(1): 9-22. doi: 10.6023/A19090340 shu

New Polymerizations Based on Green Monomer of Carbon Dioxide

Song Bo ^a ,
Qin Anjun ^a,, ,
Tang Ben Zhong ^a,b,,

a.
State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, Center for Aggregation-Induced Emission, South China University of Technology, Guangzhou 510640
b.
Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science & Technology, Hong Kong

Corresponding author: Qin Anjun, msqinaj@scut.edu.cn Tang Ben Zhong, tangbenz@ust.hk
Received Date: 15 September 2019
Available Online: 31 January 2019
Fund Project: the National Natural Science Foundation of China 21490571the Natural Science Foundation of Guangdong Province 2016A030312002the National Natural Science Foundation of China 21788102the National Natural Science Foundation of China 21525417the Innovation and Technology Commission of Hong Kong ITC-CNERC14S01Project supported by the National Natural Science Foundation of China (Nos. 21788102, 21525417, 21490571), the Natural Science Foundation of Guangdong Province (Nos. 2016A030312002, 2019B030301003), and the Innovation and Technology Commission of Hong Kong (ITC-CNERC14S01)the Natural Science Foundation of Guangdong Province 2019B030301003

Figures(41)

Carbon dioxide (CO₂) is an abundant, inexpensive, non-toxic and renewable C1 resource, and it is also a kind of green monomer. The polymerizations based on CO₂ have been one of the hot research topics. The copolymerization of CO₂ and epoxide monomers was widely studied in the past few years and has been industrialized. Some new polymerizations based on CO₂ have also been reported recently. There are two ways to produce polymeric materials from CO₂. One is converting CO₂ into monomers for further ring opening or step growth polymerizations, such as lactone, cyclic carbonates, furan-2, 5-dicarboxylic acid. Another is directly using CO₂ as a monomer for the copolymerization with other monomers to generate polymers. They are both significant for developing new polymerizations based on CO₂ and expanding CO₂-based polymeric materials. The advances in converting CO₂ into polymeric materials during the past few years are summarized in this review and the perspective in this area is discussed.
- carbon dioxide,
- alkyne monomer,
- cyclic carbonate,
- lactone,
- furan-2, 5-dicarboxylic acid
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