Citation: Tian Haiquan, Zheng Li-Min. Cyclic Lanthanide-based Molecular Clusters: Assembly and Single Molecule Magnet Behavior[J]. Acta Chimica Sinica, ;2020, 78(1): 34-55. doi: 10.6023/A19090330 shu

Cyclic Lanthanide-based Molecular Clusters: Assembly and Single Molecule Magnet Behavior

Tian Haiquan ^a,b ,
Zheng Li-Min ^a,,

a.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210023
b.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059

Corresponding author: Zheng Li-Min, lmzheng@nju.edu.cn
Received Date: 6 September 2019
Available Online: 6 January 2019
Fund Project: the National Key R & D Program of China 2018YFA0306004the National Natural Science Foundation of China 21731003Project supported by the National Key R&D Program of China (Nos. 2017YFA0303203, 2018YFA0306004) and the National Natural Science Foundation of China (No. 21731003)the National Key R & D Program of China 2017YFA0303203

Figures(34)

Lanthanide-based single molecule magnets have received tremendous attentions in recent years owing to the strong magnetic anisotropies of the lanthanide ions arising from the strong spin-orbital couplings. Cyclic metal clusters, also called molecular wheels or metallacrown ether, are a subclass of metal clusters. From the magnetic point of view, cyclic transition metal clusters can be devided into three types, e.g. ferromagnetically coupled cyclic clusters which favor single molecule magnet behavior, and antiferromagnetically coupled even-or odd-numbered cyclic clusters with S=0 or S=1/2 ground state. The magnetic properties of lanthanide-based cyclic clusters are more complicated because the magnetic interactions between the lanthanide ions are extremely weak. The overall magnetic behavior is largely dominated by the single ion anisotropy and the dipole-dipole interactions between the metal ions. When the anisotropy axes of the lanthanide ions in the cyclic clusters are arranged in a toroidal manner, single-molecule toroics could be achieved. Therefore, the design and synthesis of cyclic lanthanide-based clusters can provide not only new materials with architectural beauty and single molecule magnet behavior, but also single-molecule toroics with vortex distribution of the magnetic dipoles of lanthanide ions, which would have potential applications in information storage, quantum computing, spintronic devices and multiferroic materials. Noting that lanthanide-based single-molecule toroics have been described detailly in several reviews, this article will summarize the current status of the cyclic lanthanide clusters with the focus on the design and assembly strategies, the structural characteristics and magnetic studies. Most work have been concentrated on the Ln₃, Ln₄ and Ln₆ cyclic clusters, including those containing oxygen centers. Examples of even-numbered cyclic clusters Ln_x (x ≥ 8) are much less, and those of odd-numbered cyclic clusters Ln_x (x ≥ 5) are rare. As the cyclic clusters are frequently distorted to different extent, many of them exhibit single molecule magnet behavior, and only few of them show toroic magnetization. It remains future challenges to design and synthesize new lanthanide-based cyclic clusters with regular and flat geometries and toroically arranged magnetic moments, and to achieve the multifunctions in the same molecular composite.
- single molecule magnet,
- lanthanide,
- cyclic cluster,
- self-assembly
1. [1]
  Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 365, 141. doi: 10.1038/365141a0
2. [2]
  Milios, C. J.; Vinslava, A.; Wernsdorfer, W.; Moggach, S.; Parsons, S.; Perlepes, S. P.; Christou, G.; Brechin, E. K. J. Am. Chem. Soc. 2007, 129, 2754. doi: 10.1021/ja068961m
3. [3]
  (a) Ishikawa, N.; Sugita, M.; Ishikawa, T.; Koshihara, S.-y.; Kaizu, Y. J. Am. Chem. Soc. 2003, 125, 8694. (b) Ishikawa, N.; Sugita, M.; Wernsdorfer, W. J. Am. Chem. Soc. 2005, 127, 3650. (c) Ishikawa, N.; Sugita, M.; Wernsdorfer, W. Angew. Chem. Int. Ed. 2005, 44, 2931.
4. [4]
5. [5]
  Blagg, R. J.; Muryn, C. A.; McInnes, E. J. L.; Tuna, F.; Winpenny, R. E. P. Angew. Chem. Int. Ed. 2011, 50, 6530. doi: 10.1002/anie.201101932
6. [6]
  Rinehart, J. D.; Fang, M.; Evans, W. J.; Long, J. R. Nat. Chem. 2011, 3, 538. doi: 10.1038/nchem.1063
7. [7]
  Chen, Y.-C.; Liu, J.-L.; Ungur, L.; Liu, J.; Li, Q.-W.; Wang, L.-F.; Ni, Z.-P.; Chibotaru, L. F.; Chen, X.-M.; Tong, M.-L. J. Am. Chem. Soc. 2016, 138, 2829. doi: 10.1021/jacs.5b13584
8. [8]
  (a) Goodwin, C. A. P.; Ortu, F.; Reta, D.; Chilton, N. F.; Mills, D. P. Nature 2017, 548, 439. (b) Guo, F.-S.; Day, B. M.; Chen, Y.-C.; Tong, M.-L.; Mansikkamäki, A.; Layfield, R. A. Angew. Chem. Int. Ed. 2017, 56, 11445. (c) Guo, F.-S.; Day, B. M.; Chen, Y.-C.; Tong, M.-L.; Mansikkamäki, A.; Layfield, R. A. Science 2018, 362, 1400.
9. [9]
  Mezei, G.; Zaleski, C. M.; Pecoraro, V. L. Chem. Rev. 2007, 107, 4933. doi: 10.1021/cr078200h
10. [10]
  Saalfrank, R. W.; Bernt, I.; Uller, E.; Hampel, F. Angew. Chem. Int. Ed. 1997, 36, 2482. doi: 10.1002/anie.199724821
11. [11]
  McInnes, E. J. L.; Timco, G. A.; Whitehead, G. F. S.; Winpenny, R. E. P. Angew. Chem. Int. Ed. 2015, 54, 14244. doi: 10.1002/anie.201502730
12. [12]
  Cadiou, C.; Murrie, M.; Paulsen, C.; Villar, V.; Wernsdorfer, W.; Winpenny, R. E. P. Chem. Commun. 2001, 2666.
13. [13]
  (a) Waldmann, O. Coord. Chem. Rev. 2005, 249, 2550. (b) Lante, V.; Rousochatzakis, I.; Penc, K.; Waldmann, O.; Mila, F. Phys. Rev. B 2009, 79, 180412(R).
14. [14]
  (a) Schnack, J. Dalton Trans. 2010, 39, 4677. (b) Bramwell, S. T.; Gingras, M. J. P. Science 2001, 294, 1495. (c) Struck, J.; Olschlager, C.; Le Targat, R.; Soltan-Panahi, P.; Eckardt, A.; Lewenstein, M.; Windpassinger, P.; Sengstock, K. Science 2011, 333, 996.
15. [15]
  Cador, O.; Gatteschi, D.; Sessoli, R.; Larsen, F. K.; Overgaard, J.; Barra, A.-L.; Teat, S. J.; Timco, G. A.; Winpenny, R. E. P. Angew. Chem. Int. Ed. 2004, 43, 5196. doi: 10.1002/anie.200460211
16. [16]
  Baker, M. L.; Timco, G. A.; Piligkos, S.; Mathieson, J. S.; Mutka, H.; Tuna, F.; Kozłowski, P.; Antkowiak, M.; Guidi, T.; Gupta, T.; Rath, H.; Woolfson, R. J.; Kamieniarz, G.; Pritchard, R. G.; Weihe, H.; Cronin, L; Rajaraman, G.; Collison, D.; McInnes, E. J. L.; Winpenny, R. E. P. Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 19113. doi: 10.1073/pnas.1213127109
17. [17]
  Yao, H.-C.; Wang, J.-J.; Ma, Y.-S.; Waldmann, O.; Du, W.-X.; Song, Y.; Li, Y.-Z.; Zheng, L.-M.; Decurtins, S.; Xin, X.-Q. Chem. Commun. 2006, 1745.
18. [18]
  Hoshino, N.; Nakano, M.; Nojiri, H.; Wernsdorfer, W.; Oshio, H. J. Am. Chem. Soc. 2009, 131, 15100. doi: 10.1021/ja9066496
19. [19]
  Fernandez, A.; Ferrando-Soria, J.; Pineda, E. M.; Tuna, F.; Vitorica-Yrezabal, I. J.; Knappke, C.; Ujma, J.; Muryn, C. A.; Timco, G. A.; Barran, P. E.; Ardavan, A.; Winpenny, R. E. P. Nat. Commun. 2016, 7, 10240. doi: 10.1038/ncomms10240
20. [20]
  Bernot, K.; Luzon, J.; Bogani, L.; Etienne, M.; Sangregorio, C.; Shanmugam, M.; Caneschi, A.; Sessoli, R.; Gatteschi, D. J. Am. Chem. Soc. 2009, 131, 5573. doi: 10.1021/ja8100038
21. [21]
  (a) Ungur, L.; Lin, S.-Y.; Tang, J.; Chibotaru, L. F. Chem. Soc. Rev. 2014, 43, 6894. (b) Tang, J.; Zhang, P. In Lanthanide Single Molecule Magnets, Springer Berlin Heidelberg, Berlin, Heidelberg, 2015, Chapter 4, pp. 127~166. (c) Li, X.-L.; Tang, J. Dalton Trans. 2019, 48, 15358.
22. [22]
  Tang, J.; Hewitt, I. J.; Madhu, N. T.; Chastanet, G.; Wernsdorfer, W.; Anson, C. E.; Benelli, C.; Sessoli, R.; Powell, A. K. Angew. Chem., Int. Ed. 2006, 45, 1729. doi: 10.1002/anie.200503564
23. [23]
  (a) Chibotaru, L. F.; Ungur, L.; Soncini, A. Angew. Chem. Int. Ed. 2008, 47, 4126. (b) Luzon, J.; Bernot, K.; Hewitt, I. J.; Anson, C. E.; Powell, A. K.; Sessoli, R. Phys. Rev. Lett. 2008, 100, 247205.
24. [24]
  Plokhov, D. I.; Popov, A. I.; Zvezdin, A. K. Phys. Rev. B: Condens. Matter Mater. Phys. 2011, 84, 224436. doi: 10.1103/PhysRevB.84.224436
25. [25]
  Costes, J.-P.; Dahan, F.; Nicodème, F. Inorg. Chem.2001, 40, 5285. doi: 10.1021/ic0103704
26. [26]
  Salman, Z.; Giblin, S. R.; Lan, Y.; Powell, A. K.; Scheuermann, R.; Tingle, R.; Sessoli, R. Phys. Rev. B 2010, 82, 174427. doi: 10.1103/PhysRevB.82.174427
27. [27]
  Xue, S.; Chen, X.-H.; Zhao, L.; Guo, Y.-N.; Tang, J. Inorg. Chem.2012, 51, 13264. doi: 10.1021/ic301785v
28. [28]
  (a) Shen, S.; Xue, S.; Lin, S.-Y.; Zhao, L.; Tang, J. Dalton Trans. 2013, 42, 10413. (b) Hänninen, M. M.; Mota, A. J.; Aravena, D.; Ruiz, E.; Sillanpää, R.; Evangelisti, M.; Colacio, E. Chem. Eur. J. 2014, 20, 8410.
29. [29]
  Zhang, L.; Zhang, P.; Zhao, L.; Wu, J.; Guo, M.; Tang, J. Inorg. Chem.2015, 54, 5571. doi: 10.1021/acs.inorgchem.5b00702
30. [30]
  Lin, S.-Y.; Zhao, L.; Guo, Y.-N.; Zhang, P.; Guo, Y.; Tang, J. Inorg. Chem.2012, 51, 10522. doi: 10.1021/ic300371m
31. [31]
  Dolinar, B. S.; Alexandropoulos, D. I.; Vignesh, K. R.; James, T.; Dunbar, K. R. J. Am. Chem. Soc.2018, 140, 908. doi: 10.1021/jacs.7b12495
32. [32]
  Wang, Y.-X.; Shi, W.; Li, H.; Song, Y.; Fang, L.; Lan, Y.; Powell, A. K.; Wernsdorfer, W.; Ungur, L.; Chibotaru, L. F.; Shen, M.; Cheng, P. Chem. Sci. 2012, 3, 3366. doi: 10.1039/c2sc21023a
33. [33]
  (a) Lin, S.-Y.; Guo, Y.-N.; Zhao, L.; Zhang, P.; Ke, H.; Tang, J. Chem. Commun.2012, 48, 6924. (b) Lin, S.-Y.; Wang, C.; Zhao, L.; Tang, J. Chem. Asian J.2014, 9, 3558.
34. [34]
  Gould, C. A.; Darago, L. E.; Gonzalez, M. I.; Demir, S.; Long, J. R. Angew. Chem. Int. Ed. 2017, 56, 10103. doi: 10.1002/anie.201612271
35. [35]
  Woodruff, D. N.; Tuna, F.; Bodensteiner, M.; Winpenny, R. E. P.; Layfield, R. A. Organometallics 2013, 32, 1224. doi: 10.1021/om3010096
36. [36]
  Pineda, E. M.; Lan, Y.; Fuhr, O.; Wernsdorfer, W.; Ruben, M. Chem. Sci. 2017, 8, 1178. doi: 10.1039/C6SC03184F
37. [37]
  Guo, P.-H.; Liu, J.; Wu, Z.-H.; Yan, H.; Chen, Y.-C.; Jia, J.-H.; Tong, M.-L. Inorg. Chem.2015, 54, 8087. doi: 10.1021/acs.inorgchem.5b01322
38. [38]
  Xue, S.; Zhao, L.; Guo, Y.-N.; Chen, X.-H.; Tang, J. Chem. Commun.2012, 48, 7031. doi: 10.1039/c2cc31864d
39. [39]
  Wu, S.-Q.; Xie, Q.-W.; An, G.-Y.; Chen, X.; Liu, C.-M.; Kou, H.-Z. Dalton Trans. 2013, 42, 4369. doi: 10.1039/c3dt50265a
40. [40]
  Anwar, M. U.; Thompson, L. K.; Dawe, L. N.; Habib, F.; Murugesu, M. Chem. Commun. 2012, 48, 4576. doi: 10.1039/c2cc17546k
41. [41]
  Das, C.; Vaidya, S.; Gupta, T.; Frost, J. M.; Righi, M.; Brechin, E. K.; Affronte, M.; Rajaraman, G.; Shanmugam, M. Chem.-Eur. J.2015, 21, 15639. doi: 10.1002/chem.201502720
42. [42]
  Wu, J.; Lin, S.-Y.; Shen, S.; Li, X.-L.; Zhao, L.; Zhang, L.; Tang, J. Dalton Trans. 2017, 46, 1577. doi: 10.1039/C6DT04456E
43. [43]
  Xue, S.; Zhao, L.; Guo, Y.-N.; Tang, J. Dalton Trans. 2012, 41, 351. doi: 10.1039/C1DT11883H
44. [44]
  Lu, J.; Zhang, Y.-Q.; Li, X.-L.; Guo, M.; Wu, J.; Zhao, L.; Tang, J. Inorg. Chem. 2019, 58, 5715. doi: 10.1021/acs.inorgchem.9b00067
45. [45]
  Bi, Y.; Wang, X.-T.; Liao, W.; Wang, X.; Deng, R.; Zhang, H.; Gao, S. Inorg. Chem.2009, 48, 11743. doi: 10.1021/ic9017807
46. [46]
  Tian, H.; Su, J.-B.; Bao, S.-S.; Kurmoo, M.; Huang, X.-D.; Zhang, Y.-Q.; Zheng, L.-M. Chem. Sci. 2018, 9, 6424. doi: 10.1039/C8SC01228H
47. [47]
  (a) Langley, S. K.; Moubaraki, B.; Forsyth, C. M.; Gass, I. A.; Murray, K. S. Dalton Trans. 2010, 39, 1705. (b) Ungur, L.; Langley, S. K.; Hooper, T. N.; Moubaraki, B. E.; Brechin, K.; Murray, K. S.; Chibotaru, L. F. J. Am. Chem. Soc. 2012, 134, 18554.
48. [48]
  Baniodeh, A.; Magnani, N.; Bräse, S.; Anson, C. E.; Powell, A. K. Dalton Trans. 2015, 44, 6343. doi: 10.1039/C5DT00237K
49. [49]
  Tian, H.; Bao, S.-S.; Zheng, L.-M. Dalton Trans. 2015, 44, 14208. doi: 10.1039/C5DT02468D
50. [50]
  Joarder, B.; Mukherjee, S.; Xue, S.; Tang, J.; Ghosh, S. K. Inorg. Chem. 2014, 53, 7554. doi: 10.1021/ic500875m
51. [51]
  Tian, H.; Bao, S.-S.; Zheng, L.-M. Eur. J. Inorg. Chem.2016, 3184.
52. [52]
  Lu, J.; Montigaud, V.; Cador, O.; Wu, J.; Zhao, L.; Li, X.-L.; Guo, M.; Le Guennic, B.; Tang, J. Inorg. Chem. 2019, 58, 11903. doi: 10.1021/acs.inorgchem.9b01068
53. [53]
  Tian, H.; Bao, S.-S.; Zheng, L.-M. Chem. Commun. 2016, 52, 2314. doi: 10.1039/C5CC08740F
54. [54]
  Tian, H.; Zhao, L.; Tang, J. Cryst. Growth. Des. 2018, 18, 1173. doi: 10.1021/acs.cgd.7b01612
55. [55]
  Chandrasekhar, V.; Bag, P.; Colacio, E. Inorg. Chem. 2013, 52, 4562. doi: 10.1021/ic400091j
56. [56]
  Kajiwara, T.; Wu, H.; Ito, T.; Iki, N.; Miyano, S. Angew. Chem. Int. Ed. 2004, 43, 1832. doi: 10.1002/anie.200353449
57. [57]
  Westin, L. G.; Kritikos, M.; Caneschi, A. Chem. Commun. 2003, 1012.
58. [58]
  Das, S.; Dey, A.; Kundu, S.; Biswas, S.; Narayanan, R. S.; Titos-Padilla, S.; Lorusso, G.; Evangelisti, M.; Colacio, E.; Chandrasekhar, V. Chem.-Eur. J.2015, 21, 16955. doi: 10.1002/chem.201501992
59. [59]
  Kajiwara, T.; Katagiri, K.; Takaishi, S.; Yamashita, M.; Iki, N. Chem. Asian J. 2006, 1, 349. doi: 10.1002/asia.200600057
60. [60]
  Zhao, L.; Xue, S.; Tang, J. Inorg. Chem. 2012, 51, 5994. doi: 10.1021/ic3005807
61. [61]
  Wang, K.; Chen, Z.-L.; Zou, H.-H.; Hu, K.; Li, H.-Y.; Zhang, Z.; Sun, W.-Y.; Liang, F.-P. Chem. Commun. 2016, 52, 8297. doi: 10.1039/C6CC02208A
62. [62]
  Biswas, S.; Das, S.; Acharya, J.; Kumar, V.; van Leusen, J.; Kögerler, P.; Herrera, J. M.; Colacio, E.; Chandrasekhar, V. Chem.-Eur. J. 2017, 23, 5154. doi: 10.1002/chem.201700471
1. [1]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
2. [2]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
3. [3]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
4. [4]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
5. [5]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
6. [6]
  Wenjian Zhang , Mengxin Fan , Wenwen Fei , Wei Bai . Cultivation of Critical Thinking Ability: Based on RAFT Polymerization-Induced Self-Assembly. University Chemistry, 2025, 40(4): 108-112. doi: 10.12461/PKU.DXHX202406099
7. [7]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
8. [8]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
9. [9]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
10. [10]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
11. [11]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
12. [12]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
13. [13]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249
14. [14]
  Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
15. [15]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
16. [16]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
17. [17]
  Zhiwen HUANG , Qi LIU , Jianping LANG . W/Cu/S cluster-based supramolecular macrocycles and their third-order nonlinear optical responses. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 79-87. doi: 10.11862/CJIC.20240184
18. [18]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
19. [19]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
20. [20]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084

Get Citation

PDF

XML

Metrics

PDF Downloads(41)
Abstract views(3393)
HTML views(689)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142