Citation: Kang Shusen, Fan Shaocong, Liu Yan, Wei Yancun, Li Ying, Fang Jingang, Meng Chuizhou. Al-Ion Polymer Solid Electrolyte[J]. Acta Chimica Sinica, ;2019, 77(7): 647-652. doi: 10.6023/A19040119 shu

Al-Ion Polymer Solid Electrolyte

Kang Shusen ^a,b,, ,
Fan Shaocong ^a,b ,
Liu Yan ^a,b ,
Wei Yancun ^a,b ,
Li Ying ^a,b ,
Fang Jingang ^a,b ,
Meng Chuizhou ^a,b,c,,

a.
State Key Laboratory for Coal-Based Low-Carbon Energy, Langfang 065001
b.
ENN Research & Development Co., Ltd, Langfang 065001
c.
School of Mechanical Engineering, Hebei University of Technology, Tianjin 300130

Corresponding author: Kang Shusen, kshusen@163.com Meng Chuizhou, 2018108@hebut.edu.cn
Received Date: 8 April 2019
Available Online: 12 July 2019
Fund Project: Project supported by the Key Research and Development Program in Hebei Province (No. 18394405D)the Key Research and Development Program in Hebei Province 18394405D

Figures(7)

Lithium ion batteries have dominated the field of energy storage for portal electronics during the past twenty years, and now it is ambitious to power electric vehicles. However, drawbacks of limited power density and cycle life time as well as cost and safety concerns lead to limitations for the emerging large-scale stationary energy storage application. Therefore, researchers all over the world have been dedicated to find alternative next-generation energy storage technologies. Rechargeable Al-ion battery is emerging as one of the most promising sustainable candidates for the usage of large-scale energy storage because of its low-cost, high charge/discharge rate capability and extremely long cycling life. However, currently most of the Al-ion battery has been developed by using of liquid electrolyte, such as ionic liquid, urea and molten salt electrolyte, which has the risk of electrolyte leakaging. Electrolyte evaporation also occurs when batteries undergo extremely long cycling charge/discharge process. While making all-solid-state Al-ion battery is able to effectively solve the leakaging problem, but there are few reports on this topic. What is more, the all-solid-state Al-ion battery also has higher energy density due to device structure design of using no separators and bulky packaging. In this paper, we have developed a new kind of solid Al-ion electrolyte by using crown ether as both functional additive and coordination group and polyethyleneglycols (PEO) as basement through a solution casting method. Experiment tests indicates that the crown ether could not only yield a good stability and compatibility of Al ions with PEO but also reduce the crystallinity of composite electrolyte, which is helpful for achieving high ion conductivity. The obtained AF solid-state electrolyte has a high ion-conductivity (5.5×10^-6 S/cm at room temperature, 1.86×10^-3 S/cm at 100℃), broad electrochemical potential window (0~3 V) and strong mechanical property. This work provides applicable high-performance polymer electrolyte and paves the way to develop the full all-solid-state Al-ion batteries.
- Al-ion battery,
- solid polymer electrolyte (SPE),
- solution casting method,
- crown
1. [1]
  Masanobu, C.; Hiroki, T.; Shota, M.; Eiji, H.; Hiroshi, I. ACS Appl. Mater. Interfaces 2015, 7, 24385. doi: 10.1021/acsami.5b06420
2. [2]
  Jayaprakash, N.; Das, S. K.; Archer, L. A. Chem. Commun. 2011, 47, 12610. doi: 10.1039/c1cc15779e
3. [3]
  Wang, W.; Jiang, B.; Xiong, W.; Sun, H.; Lin, Z.; Hu, L.; Tu, J.; Hou, J.; Zhu, H.; Jiao, S. Sci. Rep. 2013, 160, 3383.
4. [4]
  Liu, S.; Hu, J. J.; Yan, N. F.; Pan, G. L.; Li, G. R.; Gao, X. P. Energy Environ. Sci. 2012, 5, 9743. doi: 10.1039/c2ee22987k
5. [5]
  Rani, J. V.; Kanakaiah, V.; Dadmal, T.; Rao, M. S.; Bhavanarushi, S. J. Electrochem. Soc. 2013, 160, A1781. doi: 10.1149/2.072310jes
6. [6]
  Hudak, N. S. J. Phys. Chem. C 2014, 118, 5203.
7. [7]
  Sun, H.; Wang, W.; Yu, Z.; Yuan, Y.; Wang, S.; Jiao, S. Chem. Commun. 2015, 51, 11892. doi: 10.1039/C5CC00542F
8. [8]
  Lin, M.; Gong, M.; Lu, B.; Wu, Y.; Wang, D.; Guan, M.; Angell, M.; Chen, C.; Yang, J.; Wang, B.; Dai, H. Nature 2015, 520, 324. doi: 10.1038/nature14340
9. [9]
  Chen, C.; Guo, F.; Liu, Y.; Huang, T.; Zheng, B.; Ananth, N.; Xu, Z.; Gao, W.; Gao, C. Adv. Mater. 2017, 1605958.
10. [10]
  Fu, L.; Li, N.; Liu, Y.; Wang, W.; Zhu, Y.; Wu, Y. Chin. J. Chem. 2017, 35, 13. doi: 10.1002/cjoc.v35.1
11. [11]
  Song, S.; Kotobuki, M.; Zheng, F.; Li, Q.; Xu, C.; Wang, Y.; Dong, W.; Li, Z.; Hua, N.; Lu, L. Solid State Ionics 2017, 300, 165. doi: 10.1016/j.ssi.2016.12.023
12. [12]
  Sun, X.; Fang, Y.; Jiang, X.; Yoshii, K.; Tsuda, T.; Dai, S. Chem. Commun. 2016, 52, 292. doi: 10.1039/C5CC06643C
13. [13]
  Yu, Z.; Jiao, S.; Li, S.; Chen, X.; Song, W.; Teng, T.; Tu, J.; Chen, H.; Zhang, G.; Fang, D. Adv. Funct. Mater. 2018, 1806799.
14. [14]
  Li, C.; Wang, J.; Chang, Z.; Yin, Y.; Yang, X.; Zhang, X. Scientia Sinica Chimica 2018, 48, 964.
15. [15]
  Nagasubramanian, G.; Stefano, S. D. J. Electrochem. Soc. 1990, 137, 3380.
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沈阳化工大学材料科学与工程学院沈阳 110142

Al-Ion Polymer Solid Electrolyte

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com