Citation: Chang Shilei, Liang Feng, Yao Yaochun, Ma Wenhui, Yang Bin, Dai Yongnian. Research Progress of Metallic Carbon Dioxide Batteries[J]. Acta Chimica Sinica, ;2018, 76(7): 515-525. doi: 10.6023/A18030125 shu

Research Progress of Metallic Carbon Dioxide Batteries

Chang Shilei ^a,b ,
Liang Feng ^a,b,c,, ,
Yao Yaochun ^a,b ,
Ma Wenhui ^a,b,c ,
Yang Bin ^a,b,c ,
Dai Yongnian ^a,b,c

a.
Vacuum Metallurgical National Engineering Laboratory, Kunming University of Science and Technology, Kunming 650093
b.
Yunnan Key Laboratory of Nonferrous Metals Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093
c.
State Key Laboratory of Complex Nonferrous Metal Resources Clear Utilization in Yunnan Province, Kunming University of Science and Technology, Kunming 650093

Corresponding author: Liang Feng, liangfeng@kmust.edu.cn
Received Date: 30 March 2018
Available Online: 30 July 2018
Fund Project: the the National Natural Science Foundation of China 51704136Project supported by the the National Natural Science Foundation of China (Nos. 51704136, 11765010), the Yunnan applied basic research project of China (No. 2016FB087) and the Yunnan Academy of Liberal Exploration Funds of China (No. 2017HA006)the Yunnan applied basic research project of China 2016FB087the Yunnan Academy of Liberal Exploration Funds of China 2017HA006the the National Natural Science Foundation of China 11765010

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Due to the heavy use of fossil fuels, the emission of carbon dioxide has been steadily increased and the climate has been deteriorated severely. In order to solve these problems, various physical and chemical methods were used to reduce the amount of carbon dioxide in the atmosphere, but the result is not so effective. Metal carbon dioxide batteries not only can capture carbon dioxide, but also can be used as clean energy storage devices. At the same time, the development and research of metal carbon dioxide batteries also promote the development of the electric vehicle industry towards a more economical, environmentally friendly and sustainable direction. Based on these advantages, metal carbon dioxide battery has developed rapidly in recent years. Li-CO₂ batteries exhibit an extremely high discharge capacity of 17625 mAh/g and a cut-off capacity of 1000 mAh/g at a current density of 100 mA/g, running for 100 cycles at low overpotentials. Quasi-solid state Na-CO₂ batteries are non-flammable and have strong electrolyte-locking ability. It can run 400 cycles at 500 mA/g with a fixed capacity of 1000 mAh/g in pure CO₂. Its electrochemical performance has the potential to be further improved. Al-CO₂ battery has good application prospects and economic benefits due to the low cost of Al as well as great economic value of the sodium aluminate as discharge product. Mg-CO₂ battery shows a discharge voltage plateau of 0.9 V when the volume ratio of CO₂/O₂ is 1:1, which is higher than that of pure O₂. This paper mainly introduces the research progress of metal (lithium, sodium, aluminum, and magnesium) carbon dioxide battery, and compares the electrochemical performance of metal (lithium, sodium) carbon dioxide battery with metal (lithium, sodium) oxygen battery, puts forward the current problems of metal carbon dioxide batteries, and provides the solutions. Finally, the future development of metal carbon dioxide batteries is reviewed.
- metal carbon dioxide battery,
- electrochemical performance,
- carbon conversion,
- energy storage,
- cathode material
1. [1]
  Friedlingstein, P.; Houghton, R. A.; Marland, G.; Hackler, J.; Boden, T. A.; Conway, T. J.; Canadell, J. G.; Raupach, M. R.; Ciais, P.; Quere, C. L. Nature Geosci. 2010, 3, 811. doi: 10.1038/ngeo1022
2. [2]
  Schrag, D. P. Science 2007, 315, 812. doi: 10.1126/science.1137632
3. [3]
  Kim, J.; Hyun, J. Y.; Chong, W. K.; Ariaratnam, S. J. Eng. Des. Technol. 2015, 15, 270.
4. [4]
  Chen, B.; Nishio, M.; Song, Y. C.; Akai, M. Energy Procedia 2009, 1, 4969. doi: 10.1016/j.egypro.2009.02.329
5. [5]
  Gao, S.; Lin, Y.; Jiao, X. C.; Sun, Y. F.; Luo, Q. Q.; Zhang, W. H.; Li, D. Q.; Yang, J. L.; Xie, Y. Nature 2016, 529, 68. doi: 10.1038/nature16455
6. [6]
  Rosen, B. A.; Salehi-Khojin, A.; Thorson, M. R.; Zhu, W.; Whipple, D. T.; Paul, J. A. Science 2011, 334, 643. doi: 10.1126/science.1209786
7. [7]
  Zhang, S.; Kang P, Ubnoske, S.; Brennaman, M. K.; Song, N.; House, R. L.; Glass, J. T.; Meyer, T. J. J. Am. Chem. Soc. 2014, 136, 7845. doi: 10.1021/ja5031529
8. [8]
  Egan, D. R. P.; Low, C. T. J.; Walsh, F. C. J. Phys. Sources 2011, 196, 5725. doi: 10.1016/j.jpowsour.2011.01.008
9. [9]
  Nier, A. O.; McElroy, M. B. J. Geophys. Res. 1977, 82, 4341. doi: 10.1029/JS082i028p04341
10. [10]
  Jiang, J.; Liu, X. F.; Zhao, S. Y.; He, P.; Zhou, H. S. Acta Chim. Sinica 2014, 72, 417.
11. [11]
  Gu, D. M.; Zhang, C. M.; Gu, S.; Zhang, Y.; Wang, Y.; Qiang, L. S. Acta Chim. Sinica 2012, 70, 2115.
12. [12]
  Cheng, F. Y.; Chen, J. Acta Chim. Sinica 2013, 71, 473.
13. [13]
  Zhang, Z.; Wang, X. G.; Zhang, X.; Xie, Z. J.; Chen, Y. N.; Ma, L. P.; Peng, Z. Q.; Zhou, Z. Adv. Sci. 2018, 5, 2198.
14. [14]
  Yang, S. X.; Qiao, Y.; He, P.; Liu, Y. J.; Cheng, Z.; Zhu, J. J.; Zhou, H. S. Energy Environ. Sci. 2017, 10, 972. doi: 10.1039/C6EE03770D
15. [15]
  Hu, X. F.; Li, Z. F.; Zhao, Y. R.; Sun, J. C.; Zhao, Q.; Wang, J. B.; Tao, Z. L.; Chen, J. Sci. Adv. 2017, 3, e1602396.
16. [16]
  Al Sadat, W. I.; Archer, L. A. Sci. Adv. 2016, 2, e1600968. doi: 10.1126/sciadv.1600968
17. [17]
  Das, S. K.; Xu, S.; Archer, L. A. Electrochem. Commun. 2013, 27, 59. doi: 10.1016/j.elecom.2012.10.036
18. [18]
  Xu, S. M..; Das, S. K.; Archer, L. A. RSC Adv. 2013, 3, 6656 doi: 10.1039/c3ra40394g
19. [19]
  Zhang, Z.; Zhang, Q.; Chen, Y. N.; Bao, J.; Zhou, X. L.; Xie, Z. J.; Wei, J. P.; Zhou, Z. Angew. Chem., Int. Ed. 2015, 54, 6550. doi: 10.1002/anie.201501214
20. [20]
  Zhang, X.; Zhang, Q.; Zhang, Z.; Chen, Y. N.; Xie, Z. J.; Wei, J. P.; Zhou, Z. Chem. Commun. 2015, 51, 14636. doi: 10.1039/C5CC05767A
21. [21]
  Hu, X. F.; Sun, J. C.; Li, Z. F.; Zhao, Q.; Chen, C. C.; Chen, J. Angew. Chem., Int. Ed. 2016, 55, 6482. doi: 10.1002/anie.201602504
22. [22]
  Xu, S. M.; Lu, Y. Y.; Wang, H. S.; Abruna, H. D.; Archer, L. A. J. Mater. Chem. A 2014, 2, 17723. doi: 10.1039/C4TA04130E
23. [23]
  Xu, S. M. Ph. D. Dissertation, Cornell University, 2016.
24. [24]
  Liu, Y.; Wang, R.; Lyu, Y. C.; Li, H.; Chen, L. Q. Energy Environ. Sci. 2014, 7, 677. doi: 10.1039/c3ee43318h
25. [25]
  Yang, S.; He, P.; Zhou, H. Energy Environ. Sci. 2016, 3, 1650.
26. [26]
  Yin, W.; Grimaud, A.; Azcarate, I.; Yang, C.; Tarascon, J. M. J. Phys. Chem. C 2018, 12, 6546.
27. [27]
  Qie, L.; Lin, Y.; Connell, J. W.; Xu, J. T.; Dai, L. M. Angew. Chem., Int. Ed. 2017, 56, 6970. doi: 10.1002/anie.201701826
28. [28]
  Zhang, X.; Wang, C. Y.; Li, H. H.; Wang, X. G.; Chen, Y. N.; Xie, Z. J.; Zhou, Z. J. Mater. Chem. A 2018, 6, 2792. doi: 10.1039/C7TA11015D
29. [29]
  Zhang, Z.; Zhang, Z. W.; Liu, P. F.; Xie, Y. P.; Cao, K. Z.; Zhou, Zhen. J. Mater. Chem. A 2018, 6, 3218. doi: 10.1039/C7TA10497A
30. [30]
  Li, S. W.; Dong, Y.; Zhou, J. W.; Liu, Y.; Wang, J. M.; Cao, X.; Han, Y. Z.; Qi, P. F.; Wang, B. Energy Environ. Sci. 2018. DOI:10.1039/C8EE00415C. doi: 10.1039/C8EE00415C
31. [31]
  Hu, X.; Li, Z.; Chen, J. Angew. Chem., Int. Ed. 2017, 56, 5785. doi: 10.1002/anie.201701928
32. [32]
  Li, C.; Guo, Z. Y.; Yang, B. C.; Liu, Y.; Wang, Y. G.; Xia, Y. Y. Angew. Chem., Int. Ed. 2017, 56, 9126. doi: 10.1002/anie.201705017
33. [33]
  Takechi, K.; Singa, T.; Asaoka, T. Chem. Commun. 2011, 47, 3463. doi: 10.1039/c0cc05176d
34. [34]
  McCloskey, B. D.; Valery, A, ; Luntz, A. C.; Gowda, S. R.; Wallraff, G. M.; Garcia, J. M.; Mori, T.; Krupp, L. E.; J. M. J. Phys. Chem. Lett. 2013, 4, 2989. doi: 10.1021/jz401659f
35. [35]
  Lim, H. D.; Song, H.; Kim, J.; Gwon, H.; Bae, Y.; Park, K. Y.; Hong, J.; Kim, H.; Kim, T.; Kim, Y. H.; Lepro, X.; Robles, R. O.; Baughman, R. H.; Kang, K. Angew. Chem., Int. Ed. 2014, 53, 3926. doi: 10.1002/anie.201400711
36. [36]
  Wang, R.; Yu, X.; Bai, J.; Li, H.; Huang, X. J.; Chen, L. Q.; Yang, X. Q. J. Power Sources 2012, 218, 113. doi: 10.1016/j.jpowsour.2012.06.082
37. [37]
  Yin, W.; Grimaud, A.; Lepoivre, F.; Yang, C. Z.; Tarascon, J. M. J. Phys. Chem. Lett. 2016, 8, 214.
38. [38]
  Xie, Z. J.; Zhang, X.; Zhang, Z.; Zhou, Z. Adv. Mater. 2017, 29, 1605891. doi: 10.1002/adma.201605891
39. [39]
  Nemeth, K.; Srajer, G. RSC Adv. 2014, 4, 1879. doi: 10.1039/C3RA45528A
40. [40]
  Takechi, K.; Shiga, T.; Asaoka, T. Chem. Commun. 2011, 47, 3463. doi: 10.1039/c0cc05176d
41. [41]
  Lim, H. K.; Lim, H. D.; Park, K. Y.; Seo, D. H.; Gwon, H.; Hong, J.; Goddard, W. A.; Kim, H.; Kang, K. J. Am. Chem. Soc. 2013, 135, 9733. doi: 10.1021/ja4016765
42. [42]
  Fang, C.; Luo, J. M.; Jin, C. B.; Yuan, H. D.; Sheng, O. W.; Huang, H.; Gan, Y. P.; Xia, Y.; Liang, C.; Zhang, J.; Zhang, W. K.; Tao, X. Y. ACS Appl. Mater. Interfaces 2018, DOI:10.1021/acsami.8b04034. doi: 10.1021/acsami.8b04034
43. [43]
  Xu, S. M.; Lu, Y. Y.; Wang, H. S.; Abruna, H. D.; Archer, L. A. J. Mater. Chem. A 2014, 2, 17723. doi: 10.1039/C4TA04130E
44. [44]
  Gough, L. P.; Day, W. C. US Geological Survey 2010.
45. [45]
  Scrosati, B.; Garche, J. J. Power Sources 2010, 195, 2419. doi: 10.1016/j.jpowsour.2009.11.048
46. [46]
  Gao, X. Y.; Xue, J. L.; Shi, G. J. TMS 2018, 99.
47. [47]
  Kelley, C. S.; Fuller, J.; Carlin, R. T.; Wilkes, J. S. J. Electrochem. Soc. 1992, 139, 694. doi: 10.1149/1.2069286
48. [48]
  Peter, J. C. Energy Policy 2017, 106, 41. doi: 10.1016/j.enpol.2017.03.039
49. [49]
  Dymek, C. J.; Williams, J. L.; Groeger, D. J.; Auborn, J. J. J. Electrochem. Soc. 1984, 131, 2887. doi: 10.1149/1.2115436
50. [50]
  Revel, R.; Audichon, T.; Gonzalez, S. J. Power Sources 2014, 272, 415. doi: 10.1016/j.jpowsour.2014.08.056
51. [51]
  Wasserscheid, P.; Keim, W. Angew. Chem., Int. Ed. 2000, 39, 3772. doi: 10.1002/(ISSN)1521-3773
52. [52]
  Peter, J. C. Energy Policy 2017, 106, 41. doi: 10.1016/j.enpol.2017.03.039
53. [53]
  Ficher, J.; Lehmann, T.; Heitz, E. J. Appl. Electrochem. 1981, 11, 743. doi: 10.1007/BF00615179
54. [54]
  Zheng, T. X.; Hu, Y. B.; Zhang, Y. X.; Yang, S. W.; Pan, F. S. Mater. Des. 2018, 137, 245. doi: 10.1016/j.matdes.2017.10.031
55. [55]
  Liang, F.; Hayashi, K. J. Electrochem. Soc. 2015, 162, A1. doi: 10.1149/2.0221502jes
56. [56]
  Kang, Y.; Liang, F.; Hayashi, K. Electrochim. Acta 2016, 218, 119. doi: 10.1016/j.electacta.2016.09.113
57. [57]
  Liang, F.; Qiu, X. C.; Zhang, Q. K.; Kang, Y.; Koo, A.; Hayashi, K.; Chen, K. F.; Xue, D. F.; Hui, K. N.; Yadegari, H.; Sun, X. L. Nano Energy 2018, 49, 574. doi: 10.1016/j.nanoen.2018.04.074
58. [58]
  Kang, Y.; Zou, D.; Zhang, J. Y.; Liang, F.; Hayashi, K.; Wang, H.; Xue, D. F.; Chen, K. F.; Adair, K. R.; Sun, X. L. Electrochim. Acta 2017, 224, 222.
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