Citation: Du Junyi, Xia Chungu, Sun Wei. Progress in Mononuclear Iron-Oxygen and Manganese-Oxygen Adducts[J]. Acta Chimica Sinica, ;2018, 76(5): 329-346. doi: 10.6023/A18020076 shu

Progress in Mononuclear Iron-Oxygen and Manganese-Oxygen Adducts

Du Junyi ^a,b ,
Xia Chungu ^a ,
Sun Wei ^a,,

a.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, and Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics(LICP), Chinese Academy of Sciences, Lanzhou 730000
b.
University of Chinese Academy of Sciences, Beijing 100049

Corresponding author: Sun Wei, wsun@licp.cas.cn
Received Date: 22 February 2018
Available Online: 30 May 2018
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21473226, 21773273), and the Natural Science Foundation of Jiangsu Province (No. BK20161261)the Natural Science Foundation of Jiangsu Province BK20161261the National Natural Science Foundation of China 21773273the National Natural Science Foundation of China 21473226

Figures(36)

In biological system, metalloenzymes utilize dioxygen for metabolically oxidative transformations, in which organic compounds can be oxidized efficiently. Therefore, it is of great interest to unravel the enzymatic mechanism in the development of clean and efficient catalytic oxidation reactions. In the dioxygen activation by metalloenzymes, a series of metal-oxygen adducts, such as metal-superoxo, -peroxo, -hydroperoxo, -oxo and -hydroxo species, are formed as the active intermediates. In general, these intermeditates are difficult to capture for further characterizations and investigations because of their unstability and the complicated enzymatic systems. Alternatively, the enzyme models, designed and synthesized by mimicking the active center and coordination environment of metalloenzymes, can be easily acquired and manipulated for further structure and reactivity studies. In this review, we briefly illustrate the active sites of metalloenzymes in biology and focus on the recent achievements in mononuclear iron-oxygen and manganese-oxygen adducts in biomimetic studies.
- metal-oxygen adduct,
- metalloenzymes,
- enzyme models,
- C—H bond activation,
- dioxygen activation
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